二烯丙基二乙基氯化铵 | 13107-00-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 二烯丙基二乙基氯化铵
• 英文名称: N,N-diethyl-N,N-diallylammonium chloride
• 英文别名: diallyldiethylammonium chloride；diethyl-bis(prop-2-enyl)azanium;chloride
• CAS: 13107-00-1
• 化学式: C₁₀H₂₀N*Cl
• 分子量: 189.728
• InChiKey: IOMDIVZAGXCCAC-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.78
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  苯胺 、 二烯丙基二乙基氯化铵 在 tris(triphenylphosphine)ruthenium(II) chloride 、 tin(ll) chloride 作用下， 以 1,4-二氧六环 、 水 为溶剂， 反应 20.0h， 以37%的产率得到2-乙基-3-甲基-喹啉
  参考文献：
  名称：

  在水介质中通过胺交换反应，由钌催化苯胺和氯化铝氯化铵合成喹啉

  摘要：

  在催化量的RuCl 2（PPh 3）3和SnCl 2 ·2H 2 O的存在下，苯胺在水性介质（H 2 O-二恶烷）中与烯丙基氯化铵反应，以中等至良好的收率得到相应的喹啉。SnCl 2 ·2H 2 O的存在对于喹啉的有效形成是必需的，并且针对该催化过程提出了涉及苯胺和烯丙基氯化铵之间形成亚胺的胺交换反应的反应路径。

  DOI：

  10.1016/s0040-4020(00)00694-3

文献信息

• [EN] FLUORESCENT POLYMERS FOR WATER TREATMENT<br/>[FR] POLYMÈRES FLUORESCENTS POUR LE TRAITEMENT DE L'EAU
  申请人：ECOLAB USA INC

  公开号：WO2016149471A1

  公开（公告）日：2016-09-22

  Novel fluorophores and their use as fluorescent tags for polymers used in wastewater treatment. The fluorophores are quaternary amine salts that can be used to synthesize fluorescent tagged polymers that are stable at varying pH, have significant water solubility, and may be fluorescent at wavelengths greater than 550 nm. The fluorophores readily undergo polymerization with vinylic monomers to form fluorescent tagged polymers with excellent incorporation of fluorophore into the polymer framework. The fluorescent tagged polymers are useful to monitor and optionally dose industrial wastewater.

  新型荧光团和它们作为用于污水处理中的聚合物的荧光标记物的使用。这些荧光团是季铵盐，可用于合成稳定在不同pH下、具有显著水溶性的荧光标记聚合物，并且可能在大于550纳米的波长下发光。这些荧光团容易与乙烯基单体发生聚合反应，形成具有优秀荧光团嵌入聚合物骨架的荧光标记聚合物。这些荧光标记聚合物可用于监测和必要时给工业废水投加药剂。
• CROSSLINKING AGENT, CROSSLINKED POLYMER, AND USES THEREOF
  申请人：Tanaka Shinichi

  公开号：US20100209723A1

  公开（公告）日：2010-08-19

  There is provided a novel crosslinking agent for use in crosslinked polymer fabrication, specifically a crosslinking agent containing at least one compound selected from glyoxylate and a glyoxylic acid ester derivative represented by the following general formula (1): wherein R 1 and R 2 each independently represents an alkyl group having 1 to 10 carbon atoms and R 3 represents a hydrogen atom or an alkyl group having 1 to 10 carbon atoms.

  提供了一种新型交联剂，用于交联聚合物的制备，具体来说，这种交联剂包含至少一种从乙酰乙酸酯和以下通用公式（1）表示的乙酰乙酸酯衍生物中选择的化合物：其中R1和R2各自独立表示具有1至10个碳原子的烷基基团，R3表示氢原子或具有1至10个碳原子的烷基基团。
• [EN] PREPARATION OF COMPOUNDS HAVING PESTICIDAL ACTIVITY<br/>[FR] PRÉPARATION DE COMPOSÉS AYANT UNE ACTIVITÉ PESTICIDE
  申请人：CORTEVA AGRISCIENCE LLC

  公开号：WO2021231196A1

  公开（公告）日：2021-11-18

  A method of forming a compound of formula (I) as described herein is provided. Some embodiments of the compound of formula (I) are known to have herbicidal activity. The method comprises combining a compound of formula (II) and a compound of formula (IIIa) or (IIIb), each as described herein, or a salt or ester thereof in a liquid mixture comprising the compounds of formula (II), formula (IIIa) or (IIIb), water, a non-aqueous solvent, a surfactant, a catalyst, and a ligand at certain temperature, pH, and HLB ranges to form a chemical reaction product mixture comprising the compound of formula (I) and by-products.

  本文提供了一种制备式(I)化合物的方法。其中，式(I)化合物的某些实施形式已知具有除草活性。该方法包括在液体混合物中，将式(II)化合物和式(IIIa)或(IIIb)化合物的盐或酯，每个化合物的描述均在本文中给出，与水、非水溶剂、表面活性剂、催化剂和配体在特定的温度、pH和HLB范围内混合，形成化学反应产物混合物，其中包括式(I)化合物和副产物。
• Composition comprising at least one conductive polymer and at least one film-forming polymer, and process for use thereof
  申请人：Rollat-Corvol Isabelle

  公开号：US20050048022A1

  公开（公告）日：2005-03-03

  A composition comprising, in a cosmetically acceptable medium, (a) at least one film-forming polymer and (b) at least one conductive polymer, for example, comprising at least one repeating unit chosen from aniline, pyrrole, thiophene, bisthiophene, furan, para-phenylene sulfide, vinylene para-phenylene, indole, aromatic amide, aromatic hydrazide, aromatic azomethine, and aromatic esters. A process using such a composition, and also to the use of this composition as a hair product base for shaping and/or holding the hairstyle. Also the use of this composition to give keratin fibers at least one optical effect.

  一种组合物，包括至少一种成膜聚合物和至少一种导电聚合物，在化妆中可接受的介质中，例如，包括至少一种由苯胺，吡咯，噻吩，双噻吩，呋喃，对苯二硫化物，乙烯基对苯二甲酸酯，吲哚，芳香酰胺，芳香酰肼，芳香偶氮甲烷和芳香酯中选择的至少一种重复单元的导电聚合物。使用这种组合物的过程，以及将此组合物用作发型产品基础以塑造和/或保持发型的用途。此外，使用这种组合物为角蛋白纤维提供至少一种光学效果的用途。
• Papermaking chemical, method for manufacturing same, and paper containing same
  申请人：Kiyosada Toshitsugu

  公开号：US20050272889A1

  公开（公告）日：2005-12-08

  A novel (meth)acrylamide polymer capable of forming a papermaking chemical exhibiting an excellent paper strengthening effect, drainage improvement effect, retention improvement effect, plybond strength enhancing effect, surface strength enhancing effect, and sizing improvement effect in acid, neutral, or alkaline papermaking systems, as well as a method for manufacturing this polymer, and paper that makes use of this polymer and has excellent bursting strength, internal bond strength, and other such properties is provided. This is a (meth)acrylamide polymer produced by polymerizing a monomer (a) expressed by the following general formula 1, the following monomer (b), and the following monomer (c): (a) general formula 1: (b) a (meth)acrylamide; (c) an ionic monomer other than monomer (a) expressed by general formula 1 above

  提供了一种新型（甲基）丙烯酰胺聚合物，能够形成一种造纸化学品，具有优异的造纸强化效果、排水改善效果、保留改善效果、层压强度增强效果、表面强度增强效果和尺寸稳定性改善效果，适用于酸性、中性或碱性造纸系统，以及制造该聚合物的方法和使用该聚合物的纸张，具有优异的爆裂强度、内部粘合强度和其他类似性能。该聚合物是通过聚合以下通式1所表示的单体（a）、以下单体（b）和以下单体（c）制备的：（a）通式1：（b）（甲基）丙烯酰胺；（c）除通式1所述的单体（a）之外的离子单体。