双(4-氯苯基)草酸盐 | 3155-18-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 双(4-氯苯基)草酸盐
• 英文名称: bis(4-chlorophenyl) oxalate
• 英文别名: oxalic acid bis(4-chloro-phenyl) ester；Oxalsaeure bis (4-chlor-phenylester)；Di-(4-chlorphenyl)oxalat
• CAS: 3155-18-8
• 化学式: C₁₄H₈Cl₂O₄
• 分子量: 311.121
• InChiKey: MBONTEKTGWLRLP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 海关编码：
  2917119000

反应信息

• 作为产物：
  描述：

  草酰氯 、 对氯苯酚 在 三乙胺 作用下， 以 苯 为溶剂， 生成 双(4-氯苯基)草酸盐
  参考文献：
  名称：

  Control of peroxyoxalate chemiluminescence by nitrogen-containing ligand quenching: turning off and on by ligand–metal ion host–guest interactions

  摘要：

  The control of peroxyoxalate chemiluminescence (PO-CL) by the coordination of nitrogen-containing ligands and metal cations was investigated. Turning the CL off and on was done by PO-CL using 15-monoazacrown-5-tethered anthracene and alkali metal ions. CL quenching and regeneration was also observed in the separated molecular system of 15-monoazacrown-5 and the fluorophores. CL quenching by a number of ligands bearing dipicolylamino groups was evaluated by these PO-CL reactions and found to be closely related to their oxidation potentials, which is dependent on the Weller rate law for electron exchange and this provides strong support for the existence of the CIEEL PO-CL process. When Zn2+ or Cu2+ are added to the PO-CL system quenched by the ligand, N-[2-(2,2'-dipicolylamino)ethyl]aniline, CL was turned on because the electron donating ability of the ligands was modulated. This was controlled by the coordination of the studied metal ions and, therefore, this system results in CL because of host-guest interactions. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2011.06.078

文献信息

• Catalyst for decarbonylation reaction
  申请人：UBE INDUSTRIES, LTD.

  公开号：EP0826658A1

  公开（公告）日：1998-03-04

  A catalyst composed of an organic phosphorus compound having a trivalent or pentavalent phosphorus atom and at least one carbon-phosphorus bonding or a combination of the organic phosphorus compound and a halogen atom-containing compound is effective for decarbonylation, that is, for releasing carbon monoxide from a compound containing a moiety of -CO-CO-O- in its molecular structure.

  一种由含有三价或五价磷原子的有机磷化合物和至少一个碳-磷键合或有机磷化合物与含卤原子的化合物的组合构成的催化剂对于脱羰基作用是有效的，即从含有分子结构中的-CO-CO-O-基团的化合物中释放一氧化碳。
• Process for preparation of diaryl carbonate
  申请人：UBE INDUSTRIES, LTD.

  公开号：EP0737665A1

  公开（公告）日：1996-10-16

  A diaryl carbonate is prepared at a high yield and a high selectivity by heating a diaryl oxalate in the presence of an organic phosphorous compound to release carbon monoxide therefrom. A halogen atom-containing compound can be employed in combination with the organic phosphorous compound.

  通过在有机磷化合物存在下加热草酸二芳基酯，使其释放出一氧化碳，可以高产率和高选择性地制备碳酸二芳基酯。含卤原子的化合物可与有机磷化合物结合使用。
• Process for producing a diaryl carbonate
  申请人：UBE INDUSTRIES LIMITED

  公开号：EP0795539A1

  公开（公告）日：1997-09-17

  A diaryl carbonate with a high degree of purity is produced at a high yield by (A) subjecting (a) a diaryl oxalate and a phenol compound or (b) an alkylaryl oxalate to transesterification reaction in one or two stages in the presence of a catalyst to prepare a diaryl oxalate, while removing a by-product from the reaction system; (B) collecting the diaryl oxalate from the resultant reaction product mixture of the step (A); (C) subjecting the diaryl oxalate to a decarbonylation reaction, preferably in the presence of a phosphorous compound-containing catalyst, to convert the diaryl oxalate to a corresponding diaryl carbonate, while removing a reaction by-product comprising carbon monoxide from the reaction system; and (D) collecting the diaryl carbonate from the reaction product mixture of the step (C).

  高纯度碳酸二芳基酯的制备方法是：(A)在催化剂存在下，将(a)草酸二芳基酯和苯酚化合物或(b)草酸烷基芳基酯在一个或两个阶段中进行酯交换反应，制备草酸二芳基酯，同时从反应体系中除去副产物；(B)从步骤(A)的反应产物混合物中收集草酸二芳基酯；(C) 将草酸二芳基酯进行脱羰基反应，最好是在含磷化合物催化剂存在下进行，以将草酸二芳基酯转化为相应的碳酸二芳基酯，同时从反应体系中除去由一氧化碳组成的反应副产物；以及 (D) 从步骤(C)的反应产物混合物中收集碳酸二芳基酯。
• PROCESS FOR PREPARING DIARYL ESTERS OF OXALIC ACID
  申请人：UBE INDUSTRIES, LTD.

  公开号：EP0814074A1

  公开（公告）日：1997-12-29

  The present invention relates to a process for producing a diaryl oxalate, characterized in that an alkylaryl oxalate is subjected to a disproportionation reaction in the presence of a disproportionation catalyst, thereby to produce a diaryl oxalate while removing a by-product comprising a dialkyl oxalate. The production process of the present invention is advantageous in that the kinds of the by-products are fewer than that in conventional production process for diaryl oxalate, and thus can be practically utilized in industry, and the diaryl oxalates such as diphenyl oxalate, produced by the production process of the present invention are very important industrial materials for producing chemical products such as carbamates.

  本发明涉及一种草酸二芳基酯的生产工艺，其特征在于在歧化催化剂存在下，对草酸烷基芳基酯进行歧化反应，从而生产草酸二芳基酯，同时除去由草酸二烷基酯组成的副产品。 本发明生产工艺的优点在于副产品的种类比传统草酸二芳基酯生产工艺少，因此可在工业中实际利用，而且本发明生产工艺生产的草酸二芳基酯，如草酸二苯酯，是生产氨基甲酸酯等化工产品的非常重要的工业原料。
• Preparation of diaryl carbonate
  申请人：UBE INDUSTRIES, LTD.

  公开号：EP0834496A1

  公开（公告）日：1998-04-08

  An improved process for preparing a diaryl carbonate from a diaryl oxalate in a liquid phase by decarbonylation utilizes a reaction vessel composed of two or more reaction chambers which are connected in series. The process is composed of the steps of continuously introducing the diaryl oxalate and an organic phosphorus compound having a trivalent or pentavalent phosphorus atom and at least one carbon-phosphorus bonding into the first chamber and continuously recovering a reaction mixture mainly containing the diaryl carbonate from the last chamber under the condition that a mixture of the diaryl oxalate and the organic phosphorus compound is heated in the reaction chambers, while discharging carbon monoxide released from the mixture.

  一种通过脱羰基化从液相草酸二芳基酯制备碳酸二芳基酯的改进工艺利用了一个由两个或两个以上串联的反应室组成的反应容器。该工艺包括以下步骤：将草酸二芳基酯和具有三价或五价磷原子及至少一个碳-磷键的有机磷化合物连续引入第一个反应室；在草酸二芳基酯和有机磷化合物的混合物在反应室中加热的条件下，从最后一个反应室连续回收主要含有碳酸二芳基酯的反应混合物，同时排出从混合物中释放出的一氧化碳。