trans-1-Brom-2-trichlormethyl-cyclooctan

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: trans-1-Brom-2-trichlormethyl-cyclooctan
• 英文别名: (1R,2S)-1-bromo-2-(trichloromethyl)cyclooctane
• 化学式: C₉H₁₄BrCl₃
• 分子量: 308.473
• InChiKey: WATALFRMBMIIKB-HTQZYQBOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  三氯溴甲烷 、 顺-环辛烯 在 (PhCH₂)Co(dimethylglyoxyme monoanion)2Py 作用下， 反应 2.0h， 生成 trans-1-Brom-2-trichlormethyl-cyclooctan 、 1-bromo-2-(trichloromethyl)cyclooctane 、 1-bromo-4-trichloromethylcylooctane
  参考文献：
  名称：

  Addition of Bromotrichloromethane and Tetrachloromethane tocis-Cyclooctene, Cyclohexene, and Norbornadiene in the Presence of Palladium(II) Complexes

  摘要：

  Addition of bromotrichloromethane and tetrachloromethane to alkenes in the presence of palladium(II) complexes begins with single-electron transfer from the palladium atom to polyhalomethane molecule, followed by fragmentation of the radical anion thus formed and generation of trichloromethyl radical. Halogen transfer to a carbon-centered radical arising from addition of trichloromethyl radical at the double bond occurs both from the polyhalomethane molecule and from halide palladium complex.

  DOI：

  10.1023/b:rujo.0000003181.02370.cf

文献信息

• Addition of Bromotrichloromethane and Tetrachloromethane to<i>cis</i>-Cyclooctene, Cyclohexene, and Norbornadiene in the Presence of Palladium(II) Complexes
  作者：A. S. Dneprovskii†、A. A. Ermoshkin、A. N. Kasatochkin、V. P. Boyarskii

  DOI：10.1023/b:rujo.0000003181.02370.cf

  日期：2003.7

  Addition of bromotrichloromethane and tetrachloromethane to alkenes in the presence of palladium(II) complexes begins with single-electron transfer from the palladium atom to polyhalomethane molecule, followed by fragmentation of the radical anion thus formed and generation of trichloromethyl radical. Halogen transfer to a carbon-centered radical arising from addition of trichloromethyl radical at the double bond occurs both from the polyhalomethane molecule and from halide palladium complex.