(E)-6-(4-(diphenylamino)styrenyl)-N,N-diphenylnaphthalen-2-amine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: (E)-6-(4-(diphenylamino)styrenyl)-N,N-diphenylnaphthalen-2-amine
• 英文别名: (E)-6-(4-(diphenylamino)styryl)-N,N-diphenylnaphthalen-2-amine；2-(Diphenylamino)-6-[4-(diphenylamino)styryl]naphthalene；N,N-diphenyl-6-[(E)-2-[4-(N-phenylanilino)phenyl]ethenyl]naphthalen-2-amine
• 化学式: C₄₂H₃₂N₂
• 分子量: 564.729
• InChiKey: NJWJVPXCXKIBJD-QURGRASLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.9
• 重原子数：
  44
• 可旋转键数：
  8
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-[4-(N,N-diphenylamino)styryl]-6-bromo-naphthalene 、 二苯胺 在 tris-(dibenzylideneacetone)dipalladium(0) 、 三叔丁基膦 sodium t-butanolate 作用下， 以 xylene 为溶剂， 反应 1.5h， 以60%的产率得到(E)-6-(4-(diphenylamino)styrenyl)-N,N-diphenylnaphthalen-2-amine
  参考文献：
  名称：

  Diarylamino substituted arylvinyl naphthalene compounds and a blue-light electroluminescent device having the compounds

  摘要：

  二苯胺基芳基乙烯基萘化合物，特别用于具有高纯度颜色的蓝光有机发光二极管，具有以下代表性结构式：其中Ar1、Ar2、Ar3和Ar4是取自苯基、联苯基、1-萘基、2-萘基、氟苯基、氟联苯基、1-氟基萘基、2-氟基萘基、苯基取代为甲基或乙基或异丙基或叔丁基或甲氧基或乙氧基，1-萘基取代为甲基或乙基或异丙基或叔丁基或甲氧基或乙氧基，2-萘基取代为甲基或乙基，氟苯基取代为甲基或异丙基或叔丁基或甲氧基或乙氧基；其中“Ar5”是以下取代基团之一：其中R1至R14相同或不同且为氢。

  公开号：

  US20060159953A1

文献信息

• DITRIPHENYLENE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME
  申请人：YEN FENG-WEN

  公开号：US20160204345A1

  公开（公告）日：2016-07-14

  The present invention discloses a novel ditriphenylene derivative is represented by the following formula(I), the organic EL device employing the ditriphenylene derivative as host material or dopant material of emitting layer can lower driving voltage, prolong half-life time and increase the efficiency. Wherein m, n represent an integer of 0 to 10. X is a divalent bridge selected from the atom or group consisting from O, S, C(R 3 )(R 4 ), NR 5 , Si(R 6 )(R 7 ). Ar 1 , Ar 2 , R 1 to R 7 are substituents and the same definition as described in the present invention.

  本发明公开了一种新型二三苯衍生物，其由以下式(I)表示，采用该二三苯衍生物作为有机EL器件的主体材料或发射层的掺杂材料可以降低驱动电压，延长半寿命并提高效率。其中m、n表示0到10的整数。X是从O、S、C(R3)(R4)、NR5、Si(R6)(R7)中选择的二价桥。Ar1、Ar2、R1到R7是取代基，具有与本发明中描述的相同定义。
• INDENOTRIPHENYLENE-BASED AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENCE DEVICE USING THE SAME
  申请人：YEN FENG-WEN

  公开号：US20200115369A1

  公开（公告）日：2020-04-16

  The present invention discloses an indenotriphenylene-based amine derivative and an organic electroluminescence device employing the indenotriphenylene-based amine derivative as the dopant material, the hole transporting material, or the electron blocking material of the organic electroluminescence device. The organic electroluminescence device of the present invention exhibits improved performance, such as reduced power consumption, increased current efficiency, and longer half-life time.

  本发明公开了一种基于吲哚三苯基胺衍生物的有机电致发光器件，该器件将基于吲哚三苯基胺衍生物作为有机电致发光器件的掺杂材料、空穴传输材料或电子阻挡材料。本发明的有机电致发光器件表现出改进的性能，如降低功耗、提高电流效率和延长半衰期时间。
• ORGANIC COMPOUND AND ORGANIC ELECTROLUMINESCENCE DEVICE USING THE SAME
  申请人：YEN FENG-WEN

  公开号：US20200235306A1

  公开（公告）日：2020-07-23

  The present invention discloses an organic compound resented by the following formula (1) and an organic electroluminescence device using the organic compound. The organic compound may be for lowering a driving voltage or power consumption or increasing a current efficiency of half-life of the organic electroluminescence device. The same definition as described in the present invention.

  本发明公开了一种由以下式（1）表示的有机化合物，以及使用该有机化合物的有机电致发光器件。该有机化合物可用于降低有机电致发光器件的驱动电压或功耗，或增加器件的半衰期的电流效率。与本发明中描述的相同定义。
• INDENOTRIPHENYLENE DERIVATIVES AND ORGANIC LIGHT EMITTING DEVICE USING THE SAME
  申请人：LUMINESCENCE TECHNOLOGY CORPORATION

  公开号：US20140131664A1

  公开（公告）日：2014-05-15

  The present invention discloses a new indenotriphenylene derivatives and organic light emitting device using the derivatives. The organic light emitting device employing new indenotriphenylene derivatives as host material can lower driving voltage, prolong half-lifetime, increasing efficiency. The new indenotriphenylene derivatives are represented by the following formula (A): Wherein A 1 , A 2 are substituted or unsubstituted fused ring hydrocarbon units with one to five rings. Preferably A 1 , A 2 are phenyl group, naphthyl group, anthracenyl group, pyrenyl group, chrysenyl group. Perylenyl group. R 1 to R 4 are identical or different. R 1 to R 4 are independently selected from the group consisting of a hydrogen atom, a halide, alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted aralkyl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 6 to 30 carbon atoms. X is selected from carbon atom or nitrogen atom.

  本发明公开了一种新的茚三苯衍生物以及使用这些衍生物的有机发光器件。采用新的茚三苯衍生物作为主体材料的有机发光器件可以降低驱动电压，延长半寿命，并提高效率。新的茚三苯衍生物由以下式（A）表示：其中A1，A2是具有一个至五个环的取代或未取代的融合环烃基。最好的情况是A1，A2是苯基，萘基，蒽基，芘基，芴基，蒽基或苝基。R1到R4是相同或不同的。R1到R4独立地选自由氢原子，卤素，具有1至20个碳原子的烷基，具有6至30个碳原子的取代或未取代的芳基，具有6至30个碳原子的取代或未取代的芳基烷基，具有6至30个碳原子的取代或未取代的杂芳基。X选自碳原子或氮原子。
• FLUORENE COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME
  申请人：YEN FENG-WEN

  公开号：US20140151645A1

  公开（公告）日：2014-06-05

  The present invention discloses a new fluorene compound and organic EL device using the compound. The organic EL device employing the new fluorene compound as host material can lower driving voltage, prolong half-lifetime. The fluorene compound can functions as blue emitting host material of a light emitting layer and improve CIE colour purity in blue emitting device. The fluorene compound are represented by the following formula(A): Wherein R 1 to R 6 are identical or different. R 1 to R 6 are independently selected from the group consisting of a hydrogen atom, a halide, alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted aralkyl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 6 to 30 carbon atoms. R 7 ˜R 13 are identical or different R 7 to R 13 are independently selected from the group consisting of hydrogen atom, halide, alkyl group, aryl group, heteroaryl group. m and n are independently an integer of 0 to 3, X is selected from carbon or nitrogen.

  本发明公开了一种新的芴化合物以及使用该化合物的有机EL器件。采用新的芴化合物作为主体材料的有机EL器件可以降低驱动电压，延长半寿命。芴化合物可以作为发光层的蓝色发射主体材料，并提高蓝色发射器件的CIE色纯度。芴化合物由以下式(A)表示：其中R1至R6相同或不同。R1至R6独立地选自氢原子、卤素、具有1至20个碳原子的烷基基团、具有6至30个碳原子的取代或未取代芳基团、具有6至30个碳原子的取代或未取代芳基烷基基团、具有6至30个碳原子的取代或未取代杂环芳基团的组成。R7至R13相同或不同，R7至R13独立地选自氢原子、卤素、烷基基团、芳基团、杂环芳基团。m和n分别是0到3的整数，X选自碳或氮。