六氟-2,2-双(4-甲基丙烯醛基氧基苯基)丙烷 | 108050-42-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 六氟-2,2-双(4-甲基丙烯醛基氧基苯基)丙烷
• 英文名称: hexafluorobisphenol A dimethacrylate
• 英文别名: Hexafluoro-2,2-bis(4-methacryloxyphenyl)propane；[4-[1,1,1,3,3,3-hexafluoro-2-[4-(2-methylprop-2-enoyloxy)phenyl]propan-2-yl]phenyl] 2-methylprop-2-enoate
• CAS: 108050-42-6
• 化学式: C₂₃H₁₈F₆O₄
• mdl: MFCD00080522
• 分子量: 472.384
• InChiKey: AAOHKRNFHQXDFX-UHFFFAOYSA-N

物化性质

• 沸点：
  457.3±45.0 °C(Predicted)
• 密度：
  1.288±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.3
• 重原子数：
  33
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.217
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  10

安全信息

• 危险品标志：
  F
• 危险类别码：
  R36/37/38

反应信息

• 作为产物：
  描述：

  六氟双酚 A 生成 六氟-2,2-双(4-甲基丙烯醛基氧基苯基)丙烷
  参考文献：
  名称：

  KONDO, TADAO;MATSUDA, TATEHXITO;FUNAEH, YASUAKI;TAKATANI, AKIO

  摘要：

  DOI：

文献信息

• Silicon-containing compound and ocular lens material
  申请人：Menicon Co., Ltd.

  公开号：EP0781777A1

  公开（公告）日：1997-07-02

  A silicon-containing compound of the formula (I): wherein R1 is a C1-6 alkylene group; A is a group of the formula (II): wherein R2 is a hydrogen atom or a methyl group, R3 is a C1-6 trivalent hydrocarbon group or a C1-6 bivalent hydrocarbon group when R4 is a hydrogen atom, and R4 is a hydrogen atom, a hydroxyl group, a C1-6 alkyl group or a group of the formula (III): wherein R5 is a C1-6 alkylene group, and m is an integer of from 1 to 15, or a group of the formula (IV): wherein R6 is a hydrogen atom or a methyl group, and R7 is a direct bond or a C1-6 alkylene group; and n is an integer of from 1 to 15.

  化合物的化学式为（I）：其中R1是C1-6烷基；A是化学式（II）的基团：其中R2是氢原子或甲基基团，R3是C1-6三价碳氢基团或C1-6二价碳氢基团（当R4是氢原子时），而R4是氢原子、羟基、C1-6烷基或化学式（III）的基团：其中R5是C1-6烷基，m是1至15的整数，或化学式（IV）的基团：其中R6是氢原子或甲基基团，R7是直接键或C1-6烷基，n是1至15的整数。
• Dental material
  申请人：DAIKIN INDUSTRIES, LIMITED

  公开号：EP0305954A1

  公开（公告）日：1989-03-08

  A dental material comprising a copolymer which contains at least 10% by weight of at least one structural unit derived from the following monomers wherein R¹ and R² are each H, CH₃ or CF₃, R³ is H, CH₃ or F, A is -CH₂-, -CH₂CH₂-, -CH₂CH(CH₃)-, -CH(OH)-, -CH₂CH(OH)CH₂-, -CH(OCOCH₃)- or -CH₂CH(OCOCH₃)CH₂-, A′ is the same group as A or -CH₂CH₂CH₂-, B is alkylene group having 2 to 10 carbon atoms, m and n are each zero or a number of 1 to 5, p is a number of 1 to 3, q is a number of 1 to 5, provided that at least one of R¹ and R² is CF₃ when R³ is H or CH₃.

  一种牙科材料，包含一种共聚物，该共聚物含有至少 10%（按重量计）由以下单体衍生的至少一种结构单元 -CH(OH)-、-CH₂CH(OH)CH₂-、-CH(OCOCH₃)-或-CH₂CH(OCOCH₃)CH₂-，A′是与 A 相同的基团或-CH₂CH₂CH₂-、B 是具有 2 至 10 个碳原子的亚烷基，m 和 n 分别为零或 1 至 5 的数字，p 是 1 至 3 的数字，q 是 1 至 5 的数字，条件是当 R³ 是 H 或 CH₃ 时，R¹ 和 R² 中至少有一个是 CF₃。
• Soft ocular lens material
  申请人：Menicon Co., Ltd.

  公开号：EP0379146A2

  公开（公告）日：1990-07-25

  A soft ocular lens material made of a copolymer consisting essentially of: (A) from 5 to 70 parts by weight of a fluorine-­containing (meth)acrylate; (B) from 5 to 60 parts by weight of an alkyl (meth)acrylate; (C) from 3 to 45 parts by weight of a polysiloxane macromonomer having polymerizable groups at both terminals, of the formula I: wherein each of Y¹¹ and Y¹² independently represents an acryloyl group, a methacryloyl group, a vinyl group or an allyl group; each of X¹¹ and X¹² independently represents a covalent bond, an oxygen atom or an alkylene glycol group; each of R¹¹ and R¹² independently represents a linear or branched alkylene group having from 1 to 6 carbon atoms; each of R¹³, R¹⁴, R¹⁵, R¹⁶, R¹⁷ and R¹⁸ independently represents an alkyl group having from 1 to 3 carbon atoms or a phenyl group; i is an integer of from 1 to 1500; and j is an integer of from 0 to 1499 (provided that i+j is at most 1500); and (D) from 3 to 40 parts by weight of a polysiloxane macromonomer having polymerizable groups bonded via one or two urethane bonds to the siloxane main chain, of the formula II: wherein each of Y²¹ and Y²² independently represents a group selected from the group consisting of an acryloyloxy group, a methacryloyloxy group, a vinyl group and an allyl group; each of R³¹ and R³⁴ independently represents a linear or branched alkylene group having from 2 to 6 carbon atoms; each of X²¹ and X²² independently represents a covalent bond, an oxygen atom or an alkylene glycol group; each of R³² and R³³ independently represents a linear or branched alkylene group having from 1 to 6 carbon atoms; each of R²³, R²⁴, R²⁵, R²⁶, R²⁷ and R²⁸ independently represents an alkyl group having from 1 to 3 carbon atoms or a phenyl group; each of E²¹ and E²² independently represents -NHCO- (provided that in this case, each of X²¹ and X²² is a covalent bond, E²¹ forms a urethane bond together with X²⁵, and E²² forms a urethane bond together with X²⁶) or a bivalent group derived from a diisocyanate selected from the group consisting of saturated aliphatic, alicyclic and aromatic diisocyanates (provided that in this case, each of X²¹ and X²² independently represents an oxygen atom or an alkylene glycol group, E²¹ forms a urethane bond together With X²¹ and X²⁵, and E²² forms a urethane bond together with X²² and X²⁶); each of X²⁵ and X²⁶ independently represents an oxygen atom, an alkylene glycol or a group represented by the formula V: wherein R⁴¹ is a trivalent hydrocarbon group having from 1 to 6 carbon atoms; Y²³ represents a group selected from the group consisting of an acryloyloxy group, a methacryloyloxy group, a vinyl group and a allyl group; R³⁶ represents a linear or branched alkylene group having from 2 to 6 carbon atoms; X²³ represents a covalent bond, an oxygen atom or an alkylene glycol group; E²³ represents -NHCO- (provided that in this case, X²³ is a covalent bond) or a bivalent group derived from a diisocyanate selected from the group consisting of saturated aliphatic, alicyclic and aromatic diisocyanates (provided that in this case, X²³ is an oxygen atom or an alkylene glycol group), which forms a urethane bond together with X²³ and the adjacent oxygen atom bonded to R⁴¹; a is an integer of from 1 to 1500; and b is an integer of from 0 to 1499, provided a+b ≦ 1500; as essential copolymer components.

  一种由共聚物制成的软性眼透镜材料，其主要成分包括 (A) 5 至 70 份(重量)含氟(甲基)丙烯酸酯； (B) 5 至 60 份（按重量计）烷基（甲基）丙烯酸酯； (C) 3 至 45 份（按重量计）在两端具有可聚合基团的聚硅氧烷大单体，其式为 I： 其中 Y¹¹ 和 Y¹² 各自独立地代表丙烯酰基、甲基丙烯酰基、乙烯基或烯丙基； X¹¹ 和 X¹² 各自独立地代表共价键、氧原子或亚烷基二醇基； R¹¹ 和 R¹² 各自独立地代表具有 1 至 6 个碳原子的直链或支链亚烷基；R¹³、R¹⁴、R¹⁵、R¹⁶、R¹⁷ 和 R¹⁸ 各自独立地代表具有 1 至 3 个碳原子的烷基或苯基； i 是 1 至 1500 的整数；和 j 是 0 至 1499 的整数（条件是 i+j 至多为 1500）；和 (D) 3 至 40 份(重量)的聚硅氧烷大单体，其可聚合基团通过一个或两个 聚氨酯键与硅氧烷主链结合，如式 II 所示： 其中 Y²¹ 和 Y²² 各自独立地代表选自丙烯酰氧基、甲基丙烯酰氧基、乙烯基和烯丙基的基团； R³¹ 和 R³⁴ 各自独立地代表具有 2 至 6 个碳原子的直链或支链亚烷基；X²¹和X²²各自独立地代表共价键、氧原子或烯二醇基团；R³²和R³³各自独立地代表具有1至6个碳原子的直链或支链亚烷基；R²³、R²⁴、R²⁵、R²⁶、R²⁷和R²⁸各自独立地代表具有1至3个碳原子的烷基或苯基；E²¹ 和 E²² 中的每一个独立地代表-NHCO-（条件是在这种情况下，X²¹ 和 X²² 中的每一个是共价键，E²¹ 与 X²⁵ 一起形成氨基甲酸乙酯键，E²² 与 X²⁶ 一起形成氨基甲酸乙酯键）或衍生自二异氰酸酯的二价基团，该二异氰酸酯选自由饱和脂肪族、脂环族和芳香族二异氰酸酯组成的组、或衍生自二异氰酸酯的二价基团，该二异氰酸酯选自饱和脂肪族、脂环族和芳香族二异氰酸酯（条件是在这种情况下，X²¹ 和 X²² 各自独立地代表氧原子或亚烷基二醇基团，E²¹ 与 X²¹ 和 X²⁵ 形成氨基甲酸乙酯键，E²² 与 X²² 和 X²⁶ 形成氨基甲酸乙酯键）；X²⁵ 和 X²⁶ 各自独立地代表氧原子、亚烷基二醇或式 V 所代表的基团： 其中 R⁴¹ 是具有 1 至 6 个碳原子的三价烃基；Y²³ 代表选自丙烯酰氧基、甲基丙烯酰氧基、乙烯基和烯丙基的基团；R³⁶ 代表具有 2 至 6 个碳原子的直链或支链亚烷基；X²³ 代表共价键、氧原子或亚烷基二醇基团；E²³代表-NHCO-（条件是在这种情况下，X²³是共价键）或二异氰酸酯衍生的二价基团，该二异氰酸酯选自饱和脂肪族、脂环族和芳香族二异氰酸酯（条件是在这种情况下，X²³是氧原子或亚烷基二醇基）组成的组，它与 X²³和与 R⁴¹ 结合的相邻氧原子一起形成氨基甲酸酯键；a 是 1 至 1500 的整数；b 是 0 至 1499 的整数，条件是 a+b ≦ 1500； 作为共聚物的基本成分。
• Highly oxygen-permeable heat-resistant material
  申请人：Menicon Co., Ltd.

  公开号：EP0722959A2

  公开（公告）日：1996-07-24

  A highly oxygen-permeable heat-resistant material consisting essentially of a polymer obtained by polymerizing a polymerizable component containing a silicon-containing stilbene derivative of the formula (I): wherein each of R1 and R2 which are independent of each other, is a hydrogen atom or a group of the formula (II):         -SipOp-1(CH3)2p+1     (II) wherein p is an integer of from 1 to 8, provided that at least one of R1 and R2 is the group of the formula (II).

  一种高透氧性耐热材料，主要由一种聚合物组成，该聚合物通过聚合含有式 (I) 的含硅二苯乙烯衍生物的可聚合组分而获得： 其中相互独立的 R1 和 R2 均为氢原子或式（II）的基团： -SipOp-1(CH3)2p+1 (II) 其中 p 为 1 至 8 的整数，条件是 R1 和 R2 中至少有一个是式 (II) 所示的基团。
• Ocular lens and a method for its production
  申请人：Menicon Co., Ltd.

  公开号：EP0794440A2

  公开（公告）日：1997-09-10

  An ocular lens obtained by reacting a hydroxyl group-containing polymer shaped to have an ocular lens shape, with a silicon-containing compound of the formula (I):         O=C=N-R1-SinOn-1(CH3)2n+1     (I) wherein R1 is a C1-6 linear or branched alkylene group, and n is an integer of from 1 to 15.

  一种眼球晶状体，由具有眼球晶状体形状的含羟基聚合物与式 (I) 的含硅化合物反应而得： O=C=N-R1-SinOn-1(CH3)2n+1 (I) 其中 R1 为 C1-6 直链或支链亚烷基，n 为 1 至 15 的整数。