bis(dichlorophosphino)ethane

• 分子结构分类: 有机化合物 - 有机磷化合物 - 烷基卤代膦
• 英文名称: bis(dichlorophosphino)ethane
• 英文别名: dichloro(1-dichlorophosphanylethyl)phosphane
• 化学式: C₂H₄Cl₄P₂
• 分子量: 231.813
• InChiKey: SCQPPYJUVKMKLX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  bis(dichlorophosphino)ethane 、 aqueous NH4Cl-solution 、 1,4-二溴苯 生成 Bis(bis-4-bromophenylphosphino)ethane
  参考文献：
  名称：

  摘要：

  DOI：

文献信息

• Novel Compound, Novel Ligand, Novel Transition Metal Complex, and Catalyst Including Novel Transition Metal Complex
  申请人：Korenaga Toshinobu

  公开号：US20130331576A1

  公开（公告）日：2013-12-12

  The invention provides novel ligands for transition metal complexes which exhibit high coordination power with respect to metals by being free of substituents at the positions ortho to phosphorus or arsenic and which have electron-withdrawing power comparable to the highest level known in conventional ligands. A ligand of the invention includes a compound represented by General Formula (1): R 1 R 2 R 3 A or General Formula (2): R 1 R 2 A-Y-AR 3 R 4 and having a total of 15 to 110 carbon atoms. In the formulae, A is phosphorus or arsenic; R 1 , R 2 , R 3 and R 4 are each independently a substituted pyridyl group having optionally different electron-withdrawing groups bonded to the positions meta to the atom A as well as hydrogen atoms bonded to the positions ortho to the atom A; and Y is a divalent group derived from a C 2-20 , optionally substituted and optionally heteroatom-containing, aliphatic, alicyclic or aromatic compound or from ferrocene.

  该发明提供了过渡金属配合物的新型配体，这些配体在与金属的配位能力方面表现出很高的能力，因为它们在磷或砷的邻位位置上没有取代基，并且具有与传统配体中已知的最高水平相当的电子吸引力。该发明的配体包括由通用式（1）表示的化合物：R1R2R3A或通用式（2）：R1R2A-Y-AR3R4，并且总共含有15至110个碳原子。在上述公式中，A代表磷或砷；R1、R2、R3和R4分别独立地是取代吡啶基，在位置与原子A的间位上带有可选择的不同电子吸引基团，以及在位置与原子A的邻位上带有氢原子；Y是从C2-20、可选择取代且可含有杂原子的脂肪、脂环或芳香族化合物或二茂铁中得到的二价基团。
• Polymer-supported phosphorus ligands for catalysts
  申请人：——

  公开号：US20030228629A1

  公开（公告）日：2003-12-11

  Novel phosphine and phosphine oxide ligands are prepared using polymeric supports. These compounds can be easily cleaved from the support, and along with the corresponding supported compounds, used as ligands in the preparation of novel, metal-complexed catalysts.

  使用聚合物支撑物制备了新型膦和膦氧化物配体。这些化合物可以很容易地从支撑物中解离出来，并与相应的支撑化合物一起，用作制备新型金属络合催化剂中的配体。
• Process for preparing polyfluoroalkyllithium compounds
  申请人：——

  公开号：US20030065135A1

  公开（公告）日：2003-04-03

  The invention relates to a process for preparing polyfluoroalkyl-lithium compounds by deprotonation of polyfluoroalkyl compounds by means of lithium bases.

  该发明涉及一种通过使用锂碱基对聚氟烷基化合物进行去质子化而制备聚氟烷基锂化合物的过程。
• Verfahren zur Herstellung von Polyfluoralkyllithium-Verbindungen
  申请人：BAYER AG

  公开号：EP1266902A1

  公开（公告）日：2002-12-18

  Die Erfindung betrifft ein Verfahren zur Herstellung von Polyfluoralkyllithium-Verbindungen durch Deprotonierung von Polyfluoralkyl-Verbindungen mit Lithiumbasen.

  本发明涉及一种通过多氟烷基化合物与锂碱的去质子化反应制备多氟烷基锂化合物的工艺。
• NOVEL COMPOUND, NOVEL LIGAND, NOVEL TRANSITION METAL COMPLEXES, AND CATALYSTS CONSISTING OF NOVEL TRANSITION METAL COMPLEXES
  申请人：National University Corporation Okayama University

  公开号：EP2676963A1

  公开（公告）日：2013-12-25

  The invention provides novel ligands for transition metal complexes which exhibit high coordination power with respect to metals by being free of substituents at the positions ortho to phosphorus or arsenic and which have electron-withdrawing power comparable to the highest level known in conventional ligands. A ligand of the invention includes a compound represented by General Formula (1) : R1R2R3A or General Formula (2): R1R2A-Y-AR3R4 and having a total of 15 to 110 carbon atoms. In the formulae, A is phosphorus or arsenic; R1, R2, R3 and R4 are each independently a substituted pyridyl group having optionally different electron-withdrawing groups bonded to the positions meta to the atom A as well as hydrogen atoms bonded to the positions ortho to the atom A; and Y is a divalent group derived from a C2-20, optionally substituted and optionally heteroatom-containing, aliphatic, alicyclic or aromatic compound or from ferrocene.

  本发明提供了用于过渡金属配合物的新型配体，这些配体通过在磷或砷的正交位置上不含取代基而显示出与金属的高配位能力，并且具有与传统配体已知的最高水平相当的电子萃取能力。本发明的配体包括通式（1）：R1R2R3A 或通式（2）代表的化合物：R1R2A-Y-AR3R4 所表示的化合物，其碳原子总数为 15 至 110 个。在通式中，A 是磷或砷；R1、R2、R3 和 R4 各自独立地是取代的吡啶基，该吡啶基具有与原子 A 元位置成键的任选不同的抽电子基团，以及与原子 A 正交位置成键的氢原子；Y 是二价基团，衍生自 C2-20、任选取代和任选含杂原子的脂肪族、脂环族或芳香族化合物或二茂铁。