S,S-diethylacetyldithiophosphonate

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机硫代磷化合物
• 英文名称: S,S-diethylacetyldithiophosphonate
• 英文别名: 1-Bis(ethylsulfanyl)phosphorylethanone
• 化学式: C₆H₁₃O₂PS₂
• 分子量: 212.274
• InChiKey: MFIPACYOBPQYMS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  11
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  84.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  乙酰溴 、 S,S-diethyl O-(trimethylsilyl) phosphorodithioite 以80.7%的产率得到三甲基溴硅烷
  参考文献：
  名称：

  Reaction of dialkyldithiotrimethylsilylphosphites with acyl halides

  摘要：

  It has been established that S,S-dialkyltrimethylsilyldithiophosphites react with acyl halides in two directions, depending on the nature of the halogen in the acyl halide and on the reaction conditions, thus giving as the main reaction products either dialkyldithiohalophosphites or dialkyldithioacylphosphonates. The latter compounds react with acyl halides in accordance with a retro-Arbuzov reaction scheme, giving dialkyldithiohalophosphites.

  DOI：

  10.1007/bf01150911

文献信息

• Reaction of dialkyldithiotrimethylsilylphosphites with acyl halides
  作者：V. A. Al'fonsov、A. G. Trusenev、R. M. Gainullin、�. S. Batyeva、A. N. Pudovik

  DOI：10.1007/bf01150911

  日期：1992.4

  It has been established that S,S-dialkyltrimethylsilyldithiophosphites react with acyl halides in two directions, depending on the nature of the halogen in the acyl halide and on the reaction conditions, thus giving as the main reaction products either dialkyldithiohalophosphites or dialkyldithioacylphosphonates. The latter compounds react with acyl halides in accordance with a retro-Arbuzov reaction scheme, giving dialkyldithiohalophosphites.