(2-fluoro-4-chloro-5-methylsulfonyloxyphenyl)-hydrazine

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2-fluoro-4-chloro-5-methylsulfonyloxyphenyl)-hydrazine
• 英文别名: 2-Fluoro-4-chloro-5-methylsulfonyloxyphenylhydrazine；(2-chloro-4-fluoro-5-hydrazinylphenyl) methanesulfonate
• 化学式: C₇H₈ClFN₂O₃S
• 分子量: 254.67
• InChiKey: OMJYAIOCHMFHJP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  89.8
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  (2-fluoro-4-chloro-5-methylsulfonyloxyphenyl)-hydrazine 生成 1-(2-fluoro-4-chloro-5-methylsulfonyloxyphenyl)-3,5-dimethylpyrazole
  参考文献：
  名称：

  OYAMA, XIROSI;SIMODZONO, TAKURO

  摘要：

  DOI：
• 作为产物：
  描述：

  2-chloro-4-fluoro-5-aminophenyl methanesulfonate 生成 (2-fluoro-4-chloro-5-methylsulfonyloxyphenyl)-hydrazine
  参考文献：
  名称：

  OYAMA, XIROSI;SIMODZONO, TAKURO

  摘要：

  DOI：

文献信息

• 1-arylpyrazoles, composition containing them, and herbicidal method of
  申请人：Hokko Chemical Industry Co., Ltd.

  公开号：US04752326A1

  公开（公告）日：1988-06-21

  As compounds is provided a pyrazole derivative of the formula ##STR1## wherein R.sub.1a, R.sub.1b and R.sub.1c are each a hydrogen atom, a halogen atom, a nitro group, an amino group, a (lower) alkyl group, a halo-(lower)alkyl group, a(lower)alkenyl group, a (lower)alkynyl group, a (lower)alkylcarbonylamino group, a (lower)alkoxycarbonylamino group, a mono-(lower) alkylaminocarbonylamino group or a di-(lower)alkylaminocarbonylamino group; R.sub.2 is a hydrogen atom, a (lower)alkyl group, a (lower)alkenyl group, a (lower)alkynyl group, a (lower) alkoxy(lower)alkyl group, a (lower)alkylthio(lower)alkyl group, a (lower)alkylcarbonyl(lowr)alkyl group, a (lower) alkoxycarbonyl(lower)alkyl group, a (lower)alkylthiocarbonyl(lower)alkyl group, a cyano(lower)alkyl group, a (lower)alkylsulfonyl group, phenylsulfonyl group, a halogen-substituted phenylsulfonyl group or a (lower) alkyl-substituted phenylsulfonyl group, and X and Y are the same or different and each are a halogen atom. The pyrazoles are useful as herbicidal agent and may be produced by a variety of processes.

  提供的化合物是公式##STR1##中的吡唑衍生物，其中R.sub.1a、R.sub.1b和R.sub.1c分别是氢原子、卤素原子、硝基、氨基、(较低)烷基、卤代(较低)烷基、(较低)烯基、(较低)炔基、(较低)烷基羰基氨基、(较低)烷氧羰基氨基、单(较低)烷基氨基羰基氨基或双(较低)烷基氨基羰基氨基；R.sub.2是氢原子、(较低)烷基、(较低)烯基、(较低)炔基、(较低)烷氧基(较低)烷基、(较低)烷硫基(较低)烷基、(较低)烷基羰基(较低)烷基、(较低)烷氧羰基(较低)烷基、(较低)烷硫羰基(较低)烷基、氰基(较低)烷基、(较低)烷基磺酰基、苯基磺酰基、卤代苯基磺酰基或(较低)烷基取代的苯基磺酰基，X和Y相同或不同，且各自是卤素原子。这些吡唑化合物可用作除草剂，并可通过各种工艺生产。
• New pyrazole derivatives, their production and uses
  申请人：HOKKO CHEMICAL INDUSTRY CO., LTD

  公开号：EP0202169A1

  公开（公告）日：1986-11-20

  As new compounds is provided a pyrazole derivative of the formula wherein R1a, R1b and R1c are each a hydrogen atom, a halogen atom, a nitro group, an amino group, a (lower) alkyl group, a halo-(lower)alkyl group, a (lower)alkenyl group, a (lower)alkynyl group, a (lower)alkylcarbonylamino group, a (lower)alkoxycarbonylamino group, a mono-(lower) alkylaminocarbonylamino group or a di-(lower)alkylaminocarbonylamino group; R2 is a hydrogen atom, a (lower)alkyl group, a (lower)alkenyl group, a (lower)alkynyl group, a (lower) alkoxy(lower)-alkyl group; a (lower)alkylthio(lower)alkyl group, a (lower)alkylcarbonyl(lower)alkyl group, a (lower) alkoxycarbonyl(lower)alkyl group, a (lower)alkylthiocarbonyl(lower) alkyl group, a cyano(lower)alkyl group, a (lower)alkylsulfonyl group, phenylsulfonyl group, a halogen-substituted phenylsulfonyl group or a (lower)alkyl-substituted phenylsulfonyl group, and X and Y are the same or different and each are a halogen atom. The pyrazoles are useful as herbicidal agentand may be produced by a variety of processes.

  作为新化合物，提供了一种吡唑衍生物，其式如下 其中 R1a、R1b 和 R1c 各为氢原子、卤素原子、硝基、氨基、（低级）烷基、卤代（低级）烷基、（低级）烯基、（低级）炔基、（低级）烷基羰基氨基、（低级）烷氧基羰基氨基、单（低级）烷基氨基羰基氨基或二（低级）烷基氨基羰基氨基； R2 是氢原子、(低级)烷基、(低级)烯基、(低级)炔基、(低级)烷氧基(低级)烷基；(低级)烷硫基（低级）烷基、(低级)烷羰基（低级）烷基、(低级)烷氧羰基（低级）烷基、(低级)烷硫基（低级）烷基、氰基（低级）烷基、(低级)烷磺酰基、苯磺酰基、卤素取代的苯磺酰基或(低级)烷基取代的苯磺酰基，以及 X 和 Y 相同或不同，且各自为卤素原子。吡唑可用作除草剂，并可通过多种工艺生产。
• OHYAMA, HIROSHI;ONO, TOSHIHARU;SHIMOZONO, TAKURO;TERAKAWA, TERUHIKO
  作者：OHYAMA, HIROSHI、ONO, TOSHIHARU、SHIMOZONO, TAKURO、TERAKAWA, TERUHIKO

  DOI：——

  日期：——
• OYAMA, XIROSI;SIMODZONO, TAKURO
  作者：OYAMA, XIROSI、SIMODZONO, TAKURO

  DOI：——

  日期：——
• OYAMA, XIROSI;ONO, TOSIXARU;SIMODZONO, TAKURO;TEHRAKAVA, TEHRUXIKO
  作者：OYAMA, XIROSI、ONO, TOSIXARU、SIMODZONO, TAKURO、TEHRAKAVA, TEHRUXIKO

  DOI：——

  日期：——