2-amino-4-butylamino-6-dibutylamino-1,3,5-triazine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2-amino-4-butylamino-6-dibutylamino-1,3,5-triazine
• 英文别名: 2-di-n-butylamino-4-n-butylamino-6-amino-1,3,5-triazine；N,N',N'-tributyl-[1,3,5]triazine-2,4,6-triamine；2-N,2-N,4-N-tributyl-1,3,5-triazine-2,4,6-triamine
• 化学式: C₁₅H₃₀N₆
• 分子量: 294.443
• InChiKey: QGZHVJWGMTYCRI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  21
• 可旋转键数：
  11
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  80
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  deethylterbuthylazine 、 二正丁胺 在 N,N-二异丙基乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 24.0h， 以80%的产率得到2-amino-4-butylamino-6-dibutylamino-1,3,5-triazine
  参考文献：
  名称：

  三聚氰胺-氰尿酸盐组件中线性和起皱胶带和环状玫瑰花结的热力学稳定性：模型描述

  摘要：

  在本文中，我们描述了通过协同氢键形成将 N,N-二取代三聚氰胺 1 和 N-取代氰尿酸或 5,5-二取代巴比妥酸衍生物 2 自组装成线性或起皱胶带和环状玫瑰花结的模型计算。模型描述考虑了所有可能的立体异构带结构，包括 2 到 8 种不同的成分（总共 270 种不同的物质）和一种环状六聚体花环结构。此外，包括八个空间参数 (R(12)-R(28))，代表组件内不同类型的空间相互作用。最重要的是，模型计算清楚地表明，带/花环比对直接影响花环结构内能的参数变化非常敏感。在这方面，已经表征了三个参数，即三聚氰胺和氰尿酸盐双分子缔合的基本平衡常数 K(0)、线性六聚体环化的平衡常数 K(r)/K(0) 和参数 R (12)-a(Z)b，代表相邻三聚氰胺和氰尿酸盐部分之间的吸引或排斥相互作用。例如，K(0) 从 100 增加到 10,000 M(-1)（[A](0) = [B](0) = 10 mM，K(r)

  DOI：

  10.1021/ja010664o

文献信息

• PROCESS FOR ALKYLATING TRIAZINE DERIVATIVE
  申请人：NISSAN CHEMICAL INDUSTRIES, LIMITED

  公开号：EP0760369A1

  公开（公告）日：1997-03-05

  The object of the present invention is to provide a method for producing substituted-1,3,5-triazine derivatives at high yield, in which at least one of carbon atoms in the ring thereof is substituted by a secondary amine group having at leat one of alkyl groups. The method of the present invention is a method for alkylation of 1,3,5-triazine derivatives, characterized by reacting 1,3,5-triazine derivatives (melamines, melamine derivatives, various kinds of guanaminde derivatives, etc.) which has at least one or more amino groups or mono-substituted amino groups on carbon atom of the ring thereof, with aldehydes or ketones alcohols in the presence of a catalyst of a metal of group VII and/or group VIII in the periodic table and a hydrogen-containing gas to alkylate said at least one of amino groups or mono-substituted amino groups. These derivatives are widely used as intermediates of fine chemicals such as agricultural chemicals, medications, dyestuffs, paints and the like and are widely used resin materials and as flame-retardant materials.

  本发明的目的是提供一种高产率生产取代的-1,3,5-三嗪衍生物的方法，在这种衍生物中，其环上至少有一个碳原子被至少有一个烷基的仲胺基取代。 本发明的方法是 1,3,5-三嗪衍生物的烷基化方法，其特征是将 1,3,5-三嗪衍生物（三聚氰胺、三聚氰胺衍生物、各种胍衍生物等）与至少具有一个或多个烷基的 1,3,5-三嗪衍生物（三聚氰胺、三聚氰胺衍生物、各种胍衍生物等）反应。其特征是：在元素周期表中第 VII 族和/或 VIII 族金属和含氢气体催化剂的存在下，将环的碳原子上至少有一个或多个氨基或单取代氨基的 1,3,5-三嗪衍生物（三聚氰胺、三聚氰胺衍生物、各种鸟苷酸衍生物等）与醛或酮醇反应，使上述至少一个氨基或单取代氨基烷基化。 这些衍生物被广泛用作精细化工产品的中间体，如农药、药物、染料、油漆等，也被广泛用作树脂材料和阻燃材料。
• Proton-conducting polymer
  申请人：Nippon Steel Chemical Co., Ltd.

  公开号：EP2562864A1

  公开（公告）日：2013-02-27

  The present invention provides a proton conducting polymer which provides proton conductivity without humidification and is suitable for electrochemical device materials such as solid electrolytes for fuel cells and electrolytes for batteries. The proton conducting compound is produced by polymerization of a salt of a melamine compound represented by the following equation (2) and a Bronsted acid: wherein, R1, R2, R3, R4, and R5 each is independently an alkyl group, an aryl group, a heterocyclic group, or hydrogen and at least one of them is an alkyl group, an aryl group, or a heterocyclic group; R2 and R3 or R4 and R5 may join together to form a heterocyclic structure; and the alkyl group, the aryl group, and the heterocyclic group each may have a substituent selected from the group of alkyl groups of 1 to 6 carbon atoms, aryl groups of 6 to 12 carbon atoms, heterocyclic groups, an amino group, alkylamino groups of 1 to 6 carbon atoms, a nitro group, a carboxyl group, acryl groups of 1 to 6 carbon atoms, acyloxy groups of 1 two 6 carbon atoms, a cyano group, alkylsulfonyl groups of 1 to 6 carbon atoms, alkylsulfonyloxy groups of 1 to 6 carbon atoms, a sulfoxide group, a sulfonic acid group, alkoxycarbonyl groups of 1 to 6 carbon atoms, aryloxycarbonyl groups of 6 to 12 carbon atoms, aryloxy groups of 6 to 12 carbon atoms, and alkynyl groups of 2 to 6 carbon atoms; R6 is hydrogen or an alkyl group and n is an integer equal to or larger than 1,

  本发明提供了一种质子传导聚合物，无需加湿即可提供质子传导性，适用于电化学装置材料，如燃料电池的固体电解质和电池的电解质。质子导电化合物是由下式（2）表示的三聚氰胺化合物的盐和勃朗斯特酸聚合而成： 其中，R1、R2、R3、R4 和 R5 各自独立地为烷基、芳基、杂环基或氢，且其中至少一个为烷基、芳基或杂环基；R2 和 R3 或 R4 和 R5 可连接在一起形成杂环结构；烷基、芳基和杂环基各自可具有一个取代基，该取代基可选自以下基团：1 至 6 个碳原子的烷基、6 至 12 个碳原子的芳基、杂环基、氨基、1 至 6 个碳原子的烷基氨基、硝基、羧基、1 至 6 个碳原子的丙烯基、1-6个碳原子的酰氧基、氰基、1-6个碳原子的烷磺酰基、1-6个碳原子的烷磺酰氧基、亚砜基、磺酸基、1-6个碳原子的烷氧羰基、6-12个碳原子的芳氧羰基、6-12个碳原子的芳氧基和 2-6个碳原子的炔基；R6 是氢或烷基，n 是等于或大于 1 的整数、
• Use of non-modified and modified inorganic particles having a layered structure as catalyst for synthesizing aminoplast-aldehyde precondensates and a method for synthesizing aminoplast-aldehyde precondensates
  申请人：Borealis Agrolinz Melamine GmbH

  公开号：EP2599824A1

  公开（公告）日：2013-06-05

  The present invention relates to the use of inorganic particles having a layered structure as catalyst for the synthesis of aminoplast-aldehyde precondensates, wherein the inorganic particles are either non-modified or modified with at least one amino compound, wherein the at least one amino compound comprises at least one aliphatic amino group, whereby octadecyldiethanolamine is exempted, at least one amide group and/or at least one aromatic amino group. The invention relates furthermore to a method using non-modified and/or modified inorganic particles having a layered structure for synthesising aminoplast-aldehyde precondensates, the precondensates obtained by such a method and their use.

  本发明涉及使用具有分层结构的无机颗粒作为合成氨原醛前缩合物的催化剂，其中所述无机颗粒为非改性或用至少一种氨基化合物改性，其中所述至少一种氨基化合物包括至少一种脂肪族氨基基团（十八烷基二乙醇胺除外）、至少一种酰胺基团和/或至少一种芳香族氨基基团。本发明还涉及一种使用具有分层结构的非改性和/或改性无机颗粒合成氨醛前缩合物的方法、通过这种方法获得的前缩合物及其用途。
• N-alkyl melamine formaldehyde crosslinking and curable compositions
  申请人：Brogan C. John

  公开号：US20050282994A1

  公开（公告）日：2005-12-22

  This invention relates to bis-N-alkyl melamine formaldehyde crosslinking composition or a blend of bis- and tris-N-alkyl melamine formaldehyde crosslinking composition. This invention also contemplates curable compositions comprising the bis-N-alkyl melamine formaldehyde composition and an active hydrogen-containing material and a curable composition comprising the blend of bis- and tris-N-alkyl melamine formaldehyde compounds and an active hydrogen-containing material.

  本发明涉及双-N-烷基三聚氰胺甲醛交联组合物或双-N-烷基和三-N-烷基三聚氰胺甲醛交联组合物的混合物。本发明还考虑了包含双-N-烷基三聚氰胺甲醛组合物和活性含氢材料的可固化组合物，以及包含双-N-烷基和三-N-烷基三聚氰胺甲醛混合物和活性含氢材料的可固化组合物。
• Melamine group-containing acrylates and/or methacrylates, polymerizable and curable composition thereof, molded article made of the polymerized and cured composition and resin molded article coated with the composition
  申请人：TEIJIN LIMITED

  公开号：EP0006206B1

  公开（公告）日：1982-11-24