N-1,5-cyclohexadienyl-N-phenylamine

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-1,5-cyclohexadienyl-N-phenylamine
• 英文别名: N-cyclohexa-1,5-dien-1-ylaniline
• 化学式: C₁₂H₁₃N
• 分子量: 171.242
• InChiKey: OADJAIZCIUKLCC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1-phenyl-3a,4,5,6-tetrahydro-1H-benzoimidazol-2(3H)-one 以 乙腈 为溶剂， 生成 异氰酸酯 、 N-1,5-cyclohexadienyl-N-phenylamine
  参考文献：
  名称：

  溶液中1-烯丙基-4-芳基四唑酮的光化学；结构对光产物选择性的影响†

  摘要：

  碳环烯丙基醇衍生的四唑酮的光化学 环己-2-烯醇 和 3-甲基环己-2-烯醇并从天然萜烯醇中提取了神经醇，目的是评估溶剂的影响以及笨重的烯丙基部分对光产品选择性和稳定性的影响。衍生自四唑酮的光解内罗尔 和 环己-2-烯醇通过一种途径提供了相应的嘧啶酮作为主要产物，该途径似乎与先前从无环和无阻碍的烯丙醇衍生而来的其他1-allyl-4-phenyl-1,4-dihydro-5 H -tetrazol-5-one所提议的途径相似进行了研究，但对大体积3-甲基环己-2-烯醇4c衍生的四唑酮进行光解会导致苯并咪唑酮的形成，这表明在这种情况下，N 2挤出时形成的双自由基的环化反应涉及苯基取代基而不是烯丙基部分。进行了理论计算（DFT（B3LYP）/ 3-21G *）以支持对实验结果和机理建议的解释。进行激光闪光光解实验的目的是弄清参与初级光裂解过程的中间体的性质。

  DOI：

  10.1039/c2pp25210d

文献信息

• CONJUGATED POLYMER, INSOLUBILIZED POLYMER, ORGANIC ELECTROLUMINESCENT DEVICE MATERIAL, COMPOSITION FOR ORGANIC ELECTROLUMINESCENT DEVICE, METHOD FOR PRODUCING POLYMER, ORGANIC ELECTROLUMINESCENT DEVICE, ORGANIC EL DISPLAY, AND ORGANIC EL ILLUMINATOR
  申请人：Mitsubishi Chemical Corporation

  公开号：EP2270069A1

  公开（公告）日：2011-01-05

  An object of the present invention is to provide a conjugated polymer which has a high hole transportability and is excellent in solubility and depositability. Another object of the present invention is to provide an organic electroluminescence element which is capable of low voltage driving and has a high luminous efficiency and drive stability. The conjugated polymer of the present invention is a conjugated polymer containing a specific structure as the repeating unit, where the conjugated polymer contains an insolubilizing group as a substituent, the weight average molecular weight (Mw) is 20,000 or more and the dispersity (Mw/Mn) is 2.40 or less.

  本发明的一个目的是提供一种共轭聚合物，该聚合物具有较高的空穴传输性，并具有出色的可溶性和沉积性。本发明的另一个目的是提供一种有机电致发光元件，它能够低压驱动，并具有高发光效率和驱动稳定性。本发明的共轭聚合物是一种含有特定结构作为重复单元的共轭聚合物，其中共轭聚合物含有不溶解基团作为取代基，重量平均分子量（Mw）为 20,000 或以上，分散度（Mw/Mn）为 2.40 或以下。
• ORGANIC ELECTROLUMINESCENT ELEMENT, ORGANIC EL DISPLAY DEVICE AND ORGANIC EL ILLUMINATING DEVICE
  申请人：Mitsubishi Chemical Corporation

  公开号：EP2315291A1

  公开（公告）日：2011-04-27

  To provide an organic electroluminescent element having a low driving voltage, high current efficiency and high voltage efficiency. An organic electroluminescent element comprising an anode, a cathode and an organic layer disposed between the anode and the cathode, wherein the organic layer comprises a mixed layer containing a light-emitting low molecular compound and/or a charge-transporting low molecular compound in a film containing an insolubilized polymer obtained by insolubilizing an insolubilizing polymer, and, adjacent to the mixed layer, a layer containing a light-emitting low molecular compound and a charge-transporting low molecular compound and not containing an insolubilized polymer.

  提供一种具有低驱动电压、高电流效率和高电压效率的有机电致发光元件。 一种有机电致发光元件，包括阳极、阴极和设置在阳极与阴极之间的有机层，其中有机层包括一个混合层，该混合层含有一种发光低分子化合物和/或一种电荷传输低分子化合物，该混合层在一层薄膜中，该薄膜含有一种通过对一种未沸腾聚合物进行沸腾处理而得到的未沸腾聚合物；以及一个与混合层相邻的层，该层含有一种发光低分子化合物和一种电荷传输低分子化合物，但不含有未沸腾聚合物。
• METHOD FOR MANUFACTURING ORGANIC ELECTROLUMINESCENT ELEMENT, ORGANIC ELECTROLUMINESCENT ELEMENT, DISPLAY DEVICE AND ILLUMINATING DEVICE
  申请人：Mitsubishi Chemical Corporation

  公开号：EP2515615A1

  公开（公告）日：2012-10-24

  A task/object of the present invention is to produce an organic electroluminescence element having high driving stability and long drive life at a low cost by forming a luminescent layer in a specific environment by using a luminescent layer-forming composition containing a compound having a specific structure and a solvent. The invention relates to a method for manufacturing an organic electroluminescence element having a luminescent layer between a first electrode and a second electrode formed to face said first electrode, the method comprising, as a luminescent layer-forming step, a step of forming a coating film by a wet film-forming method in an environment with an oxygen concentration of 18 to 22 vol% by using a luminescent layer-forming composition containing: a compound having a molecular weight of 400 or more and represented by the following formula (1); and a solvent (wherein each of Ar31 and Ar32 independently represents an aromatic hydrocarbon ring group or aromatic heterocyclic group having a substituent, provided that said compound represented by formula (1) does not have a partial structure derived from a nitrogen atom-containing heterocyclic ring, and the anthracene ring in formula (1) may further have an optional substituent):

  本发明的任务/目的是通过使用含有具有特定结构的化合物和溶剂的发光层形成组合物，在特定环境中形成发光层，从而以较低的成本生产出具有高驱动稳定性和长驱动寿命的有机电致发光元件。本发明涉及一种制造有机电致发光元件的方法，该元件在第一电极和第二电极之间具有发光层，该第二电极面向所述第一电极，作为发光层形成步骤，该方法包括在氧气浓度为 18 至 22 vol% 的环境中通过湿成膜法形成涂膜的步骤，该步骤中使用的发光层形成组合物含有分子量大于或等于 400 且由下式（1）表示的化合物；以及溶剂（其中 Ar31 和 Ar32 各自独立地代表芳香烃环基或具有取代基的芳香杂环基，条件是由式（1）表示的所述化合物不具有源自含氮原子杂环的部分结构，且式（1）中的蒽环可进一步具有任选取代基）：
• CLOCK LUBRICATING-OIL COMPOSITION AND CLOCK
  申请人：Citizen Holdings Co., Ltd.

  公开号：EP2949734A1

  公开（公告）日：2015-12-02

  [Problem] To provide a lubricating oil composition for a timepiece, said composition being excellent in durability. [Solution] The lubricating oil composition for a timepiece according to the present invention contains a lubricant component (A) containing a base oil (A1), at least one antiwear agent (B) selected from a neutral phosphate ester and a neutral phosphite ester, and an antioxidant (C), and is characterized in that the total acid number of the composition is not more than 0.8 mgKOH/g, the antiwear agent (B) is contained in an amount of 0.1 to 15 parts by mass based on 100 parts by mass of the lubricant component (A), the antioxidant (C) is contained in an amount of 0.01 to 3 parts by mass based on 100 parts by mass of the lubricant component (A), and the composition contains a diphenylamine derivative (C-1) represented by the following general formula (c-1) and a hindered amine compound (C-2) represented by the following general formula (c-2) as the antioxidants (C).

  [问题] 提供一种用于钟表的润滑油组合物，所述组合物具有优异的耐用性。[解决方案] 根据本发明的钟表润滑油组合物包含一种含有基础油（A1）的润滑剂成分（A）、至少一种选自中性磷酸酯和中性亚磷酸酯的抗磨剂（B）以及一种抗氧化剂（C），其特征在于组合物的总酸值不超过 0.8 mgKOH/g，抗磨剂（B）的含量为 0.抗磨剂（B）的含量为 0.1 至 15 份（以 100 份润滑剂组分（A）的质量为基准），抗氧化剂（C）的含量为 0.01 至 3 份（以 100 份润滑剂组分（A）的质量为基准），并且该组合物包含由以下通式（c-1）表示的二苯胺衍生物（C-1）和由以下通式（c-2）表示的受阻胺化合物（C-2）作为抗氧化剂（C）。
• HETEROCYCLIC COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME
  申请人：Samsung Display Co., Ltd.

  公开号：EP3657563A2

  公开（公告）日：2020-05-27

  A heterocyclic compound is represented by Formula 1. An organic light-emitting device includes: a first electrode; a second electrode facing the first electrode; and an organic layer between the first electrode and the second electrode and including an emission layer, wherein the organic light-emitting device includes at least one of the heterocyclic compound.

  一种杂环化合物由式 1 表示。一种有机发光器件包括：第一电极；面对第一电极的第二电极；以及位于第一电极和第二电极之间并包括发射层的有机层，其中有机发光器件包括至少一种杂环化合物。