N,N’-bis-n-dodecyl-trans-1,4-dihydro-1,4-diarsininetetracarboxylic acid diimide

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯烷类
• 英文名称: N,N’-bis-n-dodecyl-trans-1,4-dihydro-1,4-diarsininetetracarboxylic acid diimide
• 英文别名: 5,11-Didodecyl-2,8-dimethyl-5,11-diaza-2,8-diarsatricyclo[7.3.0.03,7]dodeca-1(9),3(7)-diene-4,6,10,12-tetrone；5,11-didodecyl-2,8-dimethyl-5,11-diaza-2,8-diarsatricyclo[7.3.0.03,7]dodeca-1(9),3(7)-diene-4,6,10,12-tetrone
• 化学式: C₃₄H₅₆As₂N₂O₄
• 分子量: 706.673
• InChiKey: RZWSNTWTUGPWRN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.58
• 重原子数：
  42
• 可旋转键数：
  22
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.76
• 拓扑面积：
  74.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  cis-1,4-dihydro-1,4-dimethyl-2,3,5,6-tetrakis(t-butoxycarbonyl)-1,4-diarsinine 在 甲酸 作用下， 以 甲苯 为溶剂， 反应 30.0h， 生成 N,N’-bis-n-dodecyl-trans-1,4-dihydro-1,4-diarsininetetracarboxylic acid diimide 、 N,N’-bis-n-dodecyl-trans-1,4-dihydro-1,4-diarsininetetracarboxylic acid diimide
  参考文献：
  名称：

  1,4-二氢胂四羧酸二亚胺在非酸性条件下从顺式到反式的立体异构化

  摘要：

  Stereoisomerization of cis-1,4-dihydro-1,4-dimethyl-1,4-diarsininetetracarboxylic acid diimides, which were prepared from cis-1,4-dihydro-1,4-diarsininetetracarboxylic acid dianhydride with n-dodecylamine or aniline, to trans-isomers in CDCl3 proceeded at room temperature and quantitatively by repeated concentration and dissolution process in various solvents such as CHCl3, toluene, and ethyl acetate. Two stereoisomers were isolated respectively as single crystals, of which structures were determined by X-ray crystallography.

  DOI：

  10.3987/com-17-13699

文献信息

• Stereoisomerization of 1,4-Dihydroarsininetetracarboxylic Acid Diimides under Non-Acidic Condition from cis- to trans-Forms
  作者：Kensuke Naka、Takuji Kato、Koushi Abe、Makoto Ishidoshiro、Shintaro Nishiyama、Susumu Tanaka、Hiroaki Imoto、Seiji Watase、Kimihiro Matsukawa、Kazuyoshi Tanaka

  DOI：10.3987/com-17-13699

  日期：——

  Stereoisomerization of cis-1,4-dihydro-1,4-dimethyl-1,4-diarsininetetracarboxylic acid diimides, which were prepared from cis-1,4-dihydro-1,4-diarsininetetracarboxylic acid dianhydride with n-dodecylamine or aniline, to trans-isomers in CDCl3 proceeded at room temperature and quantitatively by repeated concentration and dissolution process in various solvents such as CHCl3, toluene, and ethyl acetate. Two stereoisomers were isolated respectively as single crystals, of which structures were determined by X-ray crystallography.