sodium phenyl arsonite

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: sodium phenyl arsonite
• 英文别名: sodium;dioxido(phenyl)arsane
• 化学式: C₆H₅AsO₂*2Na
• 分子量: 230.006
• InChiKey: CKVCIMCHQSUDMD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -4.89
• 重原子数：
  10.0
• 可旋转键数：
  1.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  46.12
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  sodium phenyl arsonite 、 氯乙酸 在 sodium hydroxide 作用下， 以 水 为溶剂， 生成
  参考文献：
  名称：

  Kinetics of reaction of sodium phenylarsonite with chloroacetic acid in aqueous alkaline medium

  摘要：

  The reaction order with respect to its components, the rate constants, and thermodynamic parameters of the reaction of sodium phenylarsonite with chloroacetic acid in aqueous alkaline medium were elucidated. The effect of substituents at the arsenic atom on the nucleophilic reactivity of arsenite ion in the Meyer reaction is discussed.

  DOI：

  10.1134/s1070363211010105
• 作为产物：
  描述：

  氧化苯胂 在 sodium hydroxide 作用下， 以 水 为溶剂， 反应 0.5h， 生成 sodium phenyl arsonite
  参考文献：
  名称：

  Kinetics of reaction of sodium phenylarsonite with chloroacetic acid in aqueous alkaline medium

  摘要：

  The reaction order with respect to its components, the rate constants, and thermodynamic parameters of the reaction of sodium phenylarsonite with chloroacetic acid in aqueous alkaline medium were elucidated. The effect of substituents at the arsenic atom on the nucleophilic reactivity of arsenite ion in the Meyer reaction is discussed.

  DOI：

  10.1134/s1070363211010105

文献信息

• Kinetics of reaction of sodium phenylarsonite with chloroacetic acid in aqueous alkaline medium
  作者：R. R. Rakhmatullin、V. I. Gavrilov

  DOI：10.1134/s1070363211010105

  日期：2011.1

  The reaction order with respect to its components, the rate constants, and thermodynamic parameters of the reaction of sodium phenylarsonite with chloroacetic acid in aqueous alkaline medium were elucidated. The effect of substituents at the arsenic atom on the nucleophilic reactivity of arsenite ion in the Meyer reaction is discussed.