2-(N-methyl-N-3'-pyridylamino)pyridine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2-(N-methyl-N-3'-pyridylamino)pyridine
• 英文别名: N-methyl-N-pyridin-3-ylpyridin-2-amine
• 化学式: C₁₁H₁₁N₃
• 分子量: 185.228
• InChiKey: SSGQFCAGCUFQKZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  29
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  3-溴吡啶 、 2-(甲氨基)吡啶 在 tris(dibenzylideneacetone)dipalladium (0) caesium carbonate 、 4,5-双二苯基膦-9,9-二甲基氧杂蒽 作用下， 以 1,4-二氧六环 为溶剂， 反应 20.0h， 以91%的产率得到2-(N-methyl-N-3'-pyridylamino)pyridine
  参考文献：
  名称：

  Pd-Catalyzed N-Arylation of Heteroarylamines

  摘要：

  [GRAPHICS]The palladium-catalyzed N-(hetero)arylation of a number of heteroarylamines including 2-aminopyridines, 2-aminothiazoles, and their analogues has been realized using Xantphos as the ligand. Weak bases such as CS2CO3, Na2CO3, and K3PO4 were used in most cases to allow for the introduction of functional groups. Choice of the base and solvent was critical for the success of these reactions.

  DOI：

  10.1021/ol0265923

文献信息

• Novel organic electroluminescent compounds and organic electrouminescent device using the same
  申请人：EUM SUNG JIN

  公开号：US20100096982A1

  公开（公告）日：2010-04-22

  Provided are novel organic electroluminescent compounds and organic electroluminescent devices and organic solar cells comprising the same. Specifically, the organic electroluminescent compounds according to the invention are characterized in that they are represented by Chemical Formula (1): wherein, R 1 through R 10 cannot be hydrogen all at the same time. The organic electroluminescent compounds according to the invention exhibit high luminous efficiency and excellent color purity and life property of material, so that an OLED having very good operation life can be manufactured therefrom.
• Pd-Catalyzed <i>N</i>-Arylation of Heteroarylamines
  作者：Jingjun Yin、Matthew M. Zhao、Mark A. Huffman、James M. McNamara

  DOI：10.1021/ol0265923

  日期：2002.10.1

  [GRAPHICS]The palladium-catalyzed N-(hetero)arylation of a number of heteroarylamines including 2-aminopyridines, 2-aminothiazoles, and their analogues has been realized using Xantphos as the ligand. Weak bases such as CS2CO3, Na2CO3, and K3PO4 were used in most cases to allow for the introduction of functional groups. Choice of the base and solvent was critical for the success of these reactions.