十三烷-1-基苯磺酸酯 | 25474-61-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 十三烷-1-基苯磺酸酯
• 英文名称: Tridecan-1-yl benzenesulphonate
• 英文别名: tridecyl benzenesulfonate
• CAS: 25474-61-7
• 化学式: C₁₉H₃₂O₃S
• 分子量: 340.5
• InChiKey: KRTNITDCKAVIFI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.3
• 重原子数：
  23
• 可旋转键数：
  14
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.68
• 拓扑面积：
  51.8
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• Method for the neutralization of an A-zeolite filter cake
  申请人：ZEOLITE MIRA s.r.l.

  公开号：EP0175090A1

  公开（公告）日：1986-03-26

  57 The filter press cake, obtained by separation of the raw Zeolite from the major portion of the mother liquor and not washed, or only partially washed, is additivated with a suitable surface-active agent, added in the amount of from 1 to 2% in weight on the weight of the wet Zeolite. The thus- fluidized Zeolite is treated in a high-turbulence zone with sulphunc acid at a concentration greater than 70%, which is added in such an amount as to produce a nearly complete neutralization of the final Zeolite.

  57 将未加工的沸石从母液的主要部分中分离出来后得到的压滤机滤饼，未经水洗或仅部分水洗，用适当的表面活性剂进行添加活化，添加量为湿沸石重量的 1% 至 2%。 这样流化的沸石在高湍流区用浓度大于 70% 的硫酸进行处理，硫酸的添加量可使最终的沸石几乎完全中和。
• N-alkyl neoalkanamide insect repellents
  申请人：Colgate-Palmolive Company

  公开号：EP0367257A1

  公开（公告）日：1990-05-09

  N-lower alkyl neoalkanamides (N-lower alkyl trialkyl­acetamides of certain types) of 1 to 4 carbon atoms in the lower alkyl thereof and of 5 to 14 carbon atoms in the neoalkanoyl (or trialkylacetyl) group, e.g., N-methyl- and N-ethyl neodecan­amides and N-methyl and N-ethyl neotridecanamides, are new compounds, secondary amides which have insect repellent properties, being especially effective against cockroaches, e.g., the German cockroach. However, they are also useful as repellents for other insects, including American cockroaches, mosquitoes, flies, fleas, ants, and lice. Additionally, they may repel arachnids, such as spiders, ticks and mites. The new neoalkanamides may be synthesized easily, as by reacting a primary lower alkyl amine with a neoalkanoyl halide, e.g. by reacting methyl amine or ethyl amine with neodecanoyl chloride. The most effective of the described amides for insect repellency are normally liquid and are sufficiently volatile to be detectable in air by insects. They may be applied directly to surfaces to be treated or they may be incorporated in detergent compositions, such as build laundry deter­gents, floor and wall cleaners, rug cleaners and shampoos, hair shampoos, and liquid and bar soaps, and have been found to be sufficiently substantive to the substrate being washed so as to impart insect repelling properties to it. They may be dissolved, dispersed or emulsified (emulsions are considered to be special cases of dispersions) in appropriate liquid media and may be applied to surfaces to be made insect repellent, as by spraying, brushing, wiping or other suitable processes, includ­ing "aerosol" spraying from pressurized containers. They have been found to be of long lasting effectiveness, with significant and measurable insect repellency being obtainable for as long as two weeks after application. The described N-lower alkyl neoalkanamides are stable during normal uses, relatively low in manufacturing cost, of high substantivities to substrates, economical to use, unobjectionable in odor to humans, and harmless to humans and animals, and to the environment.

  N-低烷基新烷基酰胺（某些类型的 N-低烷基三烷基乙酰胺），其低烷基中含有 1 至 4 个碳原子，新烷酰基（或三烷基乙酰基）中含有 5 至 14 个碳原子，例如 N-甲基和 N-乙基新癸酰胺以及 N-甲基和 N-乙基新十三烷酰胺，是具有驱虫特性的仲酰胺类新化合物，对蟑螂（如德国蟑螂）特别有效。不过，它们也可用作其他昆虫的驱虫剂，包括美洲蟑螂、蚊子、苍蝇、跳蚤、蚂蚁和虱子。此外，它们还可以驱除蜘蛛、扁虱和螨虫等蛛形纲动物。新的新烷酰胺可以很容易地合成，例如通过伯低级烷基胺与新烷酰卤的反应，如通过甲基胺或乙基胺与新癸酰氯的反应。 所述酰胺中最有效的驱虫剂通常是液态的，具有足够的挥发性，昆虫可以在空气中检测到。它们可以直接涂抹在要处理的表面上，也可以加入洗涤剂组合物中，如制造洗衣粉、地板和墙壁清洁剂、地毯清洁剂和洗发水、洗发水、液体和条状肥皂。它们可以在适当的液体介质中溶解、分散或乳化（乳液被认为是分散体的特殊情况），并可以通过喷洒、刷洗、擦拭或其他适当的工艺，包括从加压容器中进行 "气溶胶 "喷洒，涂抹到需要驱虫的表面上。研究发现，这些产品具有持久的驱虫效果，在施用后的两周内都有明显的、可测量的驱虫效果。所述 N-低级烷基新烷酰胺在正常使用过程中性能稳定，制造成本相对较低，对基质的吸附性高，使用经济，对人体无异味，对人类、动物和环境无害。
• N-Aryl and N-cycloalkyl neoalkanamide insect repellents
  申请人：Colgate-Palmolive Company

  公开号：EP0499992A1

  公开（公告）日：1992-08-26

  N-monosubstituted neoalkanamides of 11 to 14 carbon atoms wherein the substituent on the amide nitrogen is cyclic (aromatic or cycloaliphatic, such as aryl or cycloalkyl) and of at least five carbon atoms, have been discovered to be insect repellent, providing that any aromatic substituent is unsubstituted at the ortho position and that when the neoalkanoyl moiety is pivaloyl the total number of carbon atoms in the N-cyclic neoalkanamide is at least 12. Such neoalkanamides are useful as repellents against cockroaches, including American, German and Oriental cockroaches, and are also effective against mosquitoes (both Anopheles and Aedes), black flies and carpenter ants, and to some extent against deer ticks. They may be applied to areas, locations and items which are desirably to be kept free of such insects, with applications being direct or of solutions or emulsions thereof, preferably by spraying, or in detergent compositions or other products to be applied to such areas, etc. Because the described neoalkanamides are desirably substantive to surfaces and are usually in liquid state, they give long lasting repellency to such areas, etc., and tests have shown them to be sufficiently long lasting.

  已发现 11 至 14 个碳原子的 N-单取代新烷酰胺，其中酰胺氮上的取代基为环状（芳香族或环脂肪族，如芳基或环烷基）且至少有 5 个碳原子，具有驱虫剂的作用，条件是任何芳香族取代基在正交位置上未被取代，并且当新烷酰基为新戊酰基时，N-环新烷酰胺中的碳原子总数至少为 12 个。这种新烷酰胺可用作蟑螂（包括美洲、德国和东方蟑螂）的驱避剂，对蚊子（包括按蚊和伊蚊）、黑蝇和木匠蚁也有效，在一定程度上对鹿蜱也有效。可将它们施用在希望没有此类昆虫的区域、地点和物品上，施用方式可以是直接施用，也可以是其溶液或乳液的施用，最好是通过喷洒，或在洗涤剂组合物或其他产品中施用到这些区域等。由于所述新烷酰胺对表面具有良好的吸附性，而且通常呈液态，因此它们对这些区域等具有持久的驱避作用，测试表明它们具有足够的持久性。
• CALCIUM ALKYL PHENATE SULFIDE AND PREPARATION METHOD THEREOF, AND LUBRICATING OIL COMPRISING SAME
  申请人：Xinxiang Richful Lube Additive Co., Ltd.

  公开号：EP3162877A1

  公开（公告）日：2017-05-03

  The present invention relates to the field of metal detergent, especially to a metal detergent and a preparation method thereof and a lubricant oil containing the metal detergent. The metal detergent provided by the present application is sulfurized calcium alkyl phenolate, the method for preparing the metal detergent includes the following steps: a) mixing alkyl phenol, a calcium source and base oil to obtain a mixed solution; b) mixing the mixed solution, ethylene glycol and a sulfur source to carry out sulfurization reaction to obtain a sulfurization reaction solution; c) implementing carbonation reaction between the sulfurization reaction solution and CO2 to obtain a carbonation reaction solution; and d) extracting the carbonation reaction solution with a solvent, upon refining, to obtain sulfurized calcium alkyl phenolate; wherein the solvent includes solvent oil, water and oxygenous derivative of hydrocarbon. Experimental results show that the content of free alkyl phenol is below 1.5 wt% in the sulfurized calcium alkyl phenolate prepared using the preparation method provided by the present application.

  本发明涉及金属清净剂领域，尤其涉及一种金属清净剂及其制备方法和一种含有该金属清净剂的润滑油。本申请提供的金属清净剂是硫化烷基酚钙，制备该金属清净剂的方法包括以下步骤：a)将烷基酚、钙源和基础油混合，得到混合溶液；b)将混合溶液、乙二醇和硫源混合，进行硫化反应，得到硫化反应液；c)将硫化反应液与二氧化碳进行碳化反应，得到碳化反应液；d)将碳化反应液用溶剂萃取，精制后得到硫化烷基酚钙；其中，溶剂包括溶剂油、水和烃的含氧衍生物。实验结果表明，采用本申请提供的制备方法制备的硫化烷基酚钙中游离烷基酚的含量低于 1.5 wt%。
• EASY IRONING/ANTI-WRINKLE/LESS CREASE BENEFIT OF FABRIC TREATMENT COMPOSITIONS WITH THE HELP OF SOIL RELEASE POLYMERS
  申请人：Henkel AG & Co. KGaA

  公开号：EP3272850A1

  公开（公告）日：2018-01-24

  The present invention relates to the use of soil release polymers as ironing aids in fabric treatment compositions. The invention further relates to the use of fabric treatment compositions to provide anti-wrinkle properties and/or ease or ironing benefits to a fabric treated therewith, wherein the composition comprises at least one soil release polymer. Furthermore, the invention relates to a method of reducing the creasing of fabric and to a method of providing ease of ironing benefits.

  本发明涉及在织物处理组合物中使用脱土聚合物作为熨烫助剂。本发明还涉及使用织物处理组合物为经其处理的织物提供抗皱性能和/或易于熨烫的优点，其中组合物包含至少一种土壤释放聚合物。此外，本发明还涉及一种减少织物褶皱的方法和一种提供易熨效果的方法。