2-(4-methylphenyl)-2-(4-hydroxyphenyl)-1,1,1,3,3,3hexafluoropropane

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(4-methylphenyl)-2-(4-hydroxyphenyl)-1,1,1,3,3,3hexafluoropropane
• 英文别名: 2-(4-hydroxyphenyl)-2-(4-methylphenyl)hexafluoropropane；4-[1,1,1,3,3,3-hexafluoro-2-(4-methylphenyl)propan-2-yl]phenol
• 化学式: C₁₆H₁₂F₆O
• 分子量: 334.261
• InChiKey: SFWSTTWKVLWJNE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  23
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  1,3-二硝基苯 、 2-(4-methylphenyl)-2-(4-hydroxyphenyl)-1,1,1,3,3,3hexafluoropropane 在 potassium carbonate 作用下， 以 N-甲基乙酰胺 为溶剂， 生成 2-(4-methylphenyl)-2-[4-(3-nitrophenoxy)phenyl]hexafluoropropane
  参考文献：
  名称：

  Hexafluoroisopropyl-containing monomers, process for their preparation

  摘要：

  式I的化合物可以通过从2-(4-甲基苯基)-2-六氟异丙醇中进行各种工艺步骤来制备。含六氟异丙基的单体是制备线性聚酰胺和聚酰亚胺的重要起始化合物。

  公开号：

  US05110983A1
• 作为产物：
  描述：

  六氟-2-(对甲苯基)异丙醇 、 苯酚 以84%的产率得到
  参考文献：
  名称：

  LAU, JURGEN;SIEGEMUND, GUNTER;ROHRSCHEID, FREIMUND

  摘要：

  DOI：

文献信息

• PROCESS FOR MAKING BENZOXAZINES
  申请人：Cytec Industries Inc.

  公开号：US20160115139A1

  公开（公告）日：2016-04-28

  A synthesis process for making a benzoxazine compound containing at least one benzoxazine unit from aromatic amine containing at least one primary amino group, at least one phenolic compound with at least one ortho-hydrogen, and alkyl formcel. In one embodiment, the aromatic amine is reacted with alkyl formcel to generate an alkoxymethyl intermediate compound. Subsequently, the intermediate compound is reacted with a phenol to generate the benzoxazine compound. In another embodiment, the benzoxazine compound is formed by reacting aromatic amine with alkyl formcel and phenol in one reaction step. Also disclosed is a method for isolating the alkoxymethyl compound formed by reacting aromatic amine with alkyl formcel. The isolated alkoxymethyl compound is useful as a reactant in a subsequent reaction.

  一种合成过程，用于从含有至少一个苯并噁嗪单元的芳香胺，至少含有一个一级氨基的芳香胺，至少含有一个邻位氢的酚类化合物和烷基甲醛制备含有至少一个苯并噁嗪单元的苯并噁嗪化合物。在一种实施方式中，将芳香胺与烷基甲醛反应以生成烷氧甲基中间体化合物。随后，将中间体化合物与酚反应以生成苯并噁嗪化合物。在另一种实施方式中，通过在一个反应步骤中将芳香胺与烷基甲醛和酚反应来形成苯并噁嗪化合物。还公开了一种方法，用于分离由芳香胺与烷基甲醛反应形成的烷氧甲基化合物。分离的烷氧甲基化合物可用作随后反应中的反应物。
• MELAMINE PHENYLPHOSPHONATE FLAME RETARDANT COMPOSITIONS
  申请人：Fuchs Sabine

  公开号：US20110266507A1

  公开（公告）日：2011-11-03

  The present invention relates to flame retardant polymer compositions which comprise melamine phenylphosphonates and mixtures with dihydro-oxa-phosphaphenanthrene derivatives. The compositions are especially useful for the manufacture of flame retardant compounds based on polyfunctional epoxides or polycondensates like polyesters, polyamides and polycarbonates.

  本发明涉及阻燃聚合物组合物，其包括三聚氰胺苯基膦酸盐和与二氢氧磷菲衍生物混合物。该组合物特别适用于基于多功能环氧化合物或聚酯，聚酰胺和聚碳酸酯的阻燃化合物的制造。
• MELAMINE PHENYLPHOSPHINATE FLAME RETARDANT COMPOSITIONS
  申请人：Fuchs Sabine

  公开号：US20110288206A1

  公开（公告）日：2011-11-24

  The present invention relates to flame retardant polymer compositions which comprise melamine phenylphosphinates and mixtures with dihydro-oxa-phosphaphenanthrene derivatives. The compositions are especially useful for the manufacture of flame retardant compounds based on polyfunctional epoxides or polycondensates like polyesters, polyamides and polycarbonates.

  本发明涉及一种阻燃聚合物组合物，其包括三聚氰胺苯基膦酸盐和二氢氧化磷酞类衍生物的混合物。该组合物特别适用于制造基于多官能团环氧树脂或聚酯、聚酰胺和聚碳酸酯的阻燃化合物。
• PHENYLPHOSPHONATE FLAME RETARDANT COMPOSITIONS
  申请人：Xalter Rainer

  公开号：US20120108712A1

  公开（公告）日：2012-05-03

  The present invention relates to flame retardant polymer compositions which comprise mixtures of melamine or guanidine phenylphosphonates and mixtures with 2,2,6,6-tetraalkyl-piperidines. The mixtures are especially useful for the manufacture of flame retardant compositions based on thermoplastic polymers.

  本发明涉及阻燃聚合物组合物，其包含三聚氰胺或鸟氨酸苯基膦酸盐和2,2,6,6-四烷基哌啶的混合物。这些混合物特别适用于基于热塑性聚合物的阻燃组合物的制造。
• AMINOGUANIDINEPHENYLPHOSPHINATE FLAME RETARDANT COMPOSITIONS
  申请人：Xalter Rainer

  公开号：US20130105745A1

  公开（公告）日：2013-05-02

  The present invention relates to flame retardant polymer compositions which comprise aminoguanidine phenylphosphinates and mixtures with additional flame retardants. The compositions are especially useful for the manufacture of flame retardant compounds based on polyfunctional epoxides or polycondensates like polyesters, polyamides and polycarbonates.

  本发明涉及含有氨基胍苯基膦酸盐和其他阻燃剂混合物的阻燃聚合物组合物。该组合物特别适用于制造基于多官能团环氧树脂或聚酯、聚酰胺和聚碳酸酯的阻燃化合物。