N-[4-(triethylammoniomethyl)benzoyl]caprolactam chloride

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-[4-(triethylammoniomethyl)benzoyl]caprolactam chloride
• 英文别名: n-[4-(Triethylammoniomethyl)benzoyl]caprolactam chloride；triethyl-[[4-(2-oxoazepane-1-carbonyl)phenyl]methyl]azanium;chloride
• 化学式: C₂₀H₃₁N₂O₂*Cl
• 分子量: 366.931
• InChiKey: IWDVAAIWDUIFSH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.61
• 重原子数：
  25
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  37.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N-[4-(triethylammoniomethyl)benzoyl]caprolactam chloride 在 双氧水 、 碳酸氢钠 作用下， 以 水 为溶剂， 生成 4-(triethylammoniomethyl)perbenzoic acid
  参考文献：
  名称：

  认识到TBLC活化的过氧化物系统在低温棉花漂白中的局限性。

  摘要：

  在这项研究中，棉在低温下用活化的过氧化物体系漂白，该体系是通过将漂白活化剂，即N- [4-（三乙基氨甲基）苯甲酰基]己内酰胺氯化物（TBCC）掺入过氧化氢（H2O2）水溶液中而建立的。 ）。实验结果表明，随着TBCC浓度在25-100g / L范围内增加，漂白性能出乎意料地降低。动力学吸附实验表明，这很可能归因于TBCC和原位生成的化合物与棉纤维的吸附相互作用。这种限制对于通常需要高TBCC浓度的棉花冷轧分批漂白过程是致命的。

  DOI：

  10.1016/j.carbpol.2015.12.013
• 作为产物：
  描述：

  N-(4-chloromethylbenzoyl)caprolactam 、 三乙胺 以 乙腈 为溶剂， 反应 4.0h， 以6.81 g的产率得到N-[4-(triethylammoniomethyl)benzoyl]caprolactam chloride
  参考文献：
  名称：

  Method for synthesizing cationic bleach activators via a single-bath reaction

  摘要：

  本发明提供了一种通过单浴反应合成阳离子漂白剂活化剂的方法，包括以下步骤：分别在各自的溶剂中溶解4-氯甲基苯甲酰氯和内酰胺，向内酰胺溶液中加入酸结合剂，然后将4-氯甲基苯甲酰氯溶液滴加到内酰胺/酸结合剂溶液中，最后加入三级胺到上述溶液中以制得反应溶液，进一步进行混合和回流处理。洗涤和干燥后的最终产品是TBLC阳离子漂白剂活化剂。本发明的方法极大地简化了合成过程，并降低了制备阳离子漂白剂活化剂（TBLC）的反应条件的严格性。同时，本方法产生高产率的TBLC阳离子漂白剂活化剂，使其成为这些漂白剂活化剂的工业生产的适当选择。

  公开号：

  US20160221955A1

文献信息

• Disinfectant wipe dispenser
  申请人：PERACIDE (UK) LIMITED

  公开号：US10300162B2

  公开（公告）日：2019-05-28

  A disinfectant wipe dispenser is provided comprising a container having first and second compartments, the first compartment being dimensioned to store a supply of wipes in use; and, separated by a baffle including one or more channels communicating between the compartments. The first compartment has an outlet through which wipes may be successively drawn; and, the second compartment is dimensioned to receive one or more portions of a disinfectant composition comprising a peroxy activator, a peroxy compound and optional further excipients, selected so that addition of the dosage form to a predetermined quantity of water produces a disinfectant solution containing peracetic acid at a concentration of at least about 1000 ppm. The channels communicate between the compartments and allow flow of water and aqueous disinfectant between the compartments, and have a maximum dimension configured to prevent movement of particles of disinfectant sediment from the second compartment to the first compartment.

  消毒湿巾分配器包括一个具有第一和第二隔间的容器，第一隔间的尺寸用于储存使用中的湿巾供应；并由一个挡板隔开，该挡板包括一个或多个在隔间之间沟通的通道。第一隔室有一个出口，湿巾可从该出口连续抽出；第二隔室的尺寸可容纳消毒剂组合物的一个或多个部分，该组合物包括过氧活化剂、过氧化合物和可选的其他赋形剂，选择这些赋形剂的目的是将该剂型添加到预定量的水中，产生含有过氧乙酸的消毒剂溶液，其浓度至少约为 1000 ppm。通道在隔室之间沟通，允许水和水性消毒剂在隔室之间流动，其最大尺寸可防止消毒剂沉淀物颗粒从第二隔室移动到第一隔室。
• Sporocidal disinfectant or sanitising composition
  申请人：Peracide (UK) Limited

  公开号：US10660338B2

  公开（公告）日：2020-05-26

  Solid disinfectant dosage forms having a peroxy activator and a peroxy compound are provided. The dosage form can be selected so that addition of the dosage form to a predetermined quantity of water produces a disinfectant solution containing peracetic acid in a concentration of at least about 1000 ppm. The dosage form can include a colour indicator arranged to provide a first colour signal when the concentration of peracetic acid is lower than about 1000 ppm and a second colour signal when the concentration is higher than about 1000 ppm and a third colour signal when the concentration falls below about 1000 ppm. The peroxy compound can be selected from the group consisting of sodium percarbonate, ammonium persulphate, calcium percarbonate, magnesium percarbonate, sodium perborate, sodium persulfate, sodium perphosphate and mixtures thereof.

  提供了具有过氧活化剂和过氧化合物的固体消毒剂剂型。可以选择该剂型，以便将该剂型添加到预定量的水中，产生含有过氧乙酸的消毒溶液，其浓度至少约为 1000 ppm。该剂型可包括一个颜色指示器，当过氧乙酸的浓度低于约 1000 ppm 时，该颜色指示器提供第一颜色信号；当浓度高于约 1000 ppm 时，该颜色指示器提供第二颜色信号；当浓度低于约 1000 ppm 时，该颜色指示器提供第三颜色信号。过氧化合物可选自过碳酸钠、过硫酸铵、过碳酸钙、过碳酸镁、过硼酸钠、过硫酸钠、过磷酸钠及其混合物。
• Establishment of an activated peroxide system for low-temperature cotton bleaching using N-[4-(triethylammoniomethyl)benzoyl]butyrolactam chloride
  作者：Changhai Xu、David Hinks、Chang Sun、Qufu Wei

  DOI：10.1016/j.carbpol.2014.11.054

  日期：2015.3

  Cotton bleaching is traditionally carried out in strongly alkaline solution of hydrogen peroxide (H2O2) at temperatures close to the boil. Such harsh processing conditions can result in extensive water and energy consumptions as well as severe chemical damage to textiles. In this study, an activated peroxide system was established for low-temperature cotton bleaching by incorporating a bleach activator, namely N-[4-(triethylammoniomethyl)benzoyl]butyrolactam chloride (TBBC) into an aqueous H2O2 solution. Experimental results showed that the TBBC-activated peroxide system exhibited the most effective bleaching performance in a pH range of 6-8 which could be approximated by adding sodium bicarbonate (NaHCO3). The TBBC/H2O2/NaHCO3 system led to rapid bleaching of cotton at a temperature as low as 50 degrees C. In comparison with the hot alkaline peroxide bleaching system, the TBBC/H2O2/NaHCO3 system provided cotton fabric with an equivalent degree of whiteness, higher degree of polymerization, and slightly lower water absorbency. The new activated peroxide system may provide a more environmentally benign approach to cotton bleaching. (C) 2014 Elsevier Ltd. All rights reserved.
• SIGNAL ACTIVATED DECONTAMINATING COATING
  申请人：Crosslink Polymer Research

  公开号：EP1926682A2

  公开（公告）日：2008-06-04
• SPOROCIDAL DISINFECTANT OR SANITISING COMPOSITION
  申请人：Peracide (UK) Limited

  公开号：EP3094177A1

  公开（公告）日：2016-11-23