1-Methyl-2-phenylethyl 4-bromobenzenecarbodithioate | 469886-41-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-Methyl-2-phenylethyl 4-bromobenzenecarbodithioate
• 英文别名: 1-phenylpropan-2-yl 4-bromobenzenecarbodithioate
• CAS: 469886-41-7
• 化学式: C₁₆H₁₅BrS₂
• 分子量: 351.3
• InChiKey: ITMWWEXRXZUGDL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  19
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  57.4
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• Methods of polymerization
  申请人：——

  公开号：US20030088028A1

  公开（公告）日：2003-05-08

  The present invention provides improved methods for conducting living/controlled polymerization on polymeric solid supports. The improved methods allow polymerization to occur directly from the non-functionalized surface of a bulk support. In addition, polymerization may be re-initiated to provide co-polymers. The disclosed methods may employ the non-nitroxide-based RAFT and ATRP control agents that allow controlled polymerization to proceed at relatively low temperatures (<80° C.). Furthermore, these improved methods may provide graft polymers with decreased levels of “in-growth” of the bulk solid support. The invention also provides substrate polymers, with improved properties for solid phase synthesis and diagnostic applications, which may be made by the disclosed methods.

  本发明提供了在聚合物固体支持物上进行活体/可控聚合的改进方法。改进后的方法可使聚合反应直接从块状支撑物的非官能化表面进行。此外，聚合可重新启动，以提供共聚物。所公开的方法可采用非硝基的 RAFT 和 ATRP 控制剂，使受控聚合在相对较低的温度（<80° C）下进行。此外，这些改进的方法还可提供接枝聚合物，降低块状固体支撑物的 "内生长 "水平。本发明还为固相合成和诊断应用提供了具有改进特性的基质聚合物，这些基质聚合物可通过所公开的方法制成。
• EP1383828A4
  申请人：——

  公开号：EP1383828A4

  公开（公告）日：2006-10-04
• A METHOD OF TREATING THE SURFACE OF A SUBSTRATE POLYMER USEFUL FOR GRAFT POLYMERIZATION
  申请人：Polymerat Pty Ltd

  公开号：EP1383828A1

  公开（公告）日：2004-01-28
• METHOD FOR PRODUCING MOLECULARLY IMPRINTED POLYMERS
  申请人：University of Dortmund Infu

  公开号：EP1781711A1

  公开（公告）日：2007-05-09
• Method for Producing Molecularly Imprinted Polymers
  申请人：Sellergren Borje

  公开号：US20080071003A1

  公开（公告）日：2008-03-20

  The invention relates to a method for producing molecular imprinted polymers (MIP) which are applied as a thin film to the surface of a support material, in which a suspension of at least one functional monomer, one template and one initiator is used for the polymerisation, and with which RAFT agents are employed.