双(七氟异丙基)-二氮烯 | 33757-15-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 双(七氟异丙基)-二氮烯
• 英文名称: Perfluoroazo-2-propane
• 英文别名: Perfluorazopropanon；Bis(heptafluorisopropyl)diazin；bis(heptafluoroisopropyl)-diazene；bis-(1,2,2,2-tetrafluoro-1-trifluoromethyl-ethyl)-diazene；Bis(1,1,1,2,3,3,3-heptafluoropropan-2-yl)diazene
• CAS: 33757-15-2
• 化学式: C₆F₁₄N₂
• 分子量: 366.057
• InChiKey: XOALLZOMNSIBEY-UHFFFAOYSA-N

物化性质

• 沸点：
  59.7±40.0 °C(Predicted)
• 密度：
  1.73±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  22
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  24.7
• 氢给体数：
  0
• 氢受体数：
  16

反应信息

• 作为反应物：
  描述：

  双(七氟异丙基)-二氮烯 反应 4.0h， 生成 1,1,1,2,3,4,4,4-八氟-2,3-二(三氟甲基)丁烷
  参考文献：
  名称：

  Synthesis and pyrolysis of perfluoroazo-2-propane

  摘要：

  AbstractAn improved method has been used to synthesize perfluoroazo‐2‐propane. Pyrolysis over the temperature range 450–514 K in a static system has been shown to be a homogeneous, first‐order process. No pressure dependence was observed in the presence of excess inert gas (SF6). The only products were nitrogen and perfluoro‐2,3‐dimethylbutane. The rate constant (k) for the decomposition process is given by: These results lead to a straightforward mechanism for the decomposition process equation image The results are compared with those for other azo compounds. © 1994 John Wiley & Sons, Inc.

  DOI：

  10.1002/kin.550260109
• 作为产物：
  描述：

  六氟丙酮吖嗪 在 fluorine 作用下， 20.0 ℃ 、66.66 kPa 条件下， 反应 93.0h， 生成 双(七氟异丙基)-二氮烯
  参考文献：
  名称：

  Synthesis and pyrolysis of perfluoroazo-2-propane

  摘要：

  AbstractAn improved method has been used to synthesize perfluoroazo‐2‐propane. Pyrolysis over the temperature range 450–514 K in a static system has been shown to be a homogeneous, first‐order process. No pressure dependence was observed in the presence of excess inert gas (SF6). The only products were nitrogen and perfluoro‐2,3‐dimethylbutane. The rate constant (k) for the decomposition process is given by: These results lead to a straightforward mechanism for the decomposition process equation image The results are compared with those for other azo compounds. © 1994 John Wiley & Sons, Inc.

  DOI：

  10.1002/kin.550260109

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.8, 3, page 55 - 151
  作者：

  DOI：——

  日期：——
• Swindell, Richard F.; Zaborowski; Shreeve, Jean'ne M., Inorganic Chemistry, 1971, vol. 10, # 8, p. 1635 - 1638
  作者：Swindell, Richard F.、Zaborowski、Shreeve, Jean'ne M.

  DOI：——

  日期：——
• Electron spin resonance of perfluoroazoalkane radical anions
  作者：John L. Gerlock、Edward G. Janzen、John K. Ruff

  DOI：10.1021/ja00711a065

  日期：1970.4