5-bromo-2-(1-methylnaphthalen-4-yl)pyridine

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 5-bromo-2-(1-methylnaphthalen-4-yl)pyridine
• 英文别名: 5-Bromo-2-(4-methylnaphthalen-1-yl)pyridine
• 化学式: C₁₆H₁₂BrN
• 分子量: 298.182
• InChiKey: URESTNWSJUMGBG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  18
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1-溴-4-甲基萘 在 四(三苯基膦)钯 正丁基锂 、 sodium carbonate 作用下， 以 四氢呋喃 、 乙醇 、 正己烷 、 水 、 甲苯 为溶剂， 反应 24.5h， 生成 5-bromo-2-(1-methylnaphthalen-4-yl)pyridine
  参考文献：
  名称：

  Potential Solution Processible Phosphorescent Iridium Complexes toward Applications in Doped Light-Emitting Diodes:  Rapid Syntheses and Optical and Morphological Characterizations

  摘要：

  A series of carbazol-9-yl end-capped red-emitting heteroleptic iridium complexes was readily synthesized using post Suzuki coupling. The appealing solubility, photoluminescent characteristics, and morphological stability enabled the current heteroleptic iridium complexes to be highly desirable phosphorescent dopant emitters in doped light-emitting diodes for the purpose of resisting molecular aggregations in the doped emitting layers.

  DOI：

  10.1021/jo060840h

文献信息

• Potential Solution Processible Phosphorescent Iridium Complexes toward Applications in Doped Light-Emitting Diodes:  Rapid Syntheses and Optical and Morphological Characterizations
  作者：Yi-Heng Sun、Xu-Hui Zhu、Zhao Chen、Yong Zhang、Yong Cao

  DOI：10.1021/jo060840h

  日期：2006.8.1

  A series of carbazol-9-yl end-capped red-emitting heteroleptic iridium complexes was readily synthesized using post Suzuki coupling. The appealing solubility, photoluminescent characteristics, and morphological stability enabled the current heteroleptic iridium complexes to be highly desirable phosphorescent dopant emitters in doped light-emitting diodes for the purpose of resisting molecular aggregations in the doped emitting layers.