sodium O,O'-diphenyldithiophosphate

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: sodium O,O'-diphenyldithiophosphate
• 英文别名: diphenyldithiophosphoric acid sodium salt；sodium diphenyl dithiophosphate；NaS2P(OPh)2；Natrium O,O'-Diphenyldithiophosphate；Sodium;diphenoxy-sulfanylidene-sulfido-lambda5-phosphane；sodium;diphenoxy-sulfanylidene-sulfido-λ5-phosphane
• 化学式: C₁₂H₁₀O₂PS₂*Na
• 分子量: 304.306
• InChiKey: RIFVZYDFHBELKB-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.92
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  sodium O,O'-diphenyldithiophosphate 以 乙醇 、 水 为溶剂， 生成 bis(O,O-diphenyldithiophosphato)bis(1,10-phenanthroline) silver(I)
  参考文献：
  名称：

  Structure and Properties Characteristic of Dimeric Silver(I) Complex: Dinuclear Bis(O,O′-Diphenyldithiophosphato)bis(1,10-phenanthroline) Ag(I)

  摘要：

  The complex bis(O,O'-diphenyldithiophosphato)bis(1,10-phenanthroline) silver(I), Ag-2[(Pho)(2)PS2](2)(Phen)(2), has been synthesized and structurally characterized. Its crystal structure has been determined by X-ray crystallography. It crystallizes in the monoclinic system, space group P2(1)/c, with unit cell parameters a = 11.140(2) Angstrom, b = 10.044(2) Angstrom, c = 23.006(6) Angstrom, beta = 113.36(3)degrees; V = 2363.1(9) Angstrom(3), rho(calcd) = 1.600g/cm(3), and Z = 4 for R-1 = 0.0961. The coordination geometry of each Ag atom, by two N atoms from 1,10-phenanthroline ligand and by two S atoms from two O,O'-diphenyldithiophosphate anions, is that of a tetrahedron. The two diphenyldithiophosphato ligands each bridge two silver atoms to form an eight-membered Ag2S4P2 ring, while the 1,10-phenanthroline molecule coordinates to a silver atom to complete the local tetrahedral geometry. The (AgAg)-Ag-... separation is 3.185(2) Angstrom. The data of elemental analysis, IR and UV-vis spectroscopies are in good agreement with the crystal structure. The thermal gravimetry data indicate that there are two decomposition steps with one intense endothermical peak and one weak exothermical peak. The final product of the thermal decomposition is AgS.

  DOI：

  10.1023/b:ruco.0000047467.29853.07

文献信息

• Synthesis, characterization, and antimicrobial activites of some dithiophosphate silane complexes
  作者：Adnan A.S. El khaldy、Afef Janen、Alaa Abushanab、Ebony Stallworth

  DOI：10.1515/mgmc-2015-0029

  日期：2016.1.1

  Abstract The compounds MeCl2Si[S2P(OR)2], MeClSi[S2POGO]2, and MeSi[S2P(OR)2]3 (where R=Et, n-Pr, i-Pr, i-Bu, and Ph; G=-CH2CMe2CH2-, -CH2CEt2CH2-, and -CMe2CMe2-) have been prepared by reacting the sodium salt of the appropriate dithiophosphoric acid or the acid itself with MeSiCl3 in 1:1, 1:2, and 1:3 molar ratios, in benzene, at reflux. These compounds are yellow oily liquids and soluble in common

  摘要 化合物 MeCl2Si[S2P(OR)2]、MeClSi[S2POGO]2 和 MeSi[S2P(OR)2]3（其中 R=Et、n-Pr、i-Pr、i-Bu 和 Ph；G =-CH2CMe2CH2-、-CH2CEt2CH2- 和 -CMe2CMe2-) 是通过适当的二硫代磷酸的钠盐或酸本身与 MeSiCl3 以 1:1、1:2 和 1:3 的摩尔比反应制备的，在苯，回流。这些化合物是黄色油状液体，可溶于普通有机溶剂。分子量测定对应于单体。这些化合物已通过元素分析和 1H、13C、29Si 和 31P NMR 光谱表征。配体以单齿模式与硅原子配位，而硅原子又显示出四面体环境。筛选这些复合物的抗菌活性得到了积极的结果。
• Synthetic, spectroscopic, X-ray structural and antimicrobial studies of 1,3-dithia-2-stibacyclopentane derivatives of phosphorus based dithiolato ligands
  作者：H.P.S. Chauhan、U.P. Singh、N.M. Shaik、S. Mathur、V. Huch

  DOI：10.1016/j.poly.2006.04.027

  日期：2006.11

  ratio in anhydrous benzene solution. These yellow crystalline solid/semi-solid derivatives have been characterized by elemental analysis (C, H, S and Sb), molecular weights, melting point as well as spectral [UV, IR and NMR (1H, 13C and 31P)] studies. Single crystal X-ray diffraction analyses of 1,3-dithia-2-stibacyclopentane 2,3-butylenedithiophosphate revealed a monodentate mode of bonding of the dithiophosphate

  某些具有SCH2CH2SS¯bS（S）POGO类型的磷基二硫代lato配体的混合1,3-二硫代-2-stibacyclopentane衍生物（其中G = CH（Me）CH（Me）和C（Me）2 C（Me）2 }和SCH2CH2SS′bS（S）P（OR）2 其中R = Pr n，Bu n和Ph}是通过2-氯-1,3-二硫代-2-stibacyclopentane与铵/在无水苯溶液中等摩尔比的相应磷基配体的钠盐。这些黄色结晶固体/半固体衍生物已通过元素分析（C，H，S和Sb），分子量，熔点以及光谱[UV，IR和NMR（1 H，13 C和31）进行了表征。P）]研究。1,3-二硫代-2-苯乙烯基环戊烷2,3-丁二硫代磷酸酯的单晶X射线衍射分析表明，该配合物中二硫代磷酸酯配体的单齿键合方式。还已经筛选了游离配体及其锑（III）配合物的抗菌和抗真菌活性。
• Molecular Pharmacological Studies on Drug-Receptor Complexes System in Drug Action. IV. Relationship between Anticholinergic and Anticholinesterase Activities of Organophosphoryl Choline Derivatives based on their Chemical Structure
  作者：Masayasu Kimura、Isamu Saikawa

  DOI：10.1248/cpb.12.159

  日期：——

  To clarify the relationship between anticholinergic and anticholinesterase (anti-ChE) activities on the basis of chemical structure, nineteen organophosphoryl choline derivatives [chemical formula] were synthesized. Curare-like, atropine-like and anticholinesterase actions of these compounds were tested to screen. The experimental results were as follows : 1) Curare-like and atropine-like actions were both studied by Magnus method, observing their effect on rectus abdominis of frog and on intestines of white mice. Anti-ChE action on enzyme preparation from rabbit serum was tested by using Warburg's manometric method. 2) As to the basic structure of various organophosphoryl choline derivatives, curarelike action was increased in the following order of magnitude ; [chemical formula]. The R radicals increased the potency in the following order ; [chemical formula] and as for quaternary ammonium salts of derivatives, bromides were more potent than iodides. From these compounds it was found that four derivatives of NP-244 (I), NP-245 (I), NP-244pC (I) and NP244pB (I) was more potent than curare. 3) On the atropine-like action of organophosphoryl choline derivatives, the relation between their structure and potency was found to have the same tendency as in the case of curare-like action, but all of these derivative were weaker than that of atropine. 4) On the anti-ChE action of organophosphoryl choline, the basic structures increased its potency in the following order ; [chemical formula], but the change in R radicals did not always increase the potency of their curare-like action. All of these derivatives were weaker than neostigmine. 5) The relationship between curare-like and atropine-like actions and between curare-like and anti-ChE actions were discussed with the selective indexes calculated from experimental results. Some of thionothiol-phosphate have both curare-like and ChE activity, and its curare-like action is little antagonized by neostigmine. From these facts, it was suggested that acetylcholine receptor was perhaps different from ChE.

  羧胺。
• Stabilization of aqueous polymers in the presence of hydroxylamine
  申请人：CYTEC TECHNOLOGY CORP.

  公开号：EP0514649A1

  公开（公告）日：1992-11-25

  Aqueous solutions of polymers containing hydroxylamine are stabilized against viscosity degradation by adding a stabilizer thereto.

  在含有羟胺的聚合物水溶液中加入稳定剂，可防止粘度下降。
• Synthesis and Characterization of Unsymmetrical I-Bromo-3- (Dialkyl or Alkylene Dithiophosphato)Tetrabutyldistannoxanes
  作者：A. A. S. El-Khaldy

  DOI：10.1080/00945719909349478

  日期：1999.4