1-chloro-1,1-difluoroethylene

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 英文名称: 1-chloro-1,1-difluoroethylene
• 英文别名: 2-chloro-2,2-difluoroethylene；1-chloro-1,1-difluoroethene；2-Chloro-2,2-difluoroethyl
• 化学式: C₂H₂ClF₂
• 分子量: 99.4877
• InChiKey: CPRCXVAIPPLRJV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  5
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1-氯-1,1-二氟乙烷 在 hydroxide 作用下， 19.9 ℃ 、5.0 kPa 条件下， 生成 1-chloro-1,1-difluoroethylene
  参考文献：
  名称：

  Moers; Hoffmann; Malms, Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics, 1996, vol. 100, # 5, p. 540 - 552

  摘要：

  DOI：

文献信息

• Chemical reactions and lasers: Elementary steps and complex systems
  作者：J. Wolfrum

  DOI：10.1016/0584-8539(90)80172-u

  日期：1990.1
• Kinetics of Cl(2P) reactions with CF3CHCl2, CF3CHFCl, and CH3CFCl2
  作者：Rachel F. Warren、A. R. Ravishankara

  DOI：10.1002/kin.550251005

  日期：1993.10

  AbstractThe rate coefficients for the removal of Cl atoms by reaction with three HCFCs, CF3CHCl2 (HCFC‐123), CF3CHFCl (HCFC‐124), and CH3CFCl2 (HCFC 141b), were measured as a function of temperature between 276 and 397 K. CH3CF2Cl (HCFC‐142b) was studied only at 298 K. The Arrhenius expressions obtained are: k1 = (3.94 ± 0.84)× 10−12 exp[−(1740 ± 100)/T] cm3 molecule−1 s−1 for CF3CHCl2 (HCFC 123); k2 = (1.16 ± 0.41) × 10−12 exp[−(1800 ± 150)/T] cm3 molecule−1 s−1 for CF3CHFCl (HCFC 124); and k3 = (1.6 ± 1.1) × 10−12 exp[−(1800 ± 500)/T] cm3 molecule−1 s−1 for CH3CFCl2 (HCFC 141b). In case of HCFC 141b, non‐Arrhenius behavior was observed at temperatures above ca. 350 K and is attributed to the thermal decomposition of CH2CFCl2 product into Cl + CH2CFCl. In case of HCFC‐142b, only an upper limit for the 298 K value of the rate coefficient was obtained. The atmospheric significance of these results are discussed. © 1993 John Wiley & Sons, Inc.
• Rate constants for the reactions of hydroxyl with 1,1-dichloro-1-fluoroethane (HCFC-141b), 1-chloro-1,1-difluoroethane (HCFC-142b), and 1,1,1,2-tetrafluoroethane (HFC-134a)
  作者：Zhengyu Zhang、Robert E. Huie、Michael J. Kurylo

  DOI：10.1021/j100183a008

  日期：1992.2

  The rate constants for the reaction of OH with CH3CFCl2(HCFC-141b) over the temperature range 250-297 K were remeasured with improved detection sensitivity as a function of flash energy and concentration of OH radical precursor (H2O). The rate constants were reduced at the lower OH concentrations employed, suggesting complications due to secondary reactions. The new values disagree with the low-temperature values reported earlier but agree with the values extrapolated from the higher temperature results (T > 298 K). In contrast, rate constants for CH3CF2Cl(HCFC-142b) and CH2FCF3(HFC-134a), remeasured at the lower flash energy at 270 K, were found to agree with those reported earlier at higher flash energy.
• Moers; Hoffmann; Malms, Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics, 1996, vol. 100, # 5, p. 540 - 552
  作者：Moers、Hoffmann、Malms、Zellner

  DOI：——

  日期：——
• GIERCZAK, TOMASZ;TALUKDAR, RANAJIT;VAGHJIANI, GHANSHYAM L.;LOVEJOY, EDWAR+, J. GEOPHYS. RES. D, 96,(1991) N, C. 5001-5011
  作者：GIERCZAK, TOMASZ、TALUKDAR, RANAJIT、VAGHJIANI, GHANSHYAM L.、LOVEJOY, EDWAR+

  DOI：——

  日期：——