(Z)-2-(4-Hydroxyphenyl)-3-(4-methylphenyl)acrylonitrile

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: (Z)-2-(4-Hydroxyphenyl)-3-(4-methylphenyl)acrylonitrile
• 英文别名: p-hydroxy-p'-methyl-α-cyanostilbene；(Z)-2-(4-hydroxyphenyl)-3-(4-methylphenyl)prop-2-enenitrile
• 化学式: C₁₆H₁₃NO
• 分子量: 235.285
• InChiKey: JLCDJRCYTQLCQR-XNTDXEJSSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  44
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (Z)-2-(4-Hydroxyphenyl)-3-(4-methylphenyl)acrylonitrile 在 六氯环三磷腈 、 sodium hydride 作用下， 以 四氢呋喃 、 mineral oil 为溶剂， 反应 48.0h， 以92%的产率得到2,2,4,4,6,6-hexakis[4-((Z)-1-cyano-2-p-tolylvinyl)phenoxy]cyclotriphosphazene
  参考文献：
  名称：

  Synthesis of Cyclotriphosphazenes Containing Cyanostilbenes with Different Terminal Substituents

  摘要：

  The synthesis and mesomorphic properties of a class of cyclotriphosphazenes containing cyanostilbene groups with different terminal substituents (-H, -CH3, -OCH3, -CN) are described. All the resulting compounds are characterized by H-1, C-13, and P-31 NMR, matrix-assisted laser desorption/ionization time of flight, and elemental analysis. The thermal behaviors of cyclotriphosphazene derivatives are studied by the means of differential scanning calorimetry and polarizing optical microscopy. Nematic phases are observed in cyclotriphosphazenes with terminal substituents (-CH3, -OCH3, CN).

  DOI：

  10.1080/00397911.2010.542861
• 作为产物：
  描述：

  (Z)-2-(4-methoxyphenyl)-3-(p-tolyl)acrylonitrile 生成 (Z)-2-(4-Hydroxyphenyl)-3-(4-methylphenyl)acrylonitrile
  参考文献：
  名称：

  Koide, Naoyuki; Iimura, Kazuyoshi, Molecular Crystals and Liquid Crystals (1969-1991), 1988, vol. 153, p. 73 - 82

  摘要：

  DOI：

文献信息

• Koide, Naoyuki; Iimura, Kazuyoshi, Molecular Crystals and Liquid Crystals (1969-1991), 1988, vol. 153, p. 73 - 82
  作者：Koide, Naoyuki、Iimura, Kazuyoshi

  DOI：——

  日期：——
• Synthesis of Cyclotriphosphazenes Containing Cyanostilbenes with Different Terminal Substituents
  作者：Rui Bao、Min Pan、Yun Zhou、Jin-Jun Qiu、He-Qing Tang、Cheng-Mei Liu

  DOI：10.1080/00397911.2010.542861

  日期：2012.6

  The synthesis and mesomorphic properties of a class of cyclotriphosphazenes containing cyanostilbene groups with different terminal substituents (-H, -CH3, -OCH3, -CN) are described. All the resulting compounds are characterized by H-1, C-13, and P-31 NMR, matrix-assisted laser desorption/ionization time of flight, and elemental analysis. The thermal behaviors of cyclotriphosphazene derivatives are studied by the means of differential scanning calorimetry and polarizing optical microscopy. Nematic phases are observed in cyclotriphosphazenes with terminal substituents (-CH3, -OCH3, CN).