2,3,4-trinitro-benzoic acid ethyl ester

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,3,4-trinitro-benzoic acid ethyl ester
• 英文别名: 2,3,4-Trinitro-benzoesaeure-aethylester；Ethyl 2,3,4-trinitrobenzoate
• 化学式: C₉H₇N₃O₈
• 分子量: 285.17
• InChiKey: ZFGRMLYEKGWOAC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  164
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  1-甲基-2,3,4-三硝基苯 在 chromium(III) oxide 、 硫酸 作用下， 生成 2,3,4-trinitro-benzoic acid ethyl ester
  参考文献：
  名称：

  Giua, Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti, 1914, vol. <5> 23 II, p. 486

  摘要：

  DOI：

文献信息

• Process for the preparation of white graft polymer dispersions and flame-retardant polyurethane foams
  申请人：BASF Corporation

  公开号：EP0091036A2

  公开（公告）日：1983-10-12

  White graft polymer dispersions in polyoxyalkylene polyether polyols are employed together with flame retardant compounds to prepare flame retardant polyurethane foams. The polymer dispersions employ less than 0.1 mole of induced unsaturation per mole of polyol mixture. improved processes for the preparation of these polymer dispersions employ either maleate or fumarate derived polyetherester polyols or polyetherester polyols prepared by reacting a polyoxyalkylene polyether polyol with a compound selected from the group consisting of maleic acid, maleic anhydride and fumaric acid and an alkylene oxide in the presence of salts and oxides of divalent metals.

  聚氧亚烷基聚醚多元醇中的白色接枝聚合物分散体与阻燃化合物一起用于制备阻燃聚氨酯泡沫。制备这些聚合物分散体的改进工艺采用马来酸盐或富马酸盐衍生的聚醚酯多元醇或聚醚酯多元醇，聚醚酯多元醇的制备方法是将聚氧亚烷基聚醚多元醇与选自马来酸、马来酸酐、富马酸和氧化亚烷的化合物在二价金属的盐和氧化物存在下进行反应。
• A graft polymer dispersion in a mixture of low molecular weight polyols and polyether polyols and polyurethane foams prepared therefrom
  申请人：BASF Corporation

  公开号：EP0163188A2

  公开（公告）日：1985-12-04

  A low viscosity, stable graft polymer dispersion is prepared by polymerizing in the presence of a free radical initiator, from about 25 to about 70 weight percent based on the total weight of the dispersion, an ethylenically unsaturated monomer or mixture of monomers, in a polyol mixture comprising (1 ) from about 25 to about 99 weight percent of a polyol containing from 2 to 8 hydroxyl groups and having an equivalent weight from 30 to about 200, (2) from about 1 to about 75 weight percent of a macromer containing induced unsaturation, said macromer comprising the reaction product of a polyether polyol having an equivalent weight from 100 to 10,000 with a compound having both ethylenic unsaturation and a group selected from the group consisting of a hydroxyl, carboxyl, anhydride, isocyanate and epoxy or mixtures thereof. These graft polymer dispersions are useful for preparing polyurethane products.

  一种低粘度、稳定的接枝聚合物分散体是在自由基引发剂存在的情况下，在多元醇混合物中聚合乙烯基不饱和单体或单体混合物（以分散体总重量为基准，约 25% 至约 70%）而制备的，多元醇混合物包括 (1) 约 25% 至约 99% 的多元醇，该多元醇含有 2 至 8 个羟基，当量重量为 30 至约 200、(2) 约 1 至约 75 重量百分比的含有诱导不饱和的大色母粒，所述大色母粒包括当量重量为 100 至 10,000 的聚醚多元醇与具有乙烯基不饱和的化合物和选自羟基、羧基、酸酐、异氰酸酯和环氧或其混合物的基团的反应产物。这些接枝聚合物分散体可用于制备聚氨酯产品。
• Process for the preparation of integral skin polyurethane steering wheels
  申请人：BASF Corporation

  公开号：EP0297519A1

  公开（公告）日：1989-01-04

  The integral skin polyurethane steering wheel is prepared by reacting (a) a mixture of a graft polymer dispersion in a polyol or a polyol mixture (b) an organic polyisocyanate selected from the group consisting of an isocyanate prepolymer prepared by reacting 4,4′-­diphenylmethane diisocyanate with a mixture of dipropylene glycol and a polyoxypropylene glycol having a molecular weight of about 420, a polymeric polymethylene polyphenylene polyisocyanate containing about 55 weight percent diphenylmethane diisocyanate, a 1:1 mixture of 2,4′- and 4,4′-diphenylmethane diisocyanate and mixtures thereof, (c) a blowing agent, (d) a chain extender, and (e) a catalyst, surfactant and optionally flame retardants, fillers U.V. absorbers and other additives.

  整体蒙皮聚氨酯方向盘是通过以下反应制备的：(a) 接枝聚合物分散在多元醇或多元醇混合物中的混合物；(b) 有机多异氰酸酯，该有机多异氰酸酯选自以下组别：由 4、4′-diphenylmethane diisocyanate with a mixture of dipropylene glycol and a polyoxypropylene glycol having a molecular weight of about 420, a polymeric polymethylene polyphenylene polyisocyanate containing about 55 weight percent diphenylmethane diisocyanate, a 1：2,4′- 和 4,4′- 二苯基甲烷二异氰酸酯的 1:1 混合物及其混合物，(c) 发泡剂，(d) 扩链剂，(e) 催化剂，表面活性剂和可选的阻燃剂，填料 U. V. 吸收剂和其他添加剂。V. 吸收剂和其他添加剂。
• Moldable energy absorbing rigid polyurethane foam compositions
  申请人：BASF Corporation

  公开号：EP0316788A2

  公开（公告）日：1989-05-24

  Moldable energy absorbing rigid polyurethane foams are prepared by reacting a polyoxyalkylene polyether polyol containing therein a graft polymer dispersion, an alkylene oxide adduct of an aromatic amine in the presence of a crosslinking agent with an organic polyisocyanate. Alterna­tively, the aromatic amine may be replaced with an alkylene oxide adduct of pentaerythritol, ethylenediamine, α-methyl­glucoside, sorbitol and sucrose. The products are useful in various automobile body parts.

  可模塑的吸能硬质聚氨酯泡沫的制备方法是：将含有接枝聚合物分散体的聚氧亚烷基聚醚多元醇、芳香族胺的环氧烷基加合物在交联剂存在下与有机多异氰酸酯反应。或者，也可以用季戊四醇、乙二胺、α-甲基葡萄糖苷、山梨糖醇和蔗糖的环氧烷加合物代替芳香胺。这些产品适用于各种汽车车身部件。
• Flexible flame resistant polyurethane foams
  申请人：BASF Corporation

  公开号：EP0312920A2

  公开（公告）日：1989-04-26

  The invention pertains to flame retardant poly­urethane foams prepared by the reaction of a polyoxyalkylene polyether polyol with toluene diisocyanate and a blowing agent wherein the flame retardant compound is selected from the group consisting of dicyandiamide, oxamide and biuret. The amount of flame retardant may range from about 25 weight percent to about 75 weight percent of the total composition.

  本发明涉及通过聚氧亚烷基聚醚多元醇与甲苯二异氰酸酯和发泡剂反应制备的阻燃聚氨酯泡沫，其中阻燃剂化合物选自双氰胺、草胺和双脲组成的组。阻燃剂的用量可占整个组合物的约 25% 至约 75%。