1-amino-3-[4-chloro-2-fluoro-5-(2-nitrophenoxy)phenyl]-6-trifluoromethyl-1,2,3,4-tetrahydropyrimidine-2,4-dione

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-amino-3-[4-chloro-2-fluoro-5-(2-nitrophenoxy)phenyl]-6-trifluoromethyl-1,2,3,4-tetrahydropyrimidine-2,4-dione
• 英文别名: 1-amino-3-[4-chloro-2-fluoro-5-(2-nitrophenoxy)phenyl]-6-(trifluoromethyl)-2,4(1H,3H)-pyrimidinedione；1-amino-3-[4-chloro-2-fluoro-5-(2-nitrophenoxy)-phenyl]-6-trifluoromethyl-2,4(1H,3H)-pyrimidinedione；1-amino-3-[4-chloro-2-fluoro-5-(2-nitrophenoxy)phenyl]-6-(trifluoromethyl)pyrimidine-2,4-dione
• 化学式: C₁₇H₉ClF₄N₄O₅
• 分子量: 460.729
• InChiKey: VOOQPCZULJLITM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  31
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  122
• 氢给体数：
  1
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  3-[4-chloro-2-fluoro-5-(2-nitrophenoxy)phenyl]-1-[(1-methylethylidene)amino]-6-trifluoromethyl-2,4(1H, 3H)-pyrimidinedione 在 盐酸 作用下， 以 甲醇 、 乙酸乙酯 为溶剂， 生成 1-amino-3-[4-chloro-2-fluoro-5-(2-nitrophenoxy)phenyl]-6-trifluoromethyl-1,2,3,4-tetrahydropyrimidine-2,4-dione
  参考文献：
  名称：

  Process for producing carbonyl hydrazones

  摘要：

  本发明涉及一种制备化合物(I)或其盐的方法：其中R1和R2中的每一个是氢，未取代或取代的烷基，未取代或取代的烯基，未取代或取代的炔基，未取代或取代的芳基，未取代或取代的杂芳基，OR3，SR3，COR3，COOR3或氰基；R1和R2可以与相邻的碳原子结合形成未取代或取代的环状环；R4和R5中的每一个是氢，未取代或取代的烷基，未取代或取代的烯基，未取代或取代的炔基，未取代或取代的芳基，未取代或取代的杂芳基，NR6R7，OR8或SR9；R4和R5可以与相邻的C/N键的骨架结合形成杂环；其包括重排化合物(II)或其盐的方法：其中R1、R2、R4和R5如上定义。

  公开号：

  US20030187264A1

文献信息

• Diaryl ethers and processes for their preparation and herbicidal and
  申请人：Ishihara Sangyo Kaisha, Ltd.

  公开号：US06121201A1

  公开（公告）日：2000-09-19

  A compound represented by the formula (I) or its salt and herbicidal and desiccant use thereof: ##STR1## wherein X, Y are independently hydrogen, halogen, cyano, nitro, or (C.sub.1-6)haloalkyl; Z is oxygen or sulfur; and Q is ##STR2##

  化合物的化学式（I）或其盐及其除草剂和脱水剂用途：##STR1##其中X，Y分别是氢，卤素，氰基，硝基或（C.sub.1-6）卤代烷基；Z是氧或硫；Q是##STR2##
• Diaryl ethers and processes for their preparation and herbicidal and desiccant compositions containing them
  申请人：ISK Americas Incorporated

  公开号：US06333296B1

  公开（公告）日：2001-12-25

  Diaryl ether compounds useful in the control of weeds are described. An exemplary compound is represented by the general formula (I): In this formula Q is represented by Q9: X and Y represent a hydrogen atom, halogen atom, cyano group, nitro group or (C1-6)haloalkyl group. A1 and A2 are independently oxygen or sulfur atoms. R9 and R10 represent a hydrogen atom, a (C1-6)alkyl group, an acyl group, or a (C1-6)alkylsulfonyl group; or R9 and R10 may form a ring consisting of polymethylene, (CH2)m groups, where m is an integer of 2, 3, 4 or 5, together with the nitrogen atom of NR9R10, which may or may not have a (C1-6)alkyl substituent. Methods of making the compounds are also described.

  描述了在除草中有用的二芳醚化合物。一个示例化合物由通用式(I)表示： 在这个式子中，Q由Q9表示： X和Y代表氢原子、卤原子、氰基、硝基或(C1-6)卤代烷基。A1和A2独立地表示氧或硫原子。R9和R10代表氢原子、(C1-6)烷基、酰基或(C1-6)烷基磺酰基；或者R9和R10可以形成由聚亚甲基(CH2)m基团组成的环，其中m是2、3、4或5的整数，与NR9R10的氮原子一起，该氮原子可能具有或不具有(C1-6)烷基取代基。还描述了制备这些化合物的方法。
• Processes for preparing 3-phenyl-2,4(1H, 3H)-pyrimidinediones
  申请人：ISHIHARA SANGYO KAISHA, LTD.

  公开号：US20030096990A1

  公开（公告）日：2003-05-22

  A process for producing 3-phenyl-2,4(1H,3H)-pyrimidinediones having the general formula I and their salts 1 which comprises reacting the isocyanates represented by the general formula (II) 2 and the substituted hydrazono esters represented by the general formula (III) 3 in the presence of a base. These compounds are useful as herbicides, defoliants and desiccants.

  一种制备具有一般式I及其盐的3-苯基-2,4(1H,3H)-嘧啶二酮的方法，其包括在碱存在下，反应由一般式(II)2表示的异氰酸酯和由一般式(III)3表示的取代的酰肼酯。这些化合物可用作除草剂、落叶剂和干燥剂。
• Herbicidal composition
  申请人：——

  公开号：US20020107148A1

  公开（公告）日：2002-08-08

  The present invention provides to a herbicidal composition comprising as the effective components A) at least one substituted acetanilide derivative of the formula I: 1 wherein n is an integer of 1 or 2 R is H, halogen, C 1-4 alkyl or C 1-2 alkoxy Q is cyanomethyl or propargyl X is halogen B) at least one compound selected from the group consisting of aryloxyalkanoic acids, aromatic carboxylic acids, ureas, triazines, anilides, hydroxybenzonitriles, quaternary ammonium salts, triketones, aryloxyphenoxypropionic acids, oximes, sulfonylureas, imidazolinones, dinitroanilines, chloroacetanilides, oxyacetamides, thiocarbamates, amides, semicarbazones, amino acids, and inhibitors of protoporphyrinogen oxidase that includes diphenyl ethers, substituted uracils, pyrazoles, triazolinones and triazolopyridinones.

  本发明提供了一种除草组合物，其有效成分包括 A) 至少一种式 I 的取代乙酰苯胺衍生物： 1 其中 n 是 1 或 2 的整数 R 是 H、卤素、C 1-4 烷基或 C 1-2 烷氧基 Q 是氰甲基或丙炔基 X 是卤素 B) 至少一种选自以下组别的化合物：芳氧基烷酸、芳香族羧酸、脲类、三嗪类、苯胺类、羟基苯甲腈类、季铵盐类、三酮类、芳氧基苯氧基丙酸、肟类、磺酰脲类、咪唑啉酮类、二硝基苯胺类、氯乙酰苯胺类、氧乙酰胺类、硫代磷酸酯类、酰胺类、酰胺类、酰胺类、酰胺类、酰胺类、酰胺类、酰胺类、酰胺类、酰胺类、酰胺类、酰胺类咪唑啉酮类、二硝基苯胺类、氯乙酰苯胺类、氧乙酰胺类、硫代氨基甲酸酯类、酰胺类、半咔唑类、氨基酸类，以及原卟啉原氧化酶抑制剂，包括二苯醚类、取代的尿嘧啶类、吡唑类、三唑啉酮类和三唑吡啶酮类。
• DIARYL ETHERS AND PROCESSES FOR THEIR PREPARATION AND HERBICIDAL AND DESICCANT COMPOSITIONS CONTAINING THEM
  申请人：ISK Americas Incorporated

  公开号：EP0973395A1

  公开（公告）日：2000-01-26