FLUORINATED ELASTOMER FOR MOLDING OF FUEL LINE COMPONENT, AND COMPOSITION COMPRISING THE SAME
申请人:Unimatec Co., Ltd.
公开号:EP2077285A1
公开(公告)日:2009-07-08
A fluorine-containing elastomer for molding fuel system parts, which has a copolymer composition comprising 10-40% by weight of tetrafluoroethylene (TFE), 80-30% by mole of vinylidene fluoride (VdF), and 10-30% by mole of hexafluoropropylene(HFP), as copolymerized in the presence of an iodine and bromine-containing compound represented by the following general formula : RBrnIm (where R is a fluorohydrocarbon group, a chlorofluorohydrocarbon group, or a hydrocarbon group, each having 1-10 carbon atoms, and n and m each are 1 or 2), and has an intrinsic viscosity of 20-180ml/g, Mw (weight average molecular weight)/Mn (number average molecular weight) ratio of 2-20, and a molecular weight distribution of monopeak or multipeak type, and a fluorine-containing elastomer composition, which comprises the fluorine-containing elastomer, at least one of a polyol vulcanizing agent and a polyamine vulcanizing agent, an organic peroxide, and a polyfunctional unsaturated compound. The composition is suitable for use in molding fuel system parts to give fluorine-containing elastomer moldings with distinguished moldability, vulcanizate physical properties, chemical resistance, photostability and economy.
一种用于成型燃料系统部件的含氟弹性体,其共聚物成分包括 10-40%(重量比)的四氟乙烯(TFE)、80-30%(摩尔比)的偏氟乙烯(VdF)和 10-30%(摩尔比)的六氟丙烯(HFP),这些共聚物是在由下式通式表示的含碘和含溴化合物存在下共聚而成的:RBrnIm(其中 R 是氟烃基团、氯氟烃基团或烃基团,每个基团有 1-10 个碳原子,n 和 m 各为 1 或 2),本征粘度为 20-180ml/g,Mw(重量平均分子量)/Mn(数量平均分子量)比为 2-20、和含氟弹性体组合物,其中包含含氟弹性体、多元醇硫化剂和多胺硫化剂中的至少一种、有机过氧化物和多官能团不饱和化合物。该组合物适用于成型燃料系统部件,使含氟弹性体成型件具有出色的成型性、硫化物理性能、耐化学性、光稳定性和经济性。