metaphosphate(1-)

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 其他非金属有机物
• 英文名称: metaphosphate(1-)
• 英文别名: Phosphane;trihydrate
• 化学式: O₃P
• 分子量: 78.972
• InChiKey: MGGMTVYSPZCXTC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2.42
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  3
• 氢给体数：
  3
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  水 、 metaphosphate(1-) 以 gas 为溶剂， 生成 Phosphane;tetrahydrate
  参考文献：
  名称：

  Chemistry of PO−, PO2−, and PO3− in the gas phase

  摘要：

  Rate constants have been measured for reactions of the small oxyphosphorus anions PO−, PO2−, and PO3− with a selection of reactant neutrals at 300 K using a selected ion flow tube instrument. The PO− anion was the most reactive, abstracting an oxygen atom from O2, NO, CO2, and NO2 with rates below collisional. Of the neutrals studied, only NO2 transferred an O atom to PO2−, demonstrating that NO2 can provide a route from PO− to PO3− through PO2−. PO2− was found to react with WF6 through fast charge transfer, and with H2O by slow clustering. The only observed reaction found for the highly stable PO3− anion was slow clustering with H2O.

  DOI：

  10.1063/1.477015
• 作为产物：
  描述：

  sodium metaphposphate 以 水 为溶剂， 生成 sodium 、 metaphosphate(1-)
  参考文献：
  名称：

  Pascal, P., Bulletin de la Societe Chimique de France, 1923, vol. 33, p. 1613 - 1613

  摘要：

  DOI：

文献信息

• Pascal, P., Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1923, vol. 176, p. 1398 - 1398
  作者：Pascal, P.

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Na: MVol., 338, page 917 - 920
  作者：

  DOI：——

  日期：——
• Pascal, P., Bulletin de la Societe Chimique de France, 1923, vol. 33, p. 1613 - 1613
  作者：Pascal, P.

  DOI：——

  日期：——
• Chemistry of PO−, PO2−, and PO3− in the gas phase
  作者：Robert A. Morris、A. A. Viggiano

  DOI：10.1063/1.477015

  日期：1998.9.8

  Rate constants have been measured for reactions of the small oxyphosphorus anions PO−, PO2−, and PO3− with a selection of reactant neutrals at 300 K using a selected ion flow tube instrument. The PO− anion was the most reactive, abstracting an oxygen atom from O2, NO, CO2, and NO2 with rates below collisional. Of the neutrals studied, only NO2 transferred an O atom to PO2−, demonstrating that NO2 can provide a route from PO− to PO3− through PO2−. PO2− was found to react with WF6 through fast charge transfer, and with H2O by slow clustering. The only observed reaction found for the highly stable PO3− anion was slow clustering with H2O.