Abstract Chlorine trioxide Cl 2 O 6 added on an excess of TiCl 4 gives a series of anhydrous oxo-chloro-perchlorato complexes of titanium IV corresponding to the formula: Ti 6 O 4 Cl x (ClO 4 ) 16−x . x increases with the molar ratio TiCl 4 : Cl 2 O 6 and reaction time. Infrared and Raman spectra of these compounds are consistent with polymeric structure containing bridging bidentate perchlorato groups
摘要 在过量的 TiCl 4 上加入三氧化
氯 Cl 2 O 6 得到一系列无
水四
氧化钛的氧代-
氯-高
氯根配合物,其对应式为:Ti 6 O 4 Cl x (ClO 4 ) 16-x 。x随着摩尔比TiCl 4 :Cl 2 O 6 和反应时间而增加。这些化合物的红外和拉曼光谱与包含与
金属牢固结合的桥接双齿高
氯根基团的聚合物结构一致。