dineopentyl 3-fluorophthalate

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: dineopentyl 3-fluorophthalate
• 英文别名: Bis(2,2-dimethylpropyl) 3-fluorobenzene-1,2-dicarboxylate
• 化学式: C₁₈H₂₅FO₄
• 分子量: 324.393
• InChiKey: GTMQVAYLZCRIHZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  23
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  新戊醇 在 硫酸 作用下， 反应 2.0h， 以28.4%的产率得到dineopentyl 3-fluorophthalate
  参考文献：
  名称：

  PHTHALIC DIESTER DERIVATIVES AND ELECTRON DONORS

  摘要：

  公开号：

  EP1188739B1

文献信息

• SOLID CATALYST COMPONENT FOR OLEFIN POLYMERIZATION AND CATALYST
  申请人：Toho Titanium Co., Ltd.

  公开号：EP1260524A1

  公开（公告）日：2002-11-27

  The solid catalyst component for polymerization of olefins comprising (a) a magnesium compound, (b) titanium tetrachloride, (c) a phthalic acid diester or a derivative thereof, and (d1) a hydroxy group-containing hydrocarbon compound having a specific structure or (d2) a mercapto group-containing hydrocarbon compound having a specific structure and the olefin polymerization catalyst can produce olefin polymers in a very high yield, particularly can produce propylene polymers in a very high yield, while retaining high stereoregularity.

  用于烯烃聚合的固体催化剂组分包括：(a) 镁化合物；(b) 四氯化钛；(c) 邻苯二甲酸二酯或其衍生物；(d1) 具有特定结构的含羟基烃化合物或 (d2) 具有特定结构的含巯基烃化合物，该烯烃聚合催化剂能以极高的产率生产烯烃聚合物，特别是能以极高的产率生产丙烯聚合物，同时保持较高的立体规整性。
• Method for producing solid catalyst component for olefin polymerization, catalyst for olefin polymerization and a process for propylene polymerization
  申请人：TOHO TITANIUM CO., LTD.

  公开号：US10246530B2

  公开（公告）日：2019-04-02

  A method for producing a solid catalyst for olefin (co)polymerization includes bringing into contact with each other a magnesium compound, a tetravalent titanium halide compound, an organic compound represented the following general formula (1) R1k(C6H4-k)(COOR2)(COOR3)  (1) and an organic compound represented the following general formula (2) R4R5C═C (COOR6)(COOR7)  (2) wherein R1 is a halogen atom or an alkyl group, R2 and R3 are a linear alkyl group, R4 and R5 are independently an atom or group selected from a hydrogen atom, halogen, a linear alkyl group, a branched alkyl group a vinyl group, a linear or branched alkenyl group, a cycloalkenyl group, an aromatic hydrocarbon group, and R6 and R7 are independently a linear alkyl group, a branched alkyl group, a vinyl group, a linear or branched alkenyl group a cycloalkyl group, a cycloalkenyl group, or an aromatic hydrocarbon group.

  一种生产烯烃（共）聚合用固体催化剂的方法，包括使镁化合物、四价卤化钛化合物、下 列通式（1）代表的有机化合物相互接触 R1k(C6H4-k)(COOR2)(COOR3) (1) 和 代表以下通式(2)的有机化合物 R4R5C═C (COOR6)(COOR7) (2) 其中 R1 是卤素原子或烷基，R2 和 R3 是直链烷基，R4 和 R5 独立地是选自氢原子、卤素、直链烷基、支链烷基、乙烯基、直链或支链烯基、环烯基、芳香烃基的原子或基团，R6 和 R7 独立地是直链烷基、支链烷基、乙烯基、直链或支链烯基、环烷基、环烯基或芳香烃基。
• Method for producing solid catalyst component for olefin polymerization, catalyst for olefin polymerization, and method for producing olefin polymer
  申请人：Uozumi Toshiya

  公开号：US10364304B2

  公开（公告）日：2019-07-30

  A method for producing a solid catalyst component for olefin polymerization includes bringing a magnesium compound, a tetravalent titanium halide compound, and an electron donor compound represented by a general formula (1) into contact with each other, reacting the mixture, washing the resulting reaction product to obtain a solid component, bringing the solid component, a tetravalent titanium halide compound, and an electron donor compound represented by a general formula (2) into contact with each other, reacting the mixture, and washing the resulting reaction product. (R1)kC6H4-k(COOR2)(COOR3)  (1) R4R5C(COOR6)2  (2) A polymer that exhibits high activity with respect to hydrogen, high stereoregularity, and high bulk density can be obtained using a catalyst including a solid catalyst component obtained by the method.

  一种生产烯烃聚合用固体催化剂组分的方法，包括将镁化合物、四价卤化钛化合物和通式（1）表示的电子供体化合物相互接触，使混合物反应，洗涤所得反应产物以获得固体组分，将固体组分、四价卤化钛化合物和通式（2）表示的电子供体化合物相互接触，使混合物反应，洗涤所得反应产物。 (R1)kC6H4-k(COOR2)(COOR3) (1) R4R5C(COOR6)2 (2) 使用包括通过该方法获得的固体催化剂组分的催化剂，可以获得对氢具有高活性、高立体规整度和高体积密度的聚合物。
• Phthalic diester derivatives and electron donors
  申请人：——

  公开号：US20030036594A1

  公开（公告）日：2003-02-20

  A phthalic acid diester derivative represented by a specific formula and an electron donor used in an olefin polymerization catalyst containing the phthalic acid diester derivative as an effective component. The electron donor can produce polymers with a high stereoregularity at an extremely high polymerization activity and high yield, and exhibit a high response to hydrogen.

  一种以特定公式表示的邻苯二甲酸二酯衍生物和一种电子供体，用于以邻苯二甲酸二酯衍生物为有效成分的烯烃聚合催化剂。该电子供体能以极高的聚合活性和高产率生产出具有高立体规整度的聚合物，并对氢气具有高响应性。
• Solid catalyst component and catalyst for olefins polymerization
  申请人：——

  公开号：US20030130109A1

  公开（公告）日：2003-07-10

  Solid catalyst components and catalysts which comprise (a) a magnesium compound, (b) titanium tetra chloride, and (c) a phthalic acid diester or its derivative represented by a particular formula, can afford polymers of olefins in very high yield. Particularly, propylene polymers can be obtained in very high yield while retaining high stereoregularity. Moreover, they have high responsiveness to hydrogen.

  由(a)镁化合物、(b)四氯化钛和(c)邻苯二甲酸二酯或其衍生物组成的固体催化剂组分和催化剂，能以非常高的产率获得烯烃聚合物。尤其是丙烯聚合物，产量非常高，同时还能保持较高的立体规整性。此外，它们对氢的反应性也很高。