(E)-4-butyl-4''-((3,5-difluoro-4-((3,3,3-trifluoro-1-propene-1-yl)oxy)phenoxy)difluoromethyl)-2,3',3",5',5"-pentafluoro-1,1':4',1"-terphenyl

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (E)-4-butyl-4''-((3,5-difluoro-4-((3,3,3-trifluoro-1-propene-1-yl)oxy)phenoxy)difluoromethyl)-2,3',3",5',5"-pentafluoro-1,1':4',1"-terphenyl
• 英文别名: 5-(4-butyl-2-fluorophenyl)-2-[4-[[3,5-difluoro-4-[(E)-3,3,3-trifluoroprop-1-enoxy]phenoxy]-difluoromethyl]-3,5-difluorophenyl]-1,3-difluorobenzene
• 化学式: C₃₂H₂₀F₁₂O₂
• 分子量: 664.49
• InChiKey: NAHUPMACAUYBID-BQYQJAHWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.2
• 重原子数：
  46
• 可旋转键数：
  10
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  14

反应信息

• 作为产物：
  描述：

  4-((4"-butyl-2',2",3,5,6'-pentafluoro-[1,1':4',1"-terphenyl]-4-yl)difluoromethoxy)-2,6-difluorophenol 、 (E)-1-氯-3,3,3-三氟丙烯 在 sodium hydride 作用下， 以 N-甲基吡咯烷酮 、 mineral oil 为溶剂， 反应 24.5h， 以69%的产率得到(E)-4-butyl-4''-((3,5-difluoro-4-((3,3,3-trifluoro-1-propene-1-yl)oxy)phenoxy)difluoromethyl)-2,3',3",5',5"-pentafluoro-1,1':4',1"-terphenyl
  参考文献：
  名称：

  JP6299011

  摘要：

  公开号：

文献信息

• COMPOUND HAVING 3,3,3-TRIFLUORO-1-PROPENYLOXY, LIQUID CRYSTAL COMPOSITION AND LIQUID CRYSTAL DISPLAY DEVICE
  申请人：JNC PETROCHEMICAL CORPORATION

  公开号：US20140203209A1

  公开（公告）日：2014-07-24

  An object is to provide a liquid crystal compound satisfying at least one of physical properties such as a high stability to heat, light and so forth, a high clearing point, a low minimum temperature of a liquid crystal phase, a small viscosity, a suitable optical anisotropy, a large dielectric anisotropy, a suitable elastic constant and an excellent compatibility with other liquid crystal compounds, a liquid crystal composition containing the compound, and a liquid crystal display device including the composition. A solution is the compound represented by formula (1): wherein, in formula (1), for example, R 1 is alkyl having 1 to 10 carbons; ring A 1 and ring A 2 are independently 1,4-cyclohexylene or 1,4-phenylene; Z 1 and Z 2 are independently a single bond or —CF 2 O—; L 1 and L 2 are halogen; and a is 1 or 2.
• US9139773B2
  申请人：——

  公开号：US9139773B2

  公开（公告）日：2015-09-22