亚磷酸氢盐 | 15477-76-6

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 非金属氧阴离子化合物
• 中文名称: 亚磷酸氢盐
• 英文名称: hydrogen phosphite
• 英文别名: phosphite；Hydrogenphosphite
• CAS: 15477-76-6
• 化学式: HO₃P
• 分子量: 79.9799
• InChiKey: GBHRVZIGDIUCJB-UHFFFAOYSA-N

物化性质

• 密度：
  0.9967 g/cm3(Temp: 25 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  -1.7
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  66.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  sodium hypophosphite hydrate 、 二氧化碳 在 zinc sulfide sodium sulfide 作用下， 以 水 为溶剂， 生成 亚磷酸氢盐 、 草氨酸
  参考文献：
  名称：

  Semiconductor photocatalysis. 13. Effective photoreduction of carbon dioxide catalyzed by zinc sulfide quantum crystallites with low density of surface defects

  摘要：

  Freshly prepared colloidal ZnS suspensions (ZnS-0) effectively catalyze photoreduction of CO2 in water at pH 7 with NaH2PO2 in the coexistence of Na2S under UV irradiation. With competitive H-2 evolution, formate and a very small quantity of CO were formed with the apparent quantum yield PHI(1/2HCOO-, 0.24 at 313 nm, where H2PO2- was quantitatively photoxidized to HPO32-. The efficiency strongly depends on the pH of the system, preparation methods of ZnS photocatalysts, and synergistic effects of electron donors. Quantized ZnS crystallites with low density of surface defects are indispensable for the effective CO2 reduction. The synergistic effect in the use of both SH- and H2PO2- ions is discussed in terms of spectral properties of the photocatalyst.

  DOI：

  10.1021/j100187a062

文献信息

• Semiconductor photocatalysis. 13. Effective photoreduction of carbon dioxide catalyzed by zinc sulfide quantum crystallites with low density of surface defects
  作者：Masashi Kanemoto、Tsutomu Shiragami、Chyongjin Pac、Shozo Yanagida

  DOI：10.1021/j100187a062

  日期：1992.4

  Freshly prepared colloidal ZnS suspensions (ZnS-0) effectively catalyze photoreduction of CO2 in water at pH 7 with NaH2PO2 in the coexistence of Na2S under UV irradiation. With competitive H-2 evolution, formate and a very small quantity of CO were formed with the apparent quantum yield PHI(1/2HCOO-, 0.24 at 313 nm, where H2PO2- was quantitatively photoxidized to HPO32-. The efficiency strongly depends on the pH of the system, preparation methods of ZnS photocatalysts, and synergistic effects of electron donors. Quantized ZnS crystallites with low density of surface defects are indispensable for the effective CO2 reduction. The synergistic effect in the use of both SH- and H2PO2- ions is discussed in terms of spectral properties of the photocatalyst.