N,N-bis(4-methylphenyl)-4-[2-phenylethenyl]benzenamine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N-bis(4-methylphenyl)-4-[2-phenylethenyl]benzenamine
• 英文别名: 4-ditolylaminostilbene；benzenamine, 4-methyl-N-(4-methylphenyl)-N-[4-[2-phenylethenyl]phenyl]-；4-methyl-N-(4-methylphenyl)-N-[4-[(E)-2-phenylethenyl]phenyl]aniline
• 化学式: C₂₈H₂₅N
• 分子量: 375.513
• InChiKey: RMTFQLKKBBWGAH-OUKQBFOZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.2
• 重原子数：
  29
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  4-乙烯苯胺 在 tris(dibenzylideneacetone)dipalladium (0) P(i-BuNCH₂CH₂)3N 、 sodium t-butanolate 、 2,8,9-三异丁基-2,5,8,9-四氮杂-1-磷酸双向环[3.3.3]十一烷 作用下， 以 甲苯 为溶剂， 反应 32.0h， 生成 N,N-bis(4-methylphenyl)-4-[2-phenylethenyl]benzenamine
  参考文献：
  名称：

  Pd 2 dba 3 / P（i- BuNCH 2 CH 2）3 N：一种高效催化剂，用于一锅合成反式-4- N，N-二芳基氨基苯乙烯和N，N-二芳基氨基苯乙烯

  摘要：

  报道了Pd 2 dba 3 / P（i- BuNCH 2 CH 2）3 N催化一锅合成不对称取代的反式-4- N，N-二芳基氨基苯乙烯和对称和不对称取代的N，N-二芳基氨基苯乙烯衍生物。该程序涉及使用同一催化剂体系，使用两种不同的芳基卤化物（包括芳基氯化物和杂芳基卤化物作为偶联伙伴）的同一催化剂体系，在一锅中进行两个或多个钯催化的顺序偶联反应（胺化和分子间Heck反应）。

  DOI：

  10.1016/j.tet.2005.06.117

文献信息

• Electrophotographic photoconductor, process for forming an image, image forming apparatus and a process cartridge for the same
  申请人：——

  公开号：US20030190540A1

  公开（公告）日：2003-10-09

  Providing an electrophotographic photoconductor comprising a conductive support and a photoconductive layer disposed on the photoconductive support; wherein the photoconductive layer contains an azo compound expressed by a general formula <<1>>. Ar &Parenopenst;N═N—Cp) n general formula <<1>> (in the general formula <<1>>, Ar expresses one of a substituted or non-substituted aromatic carbon hydride group and heterocyclic ring aromatic series group which can be combined by way of a bond group; Cp expresses a coupler residual group; n expresses an integer of one of 1, 2, 3, and 4; at least one of the Cp is a coupler residual group selected from one of the following general formulae <<2>>, <<3>>, and <<4>>.) 1

  提供一种电照相光导体，包括导电支持和设置在光导支承上的光导层；其中，所述光导层含有一种由下式表示的偶氮化合物。
• One pot sequential reactions and novel products produced thereby
  申请人：Valsan Mecheril Nandakumar

  公开号：US20060224017A1

  公开（公告）日：2006-10-05

  A method for producing sequenced reaction products comprising performing, in one pot, a first reaction at a lower temperature followed by a second reaction at a higher temperature in the presence of a catalyst system comprising a proazahosphatrane in combination with a palladium compound is provided. In one embodiment, the first reaction is a double amination reaction and the second reaction is an arylation. Use of one pot and a single catalyst system for each set of sequential reactions is efficient and economical. Novel N,N-diarylaminostyrenes and N,N-diarylaminostilbenes are produced according to the methods described herein.

  提供了一种生产序列反应产物的方法，包括在同一个容器中，在存在包括一种临氨基膦杂环丙胺和钯化合物的催化剂体系的情况下，先在较低温度下进行第一反应，然后在较高温度下进行第二反应。在一个实施例中，第一反应是双胺化反应，第二反应是芳基化反应。对于每组顺序反应使用同一个容器和单一催化剂体系是高效且经济的。根据本文描述的方法生产了新颖的N,N-二芳基氨基苯乙烯和N,N-二芳基氨基苯乙烯。
• Electrophotographic photoconductor, process for forming an image, image forming apparatus and process cartridge for the same
  申请人：Shoshi Masayuki

  公开号：US20050112487A1

  公开（公告）日：2005-05-26

  Providing an electrophotographic photoconductor comprising a conductive support and a photoconductive layer disposed on the photoconductive support; wherein the photoconductive layer contains an azo compound expressed by a general formula <<1>>. ArN═N—Cp) n general formula <<1>> (in the general formula <<1>>, Ar expresses one of a substituted or non-substituted aromatic carbon hydride group and heterocyclic ring aromatic series group which can be combined by way of a bond group; Cp expresses a coupler residual group; n expresses an integer of one of 1, 2, 3, and 4; at least one of the Cp is a coupler residual group selected from one of the following general formulae <<2>>, <<3>>, and <<4>>.)

  提供一种电子照相感光鼓，包括一个导电支撑和一个位于导电支撑上的感光层；其中，感光层包含一个由一般式<<1>>表示的偶氮化合物。一般式<<1>>为：ArN═N—Cp)n（在一般式<<1>>中，Ar表示取代或未取代的芳香碳氢基团和杂环芳香系列基团之一，可以通过键基团结合；Cp表示偶合剩余基团；n表示1、2、3和4中的一个整数；Cp中至少有一个是从以下一般式<<2>>、<<3>>和<<4>>中选择的偶合剩余基团之一）。
• NEW POLYMER AND POLYMER LIGHT-EMITTING DEVICE USING THE SAME
  申请人：Kobayashi Satoshi

  公开号：US20080103278A1

  公开（公告）日：2008-05-01

  Provided is a polymer comprising a repeating unit represented by formula (1), wherein, A 1 represents a divalent group in which the bond distance ratio (bond distance of C(α)-A 1 /bond distance of C(α)-C(β)) is 1.10 or more; R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 , each independently represent a hydrogen atom, alkyl group, alkyloxy group, aryloxy group, arylalkyloxy group, etc. The polymer is useful as a light-emitting material, a charge transporting material, etc.

  提供的是一种聚合物，其中包含由式（1）表示的重复单元，其中A1表示具有结合距离比（C（α）-A1的结合距离/C（α）-C（β）的结合距离）为1.10或更多的二价基团；R1、R2、R3、R4、R5和R6各自独立地表示氢原子、烷基、烷氧基、芳氧基、芳基烷氧基等。该聚合物可用作发光材料、电荷传输材料等。
• Photoreceptor
  申请人：KONICA CORPORATION

  公开号：EP0153145A2

  公开（公告）日：1985-08-28

  Disclosed is a photoreceptor comprising a support and a photosensitive layer which contains an azo compound of the formula (I): wherein PI and P2 are independently a halogen atom, a hydrogen atom, an alkyl group, an alkoxy group, an aryl group, an acetylamido group, an alkylsulfonyl group, (Q1 is an alkyl group, an alkoxy group, a phenyl group, an amino group, a hydroxy group or a hydrogen atom) or Q2-C- (Q1, Q3 and Q4 independently are a halogen atom, a hydrogen atom, an alkyl group, an alkoxy group, a phenyl group, an acyl group, an ester group, a hydroxy group or a vinyl group), the alkyl group, alkoxy group, aryl group, amino group and vinyl group may have a substituent; Y1 and Y2 independently are a hydrogen atom, a halogen atom, a cyano group, a hydroxy group, an alkyl group or an- alkoxy group; m and n each represent an integer of 0 to 2, and m and n cannot be both 0; A represents a group representend by any one of the following formulae: wherein Z is a group of atoms necessary for constituting a substituted or unsubstituted aromatic carbon ring or an aromatic heterocyclic ring, P3 is a substituted or unsubstituted carbamoyl group or a substituted or unsubstituted sulfamoyl group, R1 is a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted amino group, a substituted or unsubstituted carbamoyl group, a carboxyl group and its ester group or a cyano group, A' is a substituted or unsubstituted aryl group, R2 and R3 independently are a substituted or unsubstituted alkyl group, a substituted or unsubstituted aralkyl group or a substituted or unsubstituted aryl group.

  本发明公开了一种光感受器，该光感受器由支撑层和光敏层组成，光敏层含有式（I）的偶氮化合物： 其中 PI 和 P2 独立地为卤原子、氢原子、烷基、烷氧基、芳基、乙酰氨基、烷基磺酰基、 (Q1是烷基、烷氧基、苯基、氨基、羟基或氢原子）或 Q2-C-（Q1、Q3 和 Q4 分别为卤素原子、氢原子、烷基、烷氧基、苯基、酰基、酯基、羟基或乙烯基），烷基、烷氧基、芳基、氨基和乙烯基可具有取代基； Y1 和 Y2 分别为氢原子、卤素原子、氰基、羟基、烷基或烷氧基； m 和 n 分别为 0 至 2 的整数，且 m 和 n 不能均为 0； A 代表由下式中任何一个式子表示的基团： 其中 Z 是构成取代或未取代的芳香碳环或芳香杂环所必需的原子团，P3 是取代或未取代的氨基甲酰基或取代或未取代的氨基磺酰基，R1 是氢原子，取代或未取代的烷基，取代或未取代的氨基、A'是取代或未取代的芳基，R2 和 R3 分别是取代或未取代的烷基、取代或未取代的芳基或取代或未取代的芳基。