2-(1,1,2,3,3,3-Hexafluoropropan-2-yl)-1,3-dioxolane

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氧戊环
• 英文名称: 2-(1,1,2,3,3,3-Hexafluoropropan-2-yl)-1,3-dioxolane
• 英文别名: 4-(1,1,2,3,3,3-Hexafluoropropyl)-1,3-dioxolane；4-(1,1,2,3,3,3-hexafluoropropyl)-1,3-dioxolane
• 化学式: C₆H₆F₆O₂
• 分子量: 224.103
• InChiKey: BUDYICKXYOODAH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  2,2-二甲基-1,3-二氧环戊烷 、 、 六氟丙烯 反应 16.0h， 以to afford 4-(1,1,2,3,3,3-hexafluoropropyl)-1,3-dioxolane (boiling point (b.p.) of 144° C.)的产率得到2-(1,1,2,3,3,3-Hexafluoropropan-2-yl)-1,3-dioxolane
  参考文献：
  名称：

  FLUORINATED COMPOUNDS FOR USE IN LITHIUM BATTERY ELECTROLYTES

  摘要：

  提供氟代环状和非环状碳酸酯溶剂组合物，例如各种氟代1,3-二氧兰-2-酮化合物和氟代1,3-二氧杂环-2-酮化合物，它们可作为锂离子电池的电解质溶剂。

  公开号：

  US20130224605A1

文献信息

• Fluorinated compounds for use in lithium battery electrolytes
  申请人：Lamanna William M.

  公开号：US08435679B2

  公开（公告）日：2013-05-07

  Provide are fluorinated cyclic and acyclic carbonate solvent compositions such as various fluorine substituted 1,3-dioxolane-2-one compounds and fluorine substituted 1,3-dioxane-2-one compounds, which are useful as electrolyte solvents for lithium ion batteries.

  提供的是氟代环状和非环状碳酸酯溶剂组合物，如各种氟代1,3-二氧兰-2-酮化合物和氟代1,3-二氧杂环-2-酮化合物，它们可用作锂离子电池的电解质溶剂。
• Radical addition reactions of fluorinated species. Part 7. Highly selective two-step synthesis of 1-(polyfluoroalkyl)ethane-1,2-diols; regioselectivity of the additions of methylated 1,3-dioxolanes to perfluoroolefins
  作者：Vladimı́r Cı́rkva、Oldrich Paleta

  DOI：10.1016/s0022-1139(98)00356-x

  日期：1999.4

  The two-step synthesis of the diols is based on the radical addition of 2,2-dimethyl-1,3-dioxolane (1), a protected ethane-1,2-diol, to perfluoroalk-1-enes R-F-CF=CF2 (RF=CF3, C9F19; 2, 3) and perfluoro[trifluorovinyl (poly)ethers] RFO-CF=CF2 (R-F=C3F7, C3F7O[CF(CF3)CF2], CF3(OCF2CF2)(4); 4-6) with preparative yields above 90% in each step. The additions were initiated photochemically or by dibenzoyl peroxide and were completely chemoselective and almost completely regioselective. 4-Fluoroalkylated dioxolanes obtained (7-11) were deprotected by acid methanolysis to afford 1-polyfluoroalkylethane-1,2-diols (12-16). 1,3-Dioxolane (27) or 2,2,4-trimethyl-1, 3-dioxolane (30) reacted at two centers to yield regioisomeric mixtures of fluoroalkylated dioxolanes. The factors influencing fluoroolefin and dioxolane regioselectivity are discussed. (C) 1999 Elsevier Science S.A. All rights reserved.
• US8435679B2
  申请人：——

  公开号：US8435679B2

  公开（公告）日：2013-05-07
• US9406977B2
  申请人：——

  公开号：US9406977B2

  公开（公告）日：2016-08-02
• [EN] FLUORINATED COMPOUNDS FOR USE IN LITHIUM BATTERY ELECTROLYTES<br/>[FR] COMPOSÉS FLUORÉS POUR UNE UTILISATION DANS DES ÉLECTROLYTES DE BATTERIE LITHIUM
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2008079670A1

  公开（公告）日：2008-07-03

  [EN] Provide are fluorinated cyclic and acyclic carbonate solvent compositions such as various fluorine substituted 1,3-dioxolane-2-one compounds and fluorine substituted 1,3-dioxane-2-one compounds, which are useful as electrolyte solvents for lithium ion batteries.
  [FR] L'invention concerne des compositions de solvant de type carbonate fluoré cyclique et acyclique telles que divers composés 1,3-dioxolane-2-one substitués par un atome de fluor et composés 1,3-dioxane-2-one substitués par un atome de fluor qui sont utiles comme solvants électrolytiques pour des batteries lithium ion.