全氟芴烷 | 307-08-4

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 中文名称: 全氟芴烷
• 中文别名: 全氟芴；全氟全氢芴
• 英文名称: perfluorododecahydrofluorene
• 英文别名: perfluoroperhydrofluorene；docosafluoro-decahydro-fluorene；Docosafluor-decahydro-fluoren；1,1,2,2,3,3,4,4,4a,4b,5,5,6,6,7,7,8,8,8a,9,9,9a-docosafluorofluorene
• CAS: 307-08-4
• 化学式: C₁₃F₂₂
• 分子量: 574.108
• InChiKey: PDFYOLXVKFUEPM-UHFFFAOYSA-N

物化性质

• 沸点：
  194 °C
• 密度：
  1.89
• 闪点：
  74℃
• LogP：
  6.997 (est)

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  35
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  22

安全信息

• 海关编码：
  2903999090

反应信息

• 作为产物：
  描述：

  芴 在 silver(II) fluoride 作用下， 生成 全氟芴烷
  参考文献：
  名称：

  稠环碳氟化合物的制备

  摘要：

  DOI：

  10.1021/ie50447a630

文献信息

• Perfluorocarbon liquids useful in eye treatment and diagnostic procedures
  申请人：CHILDREN'S HOSPITAL MEDICAL CENTER

  公开号：EP0089232A2

  公开（公告）日：1983-09-21

  Perfluorocarbon liquids are disclosed as being useful as substitutes for the vitreous or aqueous of the eye, and as transparentizing agents in the cornea or lens of the eye. Radiopaque liquid perfluorocarbons are useful as radiopaque agents in diagnostic procedures on the eye.

  已公开的全氟化碳液体可用作眼睛玻璃体或水液的替代物，也可用作眼睛角膜或晶状体的透明剂。 不透射线的液态全氟化碳可用作眼睛诊断程序中的不透射线剂。
• Artificial blood and other gas transport agents
  申请人：CHILDREN'S HOSPITAL MEDICAL CENTER

  公开号：EP0091820A1

  公开（公告）日：1983-10-19

  Gas transport agents containing a perfluorocyclocarbon and an amine oxide are disclosed. These compositions provide emulsions or solutions for use in oxygen transport, particularly in animals. They are therefore useful as artificial blood compositions. Large concentrations of perfluorocarbons may be employed even up to 50% or more by volume in preparing emulsions, microemulsions or solutions. The emulsions or solutions are stable under room temperature storage conditions

  本发明公开了含有全氟环碳化物和氧化胺的气体运输剂。这些组合物提供的乳液或溶液可用于氧气输送，特别是动物体内的氧气输送。因此，它们可用作人造血液组合物。在制备乳剂、微乳剂或溶液时，可以使用高浓度的全氟碳化合物，按体积计算甚至可高达 50%或以上。这些乳剂或溶液在室温储存条件下非常稳定
• Improvements in and relating to a method of detecting a certain gas in an animal
  申请人：CHILDREN'S HOSPITAL MEDICAL CENTER

  公开号：EP0118281A2

  公开（公告）日：1984-09-12

  A method to detect indirectly at least one gas, particularly dissolved gases, of an animal employing nuclear magnetic resonance techniques (NMR). The method examines an NMR spectrum to determine chemical shift relaxation times or spin-spin couplings for an element of an animal influenced by at least one gas of the animal, the chemical shift corresponding to the amount or identify of the gas.

  一种利用核磁共振技术（NMR）间接检测动物体内至少一种气体，特别是溶解气体的方法。该方法通过检测核磁共振波谱来确定受动物体内至少一种气体影响的动物元素的化学位移弛豫时间或自旋-自旋耦合，化学位移与气体的量或识别率相对应。
• Method of detecting temperature in an object
  申请人：CHILDREN'S HOSPITAL MEDICAL CENTER

  公开号：EP0122000A2

  公开（公告）日：1984-10-17

  A method to detect indirectly a temperature of an object employing nuclear magnetic resonance techniques (NMR). The method involves obtaining an NMR spectrum to determine chemical shift, relaxation times, spin-spin couplings or quadrupole couplings for an element of a compound having at least one conformational isomer wherein the compound is influenced by a temperature of the object. The difference between the detected radio frequency signals for the same element, spectral patterns or chemical shifts corresponds to the temperature of the object.

  一种利用核磁共振技术间接检测物体温度的方法。该方法包括获取核磁共振谱，以确定具有至少一种构象异构体的化合物中某一元素的化学位移、弛豫时间、自旋-自旋耦合或四极耦合，其中该化合物受物体温度的影响。 检测到的同一元素的射频信号、光谱模式或化学位移之间的差异与物体的温度相对应。
• Emulsions of perfluorocarbons in aqueous media
  申请人：ISC CHEMICALS LIMITED

  公开号：EP0196776A1

  公开（公告）日：1986-10-08

  Increased stability is conferred on oil-in-water emulsions of perfluorocarbons by addition of a minor (0.1-5% w/v) amount of a fluorinated compound of higher bailing point than the perfluoracarbon being emulsified. The added fluorinated compound is preferably a perfluorinated saturated polycyclic hydrocarbon. The most preferred additive is perfluoroperhydrofluoranthene.

  在全氟碳化合物的水包油乳液中加入少量（0.1-5% w/v）比被乳化的全氟碳化合物燃点更高的含氟化合物，可提高稳定性。添加的含氟化合物最好是全氟饱和多环烃。最理想的添加剂是全氟全氢荧蒽。