(C9H6)((CH2)4CH3)(Si(CH3)(hex-5-enyl)NH(C4H9))

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚和异茚
• 英文名称: (C9H6)((CH2)4CH3)(Si(CH3)(hex-5-enyl)NH(C4H9))
• 英文别名: N-[hex-5-enyl-methyl-(3-pentyl-1H-inden-1-yl)silyl]-2-methylpropan-2-amine
• 化学式: C₂₅H₄₁NSi
• 分子量: 383.693
• InChiKey: LAJRTUVAUDUQQC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.61
• 重原子数：
  27
• 可旋转键数：
  12
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (C9H6)((CH2)4CH3)(Si(CH3)(hex-5-enyl)NH(C4H9)) 在 dihydrogen hexachloroplatinate 作用下， 以 四氢呋喃 、 乙醚 、 正戊烷 为溶剂， 反应 54.0h， 生成 tert-Butyl-[[6-(di-cyclopenta-1,4-dienyl-methyl-silanyl)-hexyl]-methyl-(3-pentyl-1H-inden-1-yl)-silanyl]-amine
  参考文献：
  名称：

  Dinuclear ansa zirconocene complexes containing a sandwich and a half-sandwich moiety as catalysts for the polymerization of ethylene

  摘要：

  Dinuclear ansa zirconocene complexes containing a half-sandwich and a sandwich moiety and their ligand precursors have been synthesized and characterized. After activation with methylalumoxane (MAO), these catalysts produce polyethylenes with bimodal molecular weight distributions in homogeneous and heterogeneous media. The catalyst performances and the polymer properties were compared with mono nuclear reference catalysts. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01673-x

文献信息

• Diastereomeric amido functionalized ansa half-sandwich complexes of titanium and zirconium as catalyst precursors for ethylene polymerization to give resins with bimodal molecular weight distributions
  作者：Alexander Reb、Helmut G Alt

  DOI：10.1016/s1381-1169(01)00171-6

  日期：2001.10

  A total of 20 diastereomeric amido functionalized ansa half-sandwich dichloride complexes of titanium and zirconium have been prepared and characterized. All complexes were used as catalyst precursors for ethylene polymerization. Since such catalysts consist of diastereomers they have the potential to produce resins with a bimodal molecular weight distribution. (C) 2001 Elsevier Science B.V. All rights reserved.
• Dinuclear ansa zirconocene complexes containing a sandwich and a half-sandwich moiety as catalysts for the polymerization of ethylene
  作者：Helmut G Alt、Rainer Ernst、Ingrid K Böhmer

  DOI：10.1016/s0022-328x(02)01673-x

  日期：2002.9

  Dinuclear ansa zirconocene complexes containing a half-sandwich and a sandwich moiety and their ligand precursors have been synthesized and characterized. After activation with methylalumoxane (MAO), these catalysts produce polyethylenes with bimodal molecular weight distributions in homogeneous and heterogeneous media. The catalyst performances and the polymer properties were compared with mono nuclear reference catalysts. (C) 2002 Elsevier Science B.V. All rights reserved.