N,N'-bis-(2,2,6,6-tetramethyl-1-propoxypiperidin-4-yl)-N,N'-bis-{2,4-bis-{n-butyl-(2,2,6,6-tetramethyl-1-propoxypiperidin-4-yl)amino}-[1,3,5]triazin-6-yl}hexane-1,6-diamine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N'-bis-(2,2,6,6-tetramethyl-1-propoxypiperidin-4-yl)-N,N'-bis-{2,4-bis-{n-butyl-(2,2,6,6-tetramethyl-1-propoxypiperidin-4-yl)amino}-[1,3,5]triazin-6-yl}hexane-1,6-diamine
• 英文别名: N,N'-bis-(2,2,6,6-tetramethyl-1-propoxypiperidin-4-yl)-N,N'-bis-{2,4-bis-{n-butyl-(2,2,6,6-tetramethylpiperidin-4-yl)amino}-[1,3,5]triazin-6-yl}hexane-1,6-diamine；2-N-[6-[[4,6-bis[butyl-(2,2,6,6-tetramethyl-1-propoxypiperidin-4-yl)amino]-1,3,5-triazin-2-yl]-(2,2,6,6-tetramethyl-1-propoxypiperidin-4-yl)amino]hexyl]-4-N,6-N-dibutyl-2-N,4-N,6-N-tris(2,2,6,6-tetramethyl-1-propoxypiperidin-4-yl)-1,3,5-triazine-2,4,6-triamine
• 化学式: C₁₀₀H₁₉₂N₁₈O₆
• 分子量: 1742.74
• InChiKey: IDLXPEIGPBLMDS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  25.5
• 重原子数：
  124
• 可旋转键数：
  49
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.94
• 拓扑面积：
  172
• 氢给体数：
  0
• 氢受体数：
  24

反应信息

• 作为产物：
  描述：

  N,N'-bis-(2,2,6,6-tetramethylpiperidin-4-yl)-N,N'-bis-{2,4-bis-{n-butyl-(2,2,6,6-tetramethylpiperidin-4-yl)amino}-[1,3,5]triazin-6-yl}hexane-1,6-diamine 、 3-溴丙烯 在 5% Pd(II)/C(eggshell) potassium carbonate 、 过氧乙酸 作用下， 以 甲苯 、 二氯甲烷 为溶剂， 反应 4.0h， 以94%的产率得到N,N'-bis-(2,2,6,6-tetramethyl-1-propoxypiperidin-4-yl)-N,N'-bis-{2,4-bis-{n-butyl-(2,2,6,6-tetramethyl-1-propoxypiperidin-4-yl)amino}-[1,3,5]triazin-6-yl}hexane-1,6-diamine
  参考文献：
  名称：

  [EN] STERICALLY HINDERED AMINE STABILIZER
  [FR] AGENT STABILISANT AMINÉ STÉRIQUEMENT ENCOMBRÉ

  摘要：

  本发明涉及具有以下式I或II的含氧受位阻胺类化合物：(II)，其中，例如，F2、R3、R5、R6、R8、R9、R11、R12、R13、R14为正丁基；Z1至Z10为丙氧基，R1、R4、R7、R10、R13为2,2,6,6-四甲基-1-丙氧基-哌啶-4-基。还公开了包含具有式I或II的化合物和易于氧化、热降解或光诱导降解的有机材料的组合物。可选地，还包含进一步添加剂。

  公开号：

  WO2011029744A1

文献信息

• STERICALLY HINDERED AMINE STABILIZER
  申请人：Menozzi Edoardo

  公开号：US20120232197A1

  公开（公告）日：2012-09-13

  The present invention relates to oxygen-substituted sterically hindered amines of the formulae I or II: (II), wherein, for example, F 2 , R 3 , R 5 , R 6 , R 8 , R 9 , R 11 , R 12 , R 13 , R 14 are n-butyl; Z 1 to Z 10 are propoxy and R 1 , R 4 , R 7 , R 10 , R 13 are 2,2,6,6-tetramethyl-1-propoxy-piperidin-4-yl. Compositions comprising compounds of formulae I or II and an organic material, which is susceptible to oxidative, thermal or light-induced degradation, are further disclosed. Optionally, further additives are contained.

  本发明涉及公式I或II的含氧立体阻碍胺化合物：（II），其中，例如，F2，R3，R5，R6，R8，R9，R11，R12，R13，R14为正丁基；Z1至Z10为丙氧基，而R1，R4，R7，R10，R13为2,2,6,6-四甲基-1-丙氧基哌啶-4-基。此外，还公开了包含公式I或II化合物和易于氧化、热降解或光诱导降解的有机材料的组合物。可选地，还包含其他添加剂。
• HALOGEN-FREE SULPHONIC ACID ESTER AND/OR SULPHINIC ACID ESTER AS FLAME RETARDANT, FLAME RETARDANT SYNERGISTS AND RADICAL GENERATORS IN PLASTICS
  申请人：FRAUNHOFER-GESELLSCHAFT ZUR FÖRDERUNG DER ANGEWANDTEN FORSCHUNG E. V.

  公开号：US20200231783A1

  公开（公告）日：2020-07-23

  The present invention relates to the use of halogen-free sulphonic acid esters and/or sulphinic acid esters as flame retardant and/or flame retardant synergists in plastics. The invention furthermore relates to the use of said compounds as radical generators in plastics, particularly in order to increase the molecular weight of the plastics, to branch and/or cross-link the plastics, to reduce the molecular weight of the plastics, to influence the molecular weight distribution of the plastics and to graft unsaturated monomers to the plastics. The present invention furthermore relates to the use of flame-retardant plastic compositions in the electrical or electronics industry, construction industry, transport industry, preferably automobiles, aircraft, trains and ships, for medical applications, for household appliances, vehicle parts, consumer products, packaging, furniture and textiles.
• METHOD FOR STABILIZING HALOGEN-FREE THERMOPLASTIC RECYCLATES, STABILIZED PLASTIC COMPOSITIONS, AND MOLDING COMPOUNDS AND MOLDED PARTS PRODUCED THEREFROM
  申请人：FRAUNHOFER-GESELLSCHAFT ZUR FÖRDERUNG DER ANGEWANDTEN FORSCHUNG E. V.

  公开号：US20200317886A1

  公开（公告）日：2020-10-08

  The invention relates to a method for stabilizing halogen-free thermoplastic recyclates or pre-damaged plastics against oxidative, thermal, and/or actinic degradation. In the method according to the invention, at least one alditol or cyclitol is introduced into a halogen-free thermoplastic recyclate as a component, and optionally in addition thereto, at least one primary antioxidant and/or at least one secondary antioxidant is introduced into a halogen-free thermoplastic recyclate. By virtue of the method according to the invention, plastic recyclates can be stabilized against oxidative, thermal, and/or actinic degradation with a high degree of effectiveness and in a very environmentally friendly and inexpensive manner. The invention additionally relates to corresponding recyclate-based plastic compositions, to molding compound and molded parts produced therefrom, to stabilizer compositions, and to the use thereof for stabilizing halogen-free thermoplastic recyclates against oxidative, thermal, and/or actinic degradation.
• EFFICIENT PHOSPHOROUS STABILISERS BASED ON DIPHENYLAMINE AND HETEROCYCLIC DIPHENYLAMINE DERIVATIVES
  申请人：FRAUNHOFER-GESELLSCHAFT ZUR FÖRDERUNG DER ANGEWANDTEN FORSCHUNG E.V.

  公开号：US20210130582A1

  公开（公告）日：2021-05-06

  The present invention relates to the use of efficient phosphorous substances, in particular based on diphenylamine and heterocyclic diphenylamine derivatives as stabilizers for organic materials, in particular for plastic materials, against oxidative, thermal and/or actinic degradation. Te present invention additionally relates to an organic material that has been correspondingly stabilized as described above. The invention further relates to a method of stabilizing organic materials and to specific stabilizers.
• METHOD OF STABILIZING VIRGIN THERMOPLASTIC MATERIAL AND STABILIZED PLASTICS COMPOSITIONS, MOULDING COMPOUNDS AND MOULDINGS PRODUCED THEREFROM, STABILIZER COMPOSITIONS AND USES THEREOF
  申请人：FRAUNHOFER-GESELLSCHAFT ZUR FÖRDERUNG DER ANGEWANDTEN FORSCHUNG E. V.

  公开号：US20210388176A1

  公开（公告）日：2021-12-16

  The present invention relates to a method of stabilizing virgin thermoplastic material against oxidative, thermal and/or actinic degradation. In the method of the invention, at least one polyphenol and at least one alditol and/or cyclitol are introduced into a virgin thermoplastic material. The method of the invention can stabilize virgin thermoplastic material with high efficacy and in a very environmentally friendly and inexpensive manner against oxidative, thermal and/or actinic degradation. The present invention additionally also relates to correspondingly stabilized virgin thermoplastic material and to moulding compounds and mouldings produced therefrom. The present invention also further relates to stabilizer compositions and to the use thereof for stabilization of virgin thermoplastic material against oxidative, thermal and/or actinic degradation.