二十二烷亚磷酸苯 | 15824-34-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 二十二烷亚磷酸苯
• 英文名称: Didodecyl phenyl phosphite
• CAS: 15824-34-7
• 化学式: C₃₀H₅₅O₃P
• 分子量: 494.7
• InChiKey: UHKDZFIPIJSOTR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.1
• 重原子数：
  34
• 可旋转键数：
  26
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• Peroxide reduction in functionalized vegetable oils
  申请人：Denoux Michael G.

  公开号：US20080132712A1

  公开（公告）日：2008-06-05

  Disclosed is a method for the reduction of residual peroxides in vegetable oils, preferably epoxidized vegetable oils using a phosphorous compound preferably alkyl/aryl substituted phosphite compounds or hypophosphorous acid and its derivatives.

  揭示了一种用于减少植物油中残留过氧化物的方法，优选是使用磷化合物，特别是烷基/芳基取代的亚磷酸酯化合物或次磷酸及其衍生物来处理环氧化植物油。
• [EN] LIQUID BUTYLARYL PHOSPHITE COMPOSITIONS<br/>[FR] COMPOSITIONS LIQUIDES DE BUTYLARYL PHOSPHITE
  申请人：CHEMTURA CORP

  公开号：WO2011014212A1

  公开（公告）日：2011-02-03

  A phosphite composition comprising at least two of a tris(dibutylaryl) phosphite, a tris(monobutylaryl) phosphite, a bis(dibutylaryl)monobutylaryl phosphite, and a bis(monobutylaryl)dibutylaryl phosphite. The inventive phosphite composition is a liquid at ambient conditions. The inventive phosphite is a reaction product of a phorsphous trihalide with an alkylate composition having a molar ratio of monobutylaryl alkylate to dibutylaryl alkylate that is higher than 2:1 and equal to or lower than 5:1.

  一种磷酸酯组合物，包括至少两种三(二丁基芳基)磷酸酯、三(单丁基芳基)磷酸酯、双(二丁基芳基)单丁基芳基磷酸酯和双(单丁基芳基)二丁基芳基磷酸酯中的两种或以上。该创新磷酸酯组合物在常温下为液态。该创新磷酸酯是磷三卤化物与具有单丁基芳基烷基化合物的摩尔比高于2:1且等于或低于5:1的烷基化合物反应生成的产物。
• Coordination-polymeric triethanolamineperchlorato(triflato)metal inner complexes as additives for synthetic polymers
  申请人：Wehner Wolfgang

  公开号：US20090105387A1

  公开（公告）日：2009-04-23

  Stabilizer system for chlorinated polymers, especially PVC, comprising at least one coordination-polymeric triethanolamineperchlorato(triflato)metal inner complex comprising the monomer unit of the formula (A) The stabilizer system may additionally comprise substituted cyanoacetylureas or/and 6-aminouracils or/and 3-aminocrotonic esters or/and hydantoins or/and monomeric or polymeric dihydropyridines or alkaline earth metal hydroxides or/and hydrotalcites or/and dawsonites or/and zeolites or/and glycidyl compounds or/and cyanamides or/and cyanoguanidines or/and melamines. In addition, phosphites or/and sterically hindered amines or/and NOR-HALS compounds may be present.

  氯化聚合物的稳定剂体系，特别是PVC，包括至少一种配位聚合三乙醇胺高氯酸盐（三氟乙酸盐）金属内部络合物，该络合物包括式（A）的单体单位。稳定剂系统还可以包括取代的氰乙酰脲或/和6-氨基尿嘧啶或/和3-氨基巴豆酸酯或/和恒化酮或/和单体或聚合二氢吡啶或碱土金属氢氧化物或/和水滑石或/和道森石或/和沸石或/和环氧丙烷化合物或/和氰胺或/和氰基脲或/和三聚氰胺。此外，磷酸酯或/和立体阻隔胺或/和NOR-HALS化合物也可能存在。
• COORDINATION-POLYMERIC TRIETHANOLAMINEPERCHLORATO(TRIFLATO)METAL INNER COMPLEXES AS ADDITIVES FOR SYNTHETIC POLYMERS
  申请人：Wehner Wolfgang

  公开号：US20090131564A1

  公开（公告）日：2009-05-21

  Stabilizer system for chlorinated polymers, especially PVC, comprising at least one coordination-polymeric triethanolamineperchlorato(triflato)metal inner complex comprising the monomer unit of the formula (A) The stabilizer system may additionally comprise substituted cyanoacetylureas or/and 6-aminouracils or/and 3-aminocrotonic esters or/and hydantoins or/and monomeric or polymeric dihydropyridines or alkaline earth metal hydroxides or/and hydrotalcites or/and dawsonites or/and zeolites or/and glycidyl compounds or/and cyanamides or/and cyanoguanidines or/and melamines. In addition, phosphites or/and sterically hindered amines or/and NOR-HALS compounds may be present.

  氯化聚合物，尤其是PVC的稳定剂系统，包括至少一个配位聚合三乙醇胺高氯酸盐（三氟甲烷磺酸盐）金属内部配合物，其中包括公式（A）的单体单位。稳定剂系统还可以包括取代的氰乙酰脲或/和6-氨基尿嘧啶或/和3-氨基巴豆酸酯或/和咪唑二酮或/和单体或聚合二氢吡啶或碱土金属氢氧化物或/和水滑石或/和达氏石或/和沸石或/和环氧丙烷化合物或/和氰胺或/和氰基脲或/和三聚氰胺。此外，还可以存在亚磷酸酯或/和立体阻碍胺或/和NOR-HALS化合物。
• Nitro-containing esters of a substituted phenylpropionic acid, compositions containing them as stabilizing agent against oxidative degradation, and stabilizer compositions
  申请人：UNIROYAL, INC.

  公开号：EP0006745A1

  公开（公告）日：1980-01-09

  Novel nitro containing esters of a phenylpropionic acid having the geral formula wherein R, and R2 are lower alkyl or a radical of the structure and "X" represents a tertiary butyl radical can be prepared by reacting a propionic acid chlorid of the formula with the corresponding nitroalkanols of the formula These esters stabilize organic material as polyolefines normally subject to oxidative deterioration and can be a component of a stabilizer composition, the other component being a dialkyl thiodipropionate.

  新型含硝基的苯基丙酸酯，其分子式为 其中 R 和 R2 为低级烷基或结构基团 和 "X "代表叔丁基，可通过式中的丙酸氯化物与相应的式中的硝基烷醇反应制备 与相应的式中硝基烷醇反应制备 这些酯类可稳定通常会氧化变质的聚烯烃等有机材料，并可作为稳定剂组合物的一种成分，另一种成分是硫代二丙酸二烷基酯。

表征谱图