二甲胺-¹⁵N | 2876-06-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 二甲胺-¹⁵N
• 英文名称: dimethylamine-(15)N
• 英文别名: Dimethylamin-(15)N；15N-dimethylamine；15N-Dimethylamin；(15)NH(CH3)2；dimethyl-[¹⁵N]amine；15>-Dimethylamin；Dimethylamine-15N, 98 atom % 15N；N-methylmethan(15N)amine
• CAS: 2876-06-4
• 化学式: C₂H₇N
• 分子量: 46.0776
• InChiKey: ROSDSFDQCJNGOL-LBPDFUHNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.2
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  二甲胺-¹⁵N 在 氨 、 三氯氧磷 作用下， 以 四氢呋喃 为溶剂， 以49%的产率得到hexamethylphosphoramide-15N3
  参考文献：
  名称：

  Reduction of an Hexamethylphosphoramide Degradation Product: A Diazabutadiene

  摘要：

  Alkali metal over-reduction of an electron acceptor in the presence of a hydrogen atom donor, In hexamethylphosphoramide (HMPA), results in a radical that is not simply the anion radical of the acceptor. This new species exhibits an enigmatic EPR pattern. Using N-15 and H-2 labeling studies, the "HMPA degradation product" was found to be the anion radical of N,N'-dimethyl-1,4-diazabutadiene. DFT calculations support this assignment and a mechanism for its formation.

  DOI：

  10.1021/ol901798s

文献信息

• Preparations, properties, and vibrational spectra of some (dimethylamino)halogenosilanes
  作者：David G. Anderson、Janet Armstrong、Stephen Cradock

  DOI：10.1039/dt9870003029

  日期：——

  The vibrational spectra of the three (amino)monohalogenosilanes show dramitic changes on solidification, but those of the (amino)dichlorosilane are very similar in all three phases. These differences are discussed in the light of the formation of dimers in the crystalline solid of SiH2Cl(NMe2), and the presence of discrete monomers in the crystal of SiHCl2(NMe2). The n.m.r. spectra of the compounds

  我们已经制备并表征了新化合物SiH 2 Cl（NMe 2），SiH 2 Br（NMe 2），SiH 2 I（NMe 2）和SiHCl 2（NMe 2）。三种（氨基）单卤代硅烷的振动光谱显示出固化时的剧烈变化，但（氨基）二氯硅烷的振动光谱在所有三个阶段中都非常相似。根据SiH 2 Cl（NMe 2）晶体固体中二聚体的形成以及SiHCl 2（NMe 2）晶体中离散单体的存在，对这些差异进行了讨论。）。报道并简要讨论了该化合物以及单氟硅烷SiH 2 F（NMe 2）的nmr光谱。
• Structure of the dimethylamine-sulfur dioxide complex
  作者：Jung Jin Oh、Kurt W. Hillig、Robert L. Kuczkowski

  DOI：10.1021/j100172a022

  日期：1991.9

  The microwave spectrum of the charge-transfer complex between dimethylamine and sulfur dioxide was studied with a pulsed molecular beam Fourier transform microwave spectrometer. The rotational constants (in MHz) of (CH3)2NH.SO2 are A = 4445.495 (3), B = 2063.031 (1), and C = 1752.470 (1). In addition to the normal isotopic form, the rotational spectra of the (CH3)2NH.34SO2, (CH3)2(15)NH.SO2, (CH3)2ND.SO2, and two (CH3)2NH.SO18O isotopic species were assigned. Stark effect measurements gave electric dipole components of mu-a = 4.025 (1), mu-c = 1.747 (2), and mu-total = 4.388 (1) D. The structure of this complex lacks any symmetry plane. The nitrogen lone pair points toward the S atom, nearly perpendicular to the plane of the sulfur dioxide, and one methyl group staggers the oxygen atoms. The nitrogen-to-sulfur distance of 2.34 (3) angstrom is about 0.08 angstrom longer than in the trimethylamine-SO2 complex which correlates with the relative strength of the complexes. From the dipole moment and the nitrogen nuclear quadrupole coupling constants, an upper limit is estimated for electron transfer from the nitrogen to the sulfur atom of 0.25 electron. Ab initio calculations also conclude that a methyl group staggers the two oxygens of SO2.
• Preparation, characterization, and reactions of the first parent acetylene Fischer carbene complexes
  作者：Annette Rahm、William D. Wulff、Arnold L. Rheingold

  DOI：10.1021/om00027a002

  日期：1993.3

  The parent acetylenic Fischer carbene complexes of the type 2, (CO)5M=C(NMe2)C=CH, are isolated and characterized as both chromium (2a) and tungsten(2b) derivatives. Their Diels-Alder and Michael addition reactions are described, as well as the deprotonation of their acetylenic hydrogens.
• 1H, 13C and 199Hg NMR characteristics of new amine-mercuric chloride complexes
  作者：Salim S. Al-Showiman

  DOI：10.1016/s0020-1693(00)83918-3

  日期：1988.1
• Stereochemical studies with aminophosphines and related compounds having the 7-phosphanorbornene structure
  作者：Jerzy Szewczyk、Louis D. Quin

  DOI：10.1021/jo00383a003

  日期：1987.4