1-[N-(6-chloro-pyridin-3-ylmethyl)-N-methylamino]-1-methylamino-2-nitroethylene

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 1-[N-(6-chloro-pyridin-3-ylmethyl)-N-methylamino]-1-methylamino-2-nitroethylene
• 英文别名: 2-methylamino-2-[N-methyl-N-(6-chloro-pyridin-3-ylmethyl)amino]-1-nitroethylene；1-[N-(2-chloro-5-pyridylmethyl)-N-methylamino]-1-methylamino-2-nitroethylene；1-[N-(6-chloro-3-pyridylmethyl)-N-methylamino]-1-methylamino-2-nitroethylene；(E)-1-N'-[(6-chloropyridin-3-yl)methyl]-1-N,1-N'-dimethyl-2-nitroethene-1,1-diamine
• 化学式: C₁₀H₁₃ClN₄O₂
• 分子量: 256.692
• InChiKey: NXFSILLOHOWXSD-JXMROGBWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  74
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  1-[N-(6-chloro-pyridin-3-ylmethyl)-N-methylamino]-1-methylamino-2-nitroethylene 在 聚合甲醛 、 二甲胺 作用下， 以 乙腈 为溶剂， 生成 1-[N-(6-chloro-pyridin-3-ylmethyl)-N-methylamino]-3-dimethylamino-1-methylamino-2-nitro-propene
  参考文献：
  名称：

  Diaminoethylene compounds

  摘要：

  Diaminoethylene衍生物的化学式为：##STR1## 其中R.sup.1是可能被取代的杂环基团，R.sup.2、R.sup.3和R.sup.4是氢原子或可能被取代的碳氢基团，或者R.sup.3和R.sup.4与相邻的氮原子结合形成环状氨基团；R.sup.5是氢原子或可能被取代的碳氢基团或杂环基团；X是电子吸引基团；Y是羟基或取代羟基基团、氨基或取代氨基基团或巯基或取代巯基基团；n为0或1；或其盐，可用作杀虫剂。

  公开号：

  US05438065A1

文献信息

• [EN] COMPOUNDS USEFUL AS PESTICIDES<br/>[FR] COMPOSES UTILISES COMME PESTICIDES
  申请人：DOW AGROSCIENCES LLC

  公开号：WO2004058714A1

  公开（公告）日：2004-07-15

  Compounds useful to control pests are provided.

  提供用于控制害虫的化合物。
• Hydrazine compounds or their salts, processes for producing them and pesticides containing them
  申请人：ISHIHARA SANGYO KAISHA, LTD.

  公开号：EP0483647A1

  公开（公告）日：1992-05-06

  A hydrazine compound of the formula (I) or its salt: wherein A is a benzofuranyl group which may be substituted, a quinolinyl group which may be substituted, a benzothienyl group which may be substituted, a benzothiazolyl group which may be substituted, a thienothienyl group which may be substituted, a dihydrothienothienyl group which may be substituted, a dihydrocyclopentathienyl group which may substituted, a tetrahydrobenzothienyl group-which may be substituted, an indanyl group which may be substituted, or a hexahydroindanyl group which may be substituted, W is a hydrogen atom, a cyano group, -COCOOR', -S-N(R'')COOR' or -CH₂OCOR', wherein each of R' and R'' which are independent from each other, is an alkyl group or a cycloalkyl group, R is a halogen atom, an alkyl group which may be substituted by a halogen atom, an alkoxy group which may substituted by a halogen atom, an alkylthio group which may be substituted by a halogen atom, or a nitro group, n is an integer of from 0 to 5, provided that when n is 2 or more, the plurality of R may be the same or different.

  式 (I) 的肼化合物或其盐： 其中 A 是一个可被取代的苯并呋喃基、一个可被取代的喹啉基、一个可被取代的苯并噻吩基、一个可被取代的苯并噻唑基、一个可被取代的噻吩基、一个可被取代的二氢噻吩基、一个可被取代的二氢环噻吩基、一个可被取代的四氢苯并噻吩基、可被取代的二氢噻吩基、可被取代的二氢环戊噻吩基、可被取代的四氢苯并噻吩基、可被取代的茚基或可被取代的六氢茚基、W 是氢原子、氰基、-COCOOR'、-S-N(R'')COOR'或-CH₂OCOR'，其中 R'和 R''各自独立，是烷基或环烷基，R 是卤素原子、可被卤素原子取代的烷基、可被卤素原子取代的烷氧基、可被卤素原子取代的烷硫基或硝基，n 为 0 至 5 的整数，但当 n 为 2 或 2 以上时，多个 R 可以相同或不同。
• N-phenylcarbamate compound, process for preparing the same and biocidal composition for control of harmful organisms
  申请人：ISHIHARA SANGYO KAISHA, Ltd.

  公开号：EP0498396A2

  公开（公告）日：1992-08-12

  A novel N-phenylcarbamate compound or its salt where possible, which is useful as the active ingredient of a biocidal composition for control of harmful organisms, is represented by the following general formula (I): wherein R¹ is unsubstituted or substituted alkyl; R² is H, unsubstituted or substituted alkyl, alkenyl, alkynyl or cycloalkyl, or -COX¹ wherein X¹ is unsubstituted or substituted alkyl, alkenyl, alkynyl, cycloalkyl or alkoxy; Z is -CH₂S-, -SCH₂-, -CH₂O-, -OCH₂-, -CH₂CH₂-, -CH=CH-, -C≡C-, -CH₂SO-, -CH₂SO₂-, -CH₂SCH₂-, or -CH₂O-N=C(R⁴)-; R³ is unsubstituted or substituted phenyl, pyridyl, benzothiazolyl, benzoxazolyl, benzimidazolyl, imidazopyridyl, naphthyl, pyrimidinyl, thienyl, furyl, thiazolinyl, oxazolinyl, pyrazinyl, thiazolyl, oxazolyl, imidazolyl, pyrazolyl, quinolyl, indolyl, pyrrolyl, benzofuryl, benzothienyl, indanyl, tetrahydronaphthyl, dihydrobenzofuryl, dihydrobenzothienyl, benzoxazinyl, benzothiazinyl or benzoyl.

  一种新型 N-苯基氨基甲酸酯化合物或其可能的盐，可作为控制有害生物的杀生组合物的活性成分，由以下通式 (I) 表示： 其中 R¹ 是未取代或取代的烷基；R² 是 H、未取代或取代的烷基、烯基、炔基或环烷基，或 -COX¹ 其中 X¹ 是未取代或取代的烷基、烯基、炔基、环烷基或烷氧基；Z 是-CH₂S-、-SCH₂-、-CH₂O-、-OCH₂-、-CH₂CH₂-、-CH=CH-、-C≡C-、-CH₂SO-、-CH₂SO₂-、-CH₂SCH₂-或-CH₂O-N=C(R⁴)-；R³ 是未取代或取代的苯基、吡啶基、苯并噻唑基、苯并恶唑基、苯并咪唑基、咪唑并吡啶基、萘基、嘧啶基、噻吩基、呋喃基、噻唑啉基、噁唑啉基、吡嗪基、噻唑基、噁唑基、咪唑基、吡唑基、喹啉基、吲哚基、吡咯基、苯并呋喃基、苯并噻吩基、茚基、四氢萘基、二氢苯并呋喃基、二氢苯并噻吩基、苯并噁嗪基、苯并噻嗪基或苯甲酰。
• Hydrazone compounds, processes for their production, intermediates useful for their production and pesticidal compositions containing them
  申请人：ISHIHARA SANGYO KAISHA, LTD.

  公开号：EP0500111A2

  公开（公告）日：1992-08-26

  The present invention relates to a hydrazone compound of the formula (I) or its salt, a process for its preparation, an intermediate of the formula (11-5), a pesticidal composition containing said hydrazone compound or its salt as the active ingredient, and a pesticidal method of applying an effective amount thereof:

  本发明涉及一种式（I）的腙化合物或其盐、其制备工艺、式（11-5）的中间体、含有所述腙化合物或其盐作为活性成分的杀虫组合物，以及施用有效量的杀虫方法：
• Synergistic insecticidal compositions
  申请人：NIHON BAYER AGROCHEM K.K.

  公开号：EP0617890A1

  公开（公告）日：1994-10-05

  Novel insecticidal compositions of the compounds of the formula. wherein R represents hydrogen atom, acyl, alkyl or an optionally substitutable heteroarylalkyl, A represents hydrogen atom, alkyl, or a divalent group connected to B, B represents alkyl, -S-R, or a divalent group or atom connected to A, wherein R has the same meaning as mentioned above, Y represents = N- or wherein T1 represents hydrogen atom or an optionally substitutable alkyl, and X represents an electron attractive group, and methylenedioxybenzene derivatives.

  式化合物的新型杀虫组合物，其中R代表氢原子、酰基、烷基或可任选取代的杂芳基烷基，A代表氢原子、烷基或与B相连的二价基团，B代表烷基、-S-R或与A相连的二价基团或原子，其中R的含义与上述相同，Y代表＝N-或其中T1代表氢原子或可任选取代的烷基，X代表引电子基团，以及亚甲二氧基苯衍生物。