PARTICLES OF ALUMINUM SALT HYDROXIDE CONTAINING ORGANIC ACID ANION, METHOD FOR PRODUCTION THEREOF AND USE THEREOF
申请人:KYOWA CHEMICAL INDUSTRY CO., LTD.
公开号:EP1731497A1
公开(公告)日:2006-12-13
There are provided organic acid anion containing aluminum salt hydroxide particles represented by the following general formula (I):
Ma[Al1-xM'x]bAzBy (OH)n·mH2O (I)
(wherein M is at least one cation selected from the group consisting of Na+, K+, NH4+ and H3O+, M' is at least one metal cation selected from the group consisting of Cu2+, Zn2+, Ni2+, Sn4+, Zr4+, Fe2+, Fe3+ and Ti4+ , A is at least one organic acid anion, B is at least one inorganic acid anion, and a, b, m, n, x, y and z satisfy 0.7 ≤ a ≤ 1.35, 2.7 ≤ b ≤ 3.3, 0 ≤ m ≤ 5, 4 ≤ n ≤ 7, 0 ≤ x ≤ 0.6, 1.7 ≤ y ≤ 2.4, and 0.001 ≤ z ≤ 0.5, respectively.)
The particles are in the shape of grains, pairs, rectangular parallelepiped, disks (go stones), hexagonal plates, rice grains or cylinders and have a uniform particle diameter.
提供了由以下通式(I)表示的含氢氧化铝盐的有机酸阴离子颗粒:
Ma[Al1-xM'x]bAzBy (OH)n-mH2O (I)
(其中 M 是至少一种选自 Na+、K+、NH4+ 和 H3O+ 的阳离子,M'是至少一种选自 Cu2+、Zn2+、Ni2+、Sn4+、Zr4+、Fe2+、Fe3+ 和 Ti4+ 的金属阳离子,A 是至少一种有机酸阴离子,B 是至少一种无机酸阴离子,且 a、b、m、n、x、y 和 z 满足 0。7 ≤ a ≤ 1.35,2.7 ≤ b ≤ 3.3,0 ≤ m ≤ 5,4 ≤ n ≤ 7,0 ≤ x ≤ 0.6,1.7 ≤ y ≤ 2.4,0.001 ≤ z ≤ 0.5)。
颗粒的形状有粒状、对偶状、矩形平行四边形、盘状(棋子)、六角板状、米粒状或圆柱状,颗粒直径均匀一致。