benzoic acid 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorodecyl ester

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: benzoic acid 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorodecyl ester
• 英文别名: Benzoic acid 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctyl ester；2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctyl benzoate
• 化学式: C₁₅H₇F₁₅O₂
• 分子量: 504.195
• InChiKey: CKSDFSTXYFPPPB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  32
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.53
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  17

反应信息

• 作为产物：
  描述：

  2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-十五氟辛-1-醇 、 苯甲酰氯 生成 benzoic acid 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorodecyl ester
  参考文献：
  名称：

  Reverse Fluorous Solid-Phase Extraction:  A New Technique for Rapid Separation of Fluorous Compounds

  摘要：

  Fluorous-tagged compounds can rapidly be separated from organic (non-tagged) compounds by the new separation technique of reverse fluorous solid-phase extraction (r-fspe). In a reversal of the roles of solid and liquid phases in standard fluorous spe, a mixture is charged to a polar solid phase (standard silica gel) and then eluted with a fluorous solvent or solvent mixture. The organic components of the mixture are retained, while the fluorous components pass.

  DOI：

  10.1021/ol049040o

文献信息

• Reverse Fluorous Solid-Phase Extraction:  A New Technique for Rapid Separation of Fluorous Compounds
  作者：Masato Matsugi、Dennis P. Curran

  DOI：10.1021/ol049040o

  日期：2004.8.1

  Fluorous-tagged compounds can rapidly be separated from organic (non-tagged) compounds by the new separation technique of reverse fluorous solid-phase extraction (r-fspe). In a reversal of the roles of solid and liquid phases in standard fluorous spe, a mixture is charged to a polar solid phase (standard silica gel) and then eluted with a fluorous solvent or solvent mixture. The organic components of the mixture are retained, while the fluorous components pass.