methyl 1-octanesulfinate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 亚磺酸及其衍生物
• 英文名称: methyl 1-octanesulfinate
• 英文别名: Methyl octane-1-sulfinate；methyl octane-1-sulfinate
• 化学式: C₉H₂₀O₂S
• 分子量: 192.323
• InChiKey: PEYIFGYAWZMLNO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  12
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  45.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  methyl 1-octanesulfinate 、 间苯二甲醚 在 1-butyl-3-methylimidazolium heptachlorodialuminate 作用下， 反应 4.0h， 以72%的产率得到2,4-dimethoxy-1-(octylsulfinyl)benzene
  参考文献：
  名称：

  离子液体和超声波辐照对亚磺酸酯亲电亚磺酰化芳香族化合物的显着影响

  摘要：

  已经在不同的离子液体和不同的路易斯酸盐中研究了芳香族和杂芳香族化合物与亚磺酸酯作为亲电试剂的亚磺酰化反应，以获得中等至良好收率的不对称亚砜。发现 1-丁基-3-甲基咪唑氯化物和氯化铝的混合物是最有效和可回收的反应框架。超声处理似乎是最有用和最环保的活化方法，以提供比在更持久的常规搅拌条件下获得的产量更好或相当的亚砜。

  DOI：

  10.3390/molecules22091458
• 作为产物：
  描述：

  甲烷亚磺酰氯化物 、 正辛基镁溴盐 以 乙醚 为溶剂， 反应 2.5h， 生成 methyl 1-octanesulfinate
  参考文献：
  名称：

  Baudin, Jean-Bernard; Commenil, Marie-Gabrielle; Julia, Sylvestre A., Bulletin de la Societe Chimique de France, 1996, vol. 133, # 11, p. 1127 - 1141

  摘要：

  DOI：

文献信息

• Direct synthesis of sulfinic esters via ultrasound accelerated tandem reaction of thiols and alcohols with <i>N</i>-bromosuccinimide
  作者：Lan-Anh Thi Nguyen、Tri-Nghia Le、Cong-Thang Duong、Chi-Tam Vo、Fritz Duus、Thi Xuan Thi Luu

  DOI：10.1080/17415993.2021.1928669

  日期：2021.9.3

  The direct transformation of various thiols and simple alcohols with N-bromosuccinimide into sulfinic esters has been investigated by using different categories of base/acidic catalysts as well as co-solvents under varied reaction conditions. The reaction was found out to afford the sulfinic esters with high yields in the absence of catalysts, especially within the shorter time under the acceleration

  已经通过使用不同类别的碱/酸催化剂以及在不同反应条件下的共溶剂研究了各种硫醇和简单醇与 N-溴代琥珀酰亚胺直接转化为亚磺酸酯。发现该反应在不存在催化剂的情况下以高产率提供亚磺酸酯，尤其是在超声辐射加速下比在更持久的常规搅拌条件下更短的时间内。
• [EN] ACTINIC RAY-SENSITIVE OR RADIATION-SENSITIVE RESIN COMPOSITION, RESIST FILM USING THE SAME, PATTERN FORMING METHOD, MANUFACTURING METHOD OF ELECTRONIC DEVICE AND ELECTRONIC DEVICE<br/>[FR] COMPOSITION DE RÉSINE SENSIBLE AUX RAYONS ACTINIQUES OU SENSIBLE AUX RADIATIONS ACTINIQUES, FILM DE RÉSERVE QUI UTILISE CETTE DERNIÈRE, PROCÉDÉ DE FORMATION DE MOTIFS, PROCÉDÉ DE FABRICATION D'UN DISPOSITIF ÉLECTRONIQUE ET DISPOSITIF ÉLECTRONIQUE
  申请人：FUJIFILM CORP

  公开号：WO2013115345A1

  公开（公告）日：2013-08-08

  There is provided an actinic ray-sensitive or radiation-sensitive resin composition, having: (A) a resin having a repeating unit represented by formula (I); (B) a compound capable of generating an acid upon irradiation with an actinic ray or radiation; and (C) a resin having at least one repeating unit (x) out of a repeating unit represented by formula (II) and a repeating unit represented by formula (III) and containing substantially neither fluorine atom nor silicon atom, wherein the content of the repeating unit (x) is 90% or more by mole based on all repeating units in the resin (C): wherein Xa represents a hydrogen atom, an alkyl group, a cyano group or a halogen atom, each of R1a, R1b and R1c independently represents an alkyl group or a cycloalkyl group, two members of R1a, R1b and R1c may combine to form a ring structure, Xb1 represents a hydrogen atom, an alkyl group, a cyano group or a halogen atom, R2 represents an organic group having one or more CH3 partial structures and being stable to acid, Xb2 represents a hydrogen atom, an alkyl group, a cyano group or a halogen atom, R3 represents an organic group having one or more CH3 partial structures and being stable to acid, and n represents an integer of 1 to 5.