1,1''-<2,3-bis(methylene)quinoxaline>bis-4,4'-bipyridinium dication

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 1,1''-<2,3-bis(methylene)quinoxaline>bis-4,4'-bipyridinium dication
• 英文别名: 2,3-Bis[(4-pyridin-4-ylpyridin-1-ium-1-yl)methyl]quinoxaline
• 化学式: C₃₀H₂₄N₆
• 分子量: 468.561
• InChiKey: JNBOZUXPUZBDHB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  36
• 可旋转键数：
  6
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  59.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,1''-<2,3-bis(methylene)quinoxaline>bis-4,4'-bipyridinium dication 在 sodium dithionite 作用下， 以 水 为溶剂， 生成 4,4'-联吡啶 、 2,3-二甲基喹喔啉
  参考文献：
  名称：

  Unexpected decomposition of a monoquarternated 4,4′-bipyridinium dication by disodium dithionite reduction in water

  摘要：

  Instead of the expected neutral radical the reduction of a quinoxaline bridged 4,4-bipyridinium salt by disodium dithionite (DSD) in water renders 2,3-dimethylquinoxaline and 4,4'-bipyridine, In contrast, with more electronrich arenes used as spacer groups no decomposition products were observed. The mechanism of the chemically induced decomposition and the electrochemical properties of the starting compounds are reported. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(98)01105-3

文献信息

• Unexpected decomposition of a monoquarternated 4,4′-bipyridinium dication by disodium dithionite reduction in water
  作者：Holger Scheytza、Hans-Ulrich Reissig

  DOI：10.1016/s0040-4020(98)01105-3

  日期：1999.1

  Instead of the expected neutral radical the reduction of a quinoxaline bridged 4,4-bipyridinium salt by disodium dithionite (DSD) in water renders 2,3-dimethylquinoxaline and 4,4'-bipyridine, In contrast, with more electronrich arenes used as spacer groups no decomposition products were observed. The mechanism of the chemically induced decomposition and the electrochemical properties of the starting compounds are reported. (C) 1999 Elsevier Science Ltd. All rights reserved.