(2-methylbutyl)-N,N-diethylamine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: (2-methylbutyl)-N,N-diethylamine
• 英文别名: N,N-diethyl-2-methylbutylamine；(2-methylbutyl)-N,N'-diethylamine；N,N-diethyl-2-methylbutan-1-amine
• 化学式: C₉H₂₁N
• 分子量: 143.272
• InChiKey: JRHGZGWIJIJJTE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  N,N-二乙基烯丙胺 、 二乙基镁 在 二氯二茂锆 、 氯化铵 作用下， 生成 (2-methylbutyl)-N,N-diethylamine
  参考文献：
  名称：

  Regioselective reaction of functionally substituted mono-, di-, and triolefins with alkylmagnesium compounds, catalyzed by Cp2ZrCl2

  摘要：

  DOI：

  10.1007/bf00948633

文献信息

• Rhodium‐Catalysed Reductive Amination for the Synthesis of Tertiary Amines
  作者：Jonas Bianga、Niklas Kopplin、Jonas Hülsmann、Dieter Vogt、Thomas Seidensticker

  DOI：10.1002/adsc.202000746

  日期：2020.10.21

  A procedure for the synthesis of tertiary amines via reductive amination of aldehydes with molecular hydrogen as a reducing agent using homogeneous rhodium catalysis is presented. Using an amine to aldehyde ratio of 4/1 enabled the synthesis of tertiary amines from nine different aldehydes and nine different secondary amines with selectivities up to 99% and turnover frequencies (TOF) up to 7200 h−1

  提出了一种使用均相铑催化通过分子氢作为还原剂对醛类进行还原胺化反应合成叔胺的方法。使用胺/醛比率为4/1时，可以由9种不同的醛和9种不同的仲胺合成叔胺，其选择性高达99％，周转频率（TOF）高达7200 h -1... 反应显示出对醇和酯功能的高耐受性，从而允许形成多功能分子。另外，仲胺也可以通过该合成来制备。对于所有化合物，活性都是通过吸收氢气来确定的。为了增加该过程的可持续性和效率，已经成功地制定了剂量策略。使用确定的反应指标，可以化学计量使用醛和胺，而不会显着降低选择性。
• Isoprene hydroamination catalyzed by palladium xantphos complexes
  作者：Bahareh Tamaddoni Jahromi、Ali Nemati Kharat、Sara Zamanian、Abolghasem Bakhoda、Kobra Mashayekh、Sadegh Khazaeli

  DOI：10.1016/j.apcata.2012.05.018

  日期：2012.8

  Xantphos or Xantphos chalcogenide complexes with general folmula [PdCl2(X∩X)] (where X = P, O, S or Se) were synthesized by the addition of corresponding ligands to [PdCl2(COD)] (COD = 1,5-cyclooctadiene). Prepared Complexes [PdCl2(Xantphos)] and [PdCl2(Xantphos = S)] showed distorted square planar geometries, from X-ray crystallographic analysis. All of the prepared complexes showed activity toward intermolecular

  通过将相应的配体添加到[PdCl 2（COD）]中，合成具有普通薄膜[PdCl 2（X∩X）]（其中X = P，O，S或Se）的Pd（II）Xantphos或Xantphos硫族化物配合物（ COD = 1,5-环辛二烯）。通过X射线晶体学分析，制备的配合物[PdCl 2（Xantphos）]和[PdCl 2（Xantphos = S）]显示出扭曲的正方形平面几何形状。所有制备的络合物均显示出对异戊二烯与多种仲胺的分子间氢化胺化的活性。使用Pd–Xantphos作为催化剂可观察到吡咯烷的完全转化（〜100％）。当使用拥挤的仲胺时，氢化胺化反应表现出区域选择性。
• [EN] CARBAZOLE COMPOUNDS AND METHODS OF USING SAME<br/>[FR] COMPOSÉS CARBAZOLE ET LEURS MÉTHODES D'UTILISATION
  申请人：OBSCHESTVO S OGRANICHENNOY OTVETSTVENNOST YU PANACELA LABS

  公开号：WO2015050471A1

  公开（公告）日：2015-04-09

  The invention relates to carbazole compounds of formula (I) that can be used for treating microbial infections, in particular, fungal infections, and selectively kill cancer cells.

  该发明涉及一种可以用于治疗微生物感染，特别是真菌感染，并且能选择性杀死癌细胞的化妆品化合物(I)。
• Chemical compound, method for the production thereof and its use in catalyst systems for producing polyolefins
  申请人：——

  公开号：US20030013913A1

  公开（公告）日：2003-01-16

  The invention relates to a chemical compound of formula (I), wherein M 1 represents an element selected from main groups II, III or IV of the periodic table of elements; x is equal to 1, 2, 3 or 4; y is equal to 2, 3 or 4, and; A represents a cation of main group V of the periodic table of elements; R 1 is the same or different and represents a branched or unbranched linear or cyclic C 1 -C 40 group that contains carbon; R 2 is the same or different and represents a branched or unbranched linear or cyclic C 1 -C 40 group that contains carbon; R 3 represents a branched or unbranched linear or cyclic C 1 -C 40 group that contains carbon, and; R 4 represents a hydrogen atom; whereby R 2 and R 3 are always different from one another.

  本发明涉及一种化学式（I）的化合物，其中M1代表元素，所选自元素周期表的主要II、III或IV族；x等于1、2、3或4；y等于2、3或4，并且A代表元素周期表的主要V族的阳离子；R1相同或不同，代表含有碳的支链或直链线性或环状C1-C40基团；R2相同或不同，代表含有碳的支链或直链线性或环状C1-C40基团；R3代表含有碳的支链或直链线性或环状C1-C40基团，且R4代表氢原子；其中R2和R3始终彼此不同。
• Aqueous ink composition for use in an ink-jet printer
  申请人：SEIKO EPSON CORPORATION

  公开号：EP0838508A2

  公开（公告）日：1998-04-29

  An aqueous ink composition for ink jet printers, which gives reliable printing performance and yields printed images which have excellent print quality and which dry rapidly is disclosed. The ink compositions are suitable for printing on plain paper. The ink comprises water as the principal solvent, an anionic colorant, pectic acid, a base, and at least one of a penetrable solvent and/or a penetrability-imparting surfactant. The pectic acid is composed primarily of α-1,4 linked polygalacturonic acid having a degree of esterification not more than 5% where the degree of esterification is defined as the percentage of the total number of galacturonic acid units in the pectic acid which are esterified.

  本发明公开了一种用于喷墨打印机的水性油墨组合物，该组合物具有可靠的打印性能，可打印出打印质量极佳且干燥迅速的图像。这种油墨组合物适用于在普通纸上打印。油墨包括作为主溶剂的水、阴离子着色剂、果胶酸、碱和至少一种可渗透溶剂和/或渗透性促进表面活性剂。果胶酸主要由α-1,4 连接的聚半乳糖醛酸组成，其酯化程度不超过 5%，其中酯化程度定义为果胶酸中酯化的半乳糖醛酸单位总数的百分比。