ethylmethoxysilane

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: ethylmethoxysilane
• 英文别名: Ethyl(methoxy)silane；ethyl(methoxy)silane
• 化学式: C₃H₁₀OSi
• 分子量: 90.1973
• InChiKey: OUHONEIDEVTEIG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.15
• 重原子数：
  5
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  甲醇 、 diethylsilicenium ion 以 环己烷 为溶剂， 20.0 ℃ 、1.33 kPa 条件下， 反应 1440.0h， 生成 三乙基硅烷 、 dimethylmethoxysilane 、 diethylmethoxysilane 、 ethylmethoxysilane
  参考文献：
  名称：

  Radiochemical study of the gas phase reaction of nucleogenic diethylsilylium ions with methanol and butanol

  摘要：

  The gas phase ion-molecule reactions between alcohols (methanol and n-butanol) and nucleogenic diethylsilylium ions generated by the beta-decay of the tritiated diethylsilane were studied by the radiochromatographic method. Among the labelled neutral products of the silylation of alcohols diethylsilylalkoxysilanes exhibit the major yield. Diethyl-butoxysilane contains not only n-butyl groups as in the substrate (21%), but also small amounts of s-butyl (5%) and t-butyl (7%) groups. In other alkoxysilanes the diethylsilyl group of the nascent nucleogenic cation is rearranged and isomerized. Products with the similar distribution of the silylium group isomers were observed earlier in the reaction of benzene, however the yield of the products with rearranged silylium groups was substantially greater for benzene. This difference in the yield of the products with rearranged sitylium groups between benzene and alcohols is rationalized taking into account the more acidic character of the proton in the adduct oxonium ions. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01625-x

文献信息

• Radiochemical study of the gas phase reaction of nucleogenic diethylsilylium ions with methanol and butanol
  作者：T.A. Kochina、D.V. Vrazhnov、I.S. Ignatyev

  DOI：10.1016/s0022-328x(02)01625-x

  日期：2002.8

  The gas phase ion-molecule reactions between alcohols (methanol and n-butanol) and nucleogenic diethylsilylium ions generated by the beta-decay of the tritiated diethylsilane were studied by the radiochromatographic method. Among the labelled neutral products of the silylation of alcohols diethylsilylalkoxysilanes exhibit the major yield. Diethyl-butoxysilane contains not only n-butyl groups as in the substrate (21%), but also small amounts of s-butyl (5%) and t-butyl (7%) groups. In other alkoxysilanes the diethylsilyl group of the nascent nucleogenic cation is rearranged and isomerized. Products with the similar distribution of the silylium group isomers were observed earlier in the reaction of benzene, however the yield of the products with rearranged silylium groups was substantially greater for benzene. This difference in the yield of the products with rearranged sitylium groups between benzene and alcohols is rationalized taking into account the more acidic character of the proton in the adduct oxonium ions. (C) 2002 Elsevier Science B.V. All rights reserved.