N,N-dipropyloctan-3-amine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N-dipropyloctan-3-amine
• 化学式: C₁₄H₃₁N
• 分子量: 213.407
• InChiKey: VUSOFENNYPUGHS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  15
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  三正丙胺 在 rose bengal 作用下， 以 四氢呋喃 、 乙腈 为溶剂， 反应 6.0h， 生成 N,N-dipropyloctan-3-amine
  参考文献：
  名称：

  可见光对叔胺进行无金属有氧光致氰化的高活性体系：四甲基萘草酮和Crispine A的合成应用

  摘要：

  报道了一种高效的无金属催化体系，用于可见光下叔胺的有氧光致氰化。与纯氧相比，使用空气作为终端氧化剂可提高安全性，所使用的紧凑型荧光灯（CFL）光源非常经济，并且不需要卤化溶剂。该系统不仅证明对多种三烷基胺，药物和生物碱有效，而且显着还使有机染料有史以来最低的催化剂负载量（0.00001 mol％或0.1 ppm）。对获得的α-氨基腈进行了Bruylants反应和C-烷基化/脱氰，以证明复杂分子的后功能化。

  DOI：

  10.1002/chem.201504845

文献信息

• [EN] PRESSURE SENSITIVE ADHESIVES BASED ON CARBOXYLIC ACIDS AND EPOXIDES<br/>[FR] ADHÉSIFS SENSIBLES À LA PRESSION À BASE D'ACIDES CARBOXYLIQUES ET D'ÉPOXYDES
  申请人：OREGON STATE

  公开号：WO2013086004A1

  公开（公告）日：2013-06-13

  A method for making a pressure sensitive adhesive comprising: (a) reacting (i) at least one dibasic acid or anhydride thereof with (ii) at least one epoxide having at least two epoxy groups, one diol or polyol, or one diamine at a stoichiometric molar excess of reactive carboxylic acid groups relative reactive epoxy groups, hydroxyl groups or amine groups to produce a thermoplastic prepolymer or oligomer capped with a carboxylic acid group at both prepolymer or oligomer chain ends, or a thermoplastic branched prepolymer or oligomer with at least two of the prepolymer or oligomer branches and chain ends capped with a carboxylic acid group; and (b) curing the resulting carboxylic acid-capped prepolymer or oligomer with at least one polyfunctional epoxy to produce a pressure sensitive adhesive, wherein the polyfunctional epoxy is not an epoxidized vegetable oil. A method for making a pressure sensitive adhesive comprising: (a) reacting at least one dibasic acid or anhydride thereof with at least one epoxide having at least two epoxy or oxirane groups at a stoichiometric molar excess of reactive epoxy or oxirane groups relative reactive carboxylic acid groups to produce a thermoplastic prepolymer or oligomer capped with an epoxy or an oxirane group at both prepolymer or oligomer chain ends, or a thermoplastic branched prepolymer or oligomer with at least two of the prepolymer or oligomer branches and chain ends capped with an epoxy or oxirane group; and (b) (i) curing the resulting epoxy-capped prepolymer or oligomer with at least one polybasic acid, or (ii) thermally curing the resulting epoxy-capped prepolymer or oligomer, to produce a pressure sensitive adhesive.