undecachloro-cyclohexane

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: undecachloro-cyclohexane
• 英文别名: Undecachlor-cyclohexan；Undecachlorocyclohexane；1,1,2,2,3,3,4,4,5,5,6-undecachlorocyclohexane
• 化学式: C₆HCl₁₁
• 分子量: 463.057
• InChiKey: BRGXLAZKABKITL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  undecachloro-cyclohexane 、 alkaline earth salt of/the/ methylsulfuric acid 生成 五氯苯
  参考文献：
  名称：

  van der Linden, Recueil des Travaux Chimiques des Pays-Bas, 1938, vol. 57, p. 217,222

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 氯 作用下， 生成 undecachloro-cyclohexane
  参考文献：
  名称：

  van der Linden, Recueil des Travaux Chimiques des Pays-Bas, 1938, vol. 57, p. 217,222

  摘要：

  DOI：

文献信息

• Acid- and radical-generating agent and method for generating acid and radical
  申请人：FUJIFILM Wako Pure Chemical Corporation

  公开号：US10451967B2

  公开（公告）日：2019-10-22

  It is a subject of the present invention to provide an acid- and radical-generating agent which has high sensitivity to an active energy ray having a wavelength of around 300 to 450 nm, and can exert both high acid-generating performance and high radical-generating performance, and has heat resistance; and a method for generating an acid and a radical. The present invention relates to a compound represented by the general formula (A); an acid- and radical-generating agent comprising the compound; and a method for generating an acid and a radical: wherein n pieces of R1 each independently represent an alkyl group, which may have a specific functional group in the chain, or in which a hydrogen atom may be substituted by a halogen atom; an alkoxy group, in which a hydrogen atom may be substituted by a halogen atom; an aryl group or an aryloxy group, in which a hydrogen atom may be substituted by a halogen atom, an alkyl group or a haloalkyl group; or an arylalkyl group or an arylalkyloxy group, in which a hydrogen atom may be substituted by a halogen atom, an alkyl group or a haloalkyl group; n pieces of R2 and R3 each independently represent a hydrogen atom, an alkyl group or an alkoxycarbonyl group; R4 to R7 each independently represent a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an alkenyl group, an aryl group, an alkoxycarbonyl group, a dialkylamino group or a nitro group; Y represents an oxygen atom, a sulfur atom, or a carbonyl group; n pieces of Z each independently represent a sulfonyl group or an alkoxyphosphoryl group; n represents 1 or 2.

  本发明的一个目的是提供一种对波长约为300至450纳米的活性能量射线具有高灵敏度的酸和自由基生成剂，能够发挥高酸生成性能和高自由基生成性能，并具有耐热性；以及一种生成酸和自由基的方法。本发明涉及一种由通式（A）表示的化合物；包括该化合物的酸和自由基生成剂；以及生成酸和自由基的方法：其中n个R1分别独立表示一种烷基基团，该烷基基团可能在链中具有特定的功能基团，或者氢原子可能被卤原子取代；一种烷氧基团，其中氢原子可能被卤原子取代；一种芳基或芳氧基，其中氢原子可能被卤原子，烷基或卤代烷基取代；或一种芳基烷基或芳基氧基，其中氢原子可能被卤原子，烷基或卤代烷基取代；n个R2和R3分别独立表示氢原子，烷基基团或烷氧羰基团；R4到R7分别独立表示氢原子，卤原子，烷基基团，烷氧基团，烯基基团，芳基，烷氧羰基团，二烷基氨基团或硝基；Y表示氧原子，硫原子或羰基；n个Z分别独立表示磺酰基或烷氧基磷酰基；n表示1或2。
• Magnesium-containing electrolytic solution
  申请人：FUJIFILM Wako Pure Chemical Corporation

  公开号：US10367231B2

  公开（公告）日：2019-07-30

  It is an object of the present invention to provide an electrolytic solution having high oxidation decomposition potential, where dissolution and deposition of magnesium proceed repeatedly and stably, using a non-nucleophilic alkoxide-type magnesium salt. The present invention relates to (1) an electrolytic solution for a magnesium battery comprising a mixture of a compound represented by the following general formula (I), a Lewis acid and a solvent: (2) an electrochemical device comprising the electrolytic solution, a positive electrode and a negative electrode, and (3) a compound represented by the following general formula (I′):

  本发明的目的是提供一种具有高氧化分解电位的电解液，使用非亲核烷氧基型镁盐，使镁的溶解和沉积能够重复和稳定地进行。本发明涉及(1)一种用于镁电池的电解液，包括以下通式(I)所代表的化合物、路易斯酸和溶剂的混合物：(2)一种电化学装置，包括上述电解液、正极和负极；以及(3)以下通式(I')所代表的化合物。
• Überwiegend ortho-verknüpfte Polyarylether
  申请人：BAYER AG

  公开号：EP0161484A1

  公开（公告）日：1985-11-21

  Die Erfindung betrifft ein Verfahren zur Herstellung von substituierten Polyarylethern aus para-substituierten Phenolen.

  本发明涉及一种用对位取代苯酚制备取代聚芳醚的工艺。
• Catalyst component for the polymerisation of olefins and process for preparing olefin polymers using same
  申请人：NIPPON OIL COMPANY, LIMITED

  公开号：EP0587440A2

  公开（公告）日：1994-03-16

  A catalyst component for use in the polymerization or copolymerization of olefin(s) is obtained by contacting the following components (1) to (4) with one another: (1) a compound of the general formula Me¹R¹p(OR²)qX¹4-p-q where R¹ is a hydrocarbon radical having 1 to 24 carbon atoms, X¹ is a halogen atom, Me¹ is Zr, Ti or Hf, and n is 0 ≦ n ≦ 4; (2) a compound of the general formula Me²R³m(OR⁴)nX²z-m-n where R² is a hydrocarbon radical having 1 to 24 carbon atoms, X² is a halogen atom, Me² is an element from Groups I to III in the Periodic Table, z is the valence of Me² and m is 0 ≦ m ≦ z; (3) an organocyclic compound having two or more conjugated double bonds; and (4) a modified organoaluminum compound containing Al-O-Al bond and with at least one branched-chain alkyl group being attached to aluminum atom.

  将下列组分（1）至（4）相互接触，可得到用于烯烃聚合或共聚的催化剂组分： (1) 通式为 Me¹R¹p(OR²)qX¹4-p-q的化合物 其中，R¹为具有 1 至 24 个碳原子的烃基；X¹为卤素原子；Me¹为 Zr、Ti 或 Hf；n 为 0 ≦ n ≦ 4； (2) 通式为 Me²R³m(OR⁴)nX²z-m-n的化合物，其中 R²为具有 1 至 24 个碳原子的烃基；X²为卤素原子；Me²为元素周期表中第 I 至 III 族的元素；z 为 Me²的化合价；m 为 0 ≦ m ≦ z； (3) 具有兩個或以上共轭双键的有机环化合物；及 (4) 含 Al-O-Al 键且至少有一个支链烷基与铝原子相连的改性有机铝化合物。
• OLEFIN OLIGOMERIZATION CATALYST AND PROCESS FOR THE PREPARATION OF OLEFIN OLIGOMER USING IT
  申请人：NIPPON OIL COMPANY, LTD.

  公开号：EP0758563A1

  公开（公告）日：1997-02-19

  An oligomerization catalyst according to the invention comprises a nickel compound (A); an organophosphoric compound (B); an organoaluminum compound (C); and a compound of the group consisting of carbon-halogen bond-containing compounds, oxoacid and salts thereof, sulfonic acid and derivatives thereof, and compounds of any of the formulae QX4n, QRn, QR'n, QX4lRm, QX4lR'm, QRlR'm, Q1(BR4)p and R''(BR4) wherein Q is an element of the group consisting of Mg, Ti, Zr, B and Sn, Q1 is an element of the group consisting of Li, Na, K, Ca and Zn, X4 is a halogen or hydrogen atom, R is a C1-C12 hydrocarbon group, R' is a C1-C12 oxygen-containing hydrocarbon groiup, R'' is a C1-C20 hydrocarbon group or an ammonium group, n is a valence of Q, l, m is a natural member that satisfied n=l+m, and p is a valence of Q1. This catalyst is useful for the production of alpha-olefinic oligomers.

  根据本发明的低聚催化剂包括镍化合物（A）；有机磷化合物（B）；有机铝化合物（C）；以及由以下物质组成的一组化合物：含碳-卤素键化合物、氧酸及其盐、磺酸及其衍生物，以及式 QX4n、QRn、QR'n、QX4lRm、QX4lR'm、QRlR'm、Q1(BR4)p 和 R''(BR4)中任何一种的化合物 其中 Q 是由镁、钛、锆、硼和锡组成的组中的元素、X4 是卤素或氢原子，R 是 C1-C12 烃基，R'是 C1-C12 含氧烃基，R''是 C1-C20 烃基或铵基，n 是 Q 的化合价，l、m 是满足 n=l+m 的自然数，p 是 Q1 的化合价。这种催化剂可用于生产α-烯烃低聚物。