exo-5,5,6-trifluoro-6-trifluoromethylbicyclo[2.2.1]hept-2-ene

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 英文名称: exo-5,5,6-trifluoro-6-trifluoromethylbicyclo[2.2.1]hept-2-ene
• 英文别名: 5,5,6-Trifluor-6-trifluormethyl-2-norbornen；(1S,4R,6R)-5,5,6-trifluoro-6-(trifluoromethyl)bicyclo[2.2.1]hept-2-ene
• 化学式: C₈H₆F₆
• 分子量: 216.126
• InChiKey: RNVJDIGFTGLKCE-NGJCXOISSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  14.0
• 可旋转键数：
  0.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  六氟丙烯 、 环戊二烯 在 对苯二酚 作用下， 160.0~220.0 ℃ 、4.41 MPa 条件下， 生成 endo-5,5,6-trifluoro-6-trifluoromethylbicyclo[2.2.1]hept-2-ene 、 exo-5,5,6-trifluoro-6-trifluoromethylbicyclo[2.2.1]hept-2-ene
  参考文献：
  名称：

  On the reaction of hexafluoropropene with butadiene and cyclopentadiene

  摘要：

  Reaction of hexafluoropropene with butadiene and cyclopentadiene in a stationary system was studied. The reaction of hexafluoropropene with burtadiene was shown to proceed along the scheme of [2+2]-cycloaddition, and with cyclopentadiene, as [2+4]-cycloaddition.

  DOI：

  10.1134/s1070363210110137

文献信息

• On the reaction of hexafluoropropene with butadiene and cyclopentadiene
  作者：Yu. V. Khoroshavina、G. A. Nikolaev、G. A. Emel’yanov

  DOI：10.1134/s1070363210110137

  日期：2010.11

  Reaction of hexafluoropropene with butadiene and cyclopentadiene in a stationary system was studied. The reaction of hexafluoropropene with burtadiene was shown to proceed along the scheme of [2+2]-cycloaddition, and with cyclopentadiene, as [2+4]-cycloaddition.