Retropinacol/Cross-Pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols
作者:Ulf Scheffler、Reinhard Stößer、Rainer Mahrwald
DOI:10.1002/adsc.201200358
日期:2012.10.8
A new concept to access unsymmetrical 1,2-diols with high yields is reported. This new methodology is based on a retropinacol/cross-pinacol coupling process. This transformation is characterized by its operational simplicity and very mild reaction conditions.
报道了一种以高收率获得不对称1,2-二醇的新概念。这种新的方法基于逆频哪醇/跨频哪醇耦合过程。该转化的特征在于其操作简单和非常温和的反应条件。