全氟己基锍五氟化物 | 1423-20-7

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 中文名称: 全氟己基锍五氟化物
• 英文名称: perfluoro-n-hexylsulfurpentafluoride
• 英文别名: pentafluoro-tridecafluorohexyl-λ⁶-sulfane；Perfluorhexyl-schwefelpentafluorid；Hexane, 1-(pentafluorothio)-tridecafluoro-；pentafluoro(1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexyl)-λ6-sulfane
• CAS: 1423-20-7
• 化学式: C₆F₁₈S
• 分子量: 446.103
• InChiKey: GVPQTQICQWIEKB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.2
• 重原子数：
  25
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  1
• 氢给体数：
  0
• 氢受体数：
  18

反应信息

• 作为产物：
  描述：

  己硫醚 生成 全氟己基锍五氟化物
  参考文献：
  名称：

  Notes- Six and Twelve Carbon Fluorocarbon Derivatives of Sulfur Hexafluoride

  摘要：

  DOI：

  10.1021/jo01078a621

文献信息

• Process for preparing fluorochemicals
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0643155A2

  公开（公告）日：1995-03-15

  A process for preparing fluorochemical compounds, e.g., perfluoroalkanes, perfluoroethers, and perfluoroalkyl tertiary amines, comprises (a) forming a mixture comprising at least one fluorinatable, non-functional organic starting compound, e.g., propane, and at least one other compound which is present in an amount sufficient to enable the formation of a fluorochemical phase and which is selected from the group consisting of (i) perfluorochemical compounds, e.g., perfluorohexane, which boil at a higher temperature than either the fluorinatable, non-functional organic starting compound or the fluorochemical compound resulting from the subsequent fluorination of the fluorinatable, non-functional organic starting compound; and (ii) precursor compounds, e.g., hexane, which can be fluorinated in situ to produce such perfluorochemical compounds; and (b) subjecting the mixture to electrochemical fluorination in the presence of anhydrous hydrogen fluoride.

  一种制备氟化合物（如全氟烷烃、全氟醚和全氟烷基叔胺）的工艺包括 (a) 形成一种混合物，该混合物包括至少一种可氟化的非官能有机起始化合物（如丙 烷）和至少一种其它化合物，其含量足以形成氟化学相，该化合物选自以下组别： (b) 将至少一种可氟化的非官能有机起始化合物（如丙烷）和至少一种其它化合物（其 含量足以形成氟化学相，该化合物选自以下组别 (i) 全氟化合物，如全氟己烷，其沸腾温度高于可氟化的非功能性有机起始化合物或可氟化的非功能性有机起始化合物随后氟化产生的氟化合物；以及 (ii) 可就地氟化以生产此类全氟化合物的前体化合物，如正己烷；以及 (b) 在无水氟化氢存在下，对混合物进行电化学氟化。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.2, 1.3.6, page 167 - 182
  作者：

  DOI：——

  日期：——
• CONTINUOUS PROCESS FOR PURIFYING PERFLUOROCHEMICAL COMPOSITIONS
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0688309B1

  公开（公告）日：1997-10-15
• ELECTRONICALLY MODIFIED REACTION INTERMIDEATES
  申请人：Markou, Demetrios

  公开号：EP2603225A2

  公开（公告）日：2013-06-19
• Novel method for creating, suspending and stabilizing electronically modified oxygen derivatives, along with creating, suspending and stabilizing electronically modified reaction intermediates, in a bio compatible fluorocarbon suspension, for the purpose of inducing a cascading immune response in mammalian patients
  申请人：Markou Demetrios

  公开号：US20120039796A1

  公开（公告）日：2012-02-16

  A bio compatible free radical suspension, comprising of oxygen and electronically modified reaction intermediates, where a fluorocarbon is used as an inert medium for stabilization of reaction intermediates. A stabilized bio compatible electronically modified derivative suspension is produced by the subjecting a fluorocarbon to certain stressors, such as oxidizing agents, reactive intermediates, physiological gases, benzo-γ-pyrone derivatives, ultrasonic-cavitation, electric fields, magnetic fields, UV radiation, active metal catalyst, surfactant reactants, buffers, electrolytes, glucose, glucose derivatives, for the purpose of inducing a cascading immune response.