(E)-1-(1-triethylsilyl-1-propen-2-yl)naphthalene

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: (E)-1-(1-triethylsilyl-1-propen-2-yl)naphthalene
• 英文别名: triethyl-[(E)-2-naphthalen-1-ylprop-1-enyl]silane
• 化学式: C₁₉H₂₆Si
• 分子量: 282.501
• InChiKey: KULKMHYIMWGQKM-FOCLMDBBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.29
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.37
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (E)-1-(1-triethylsilyl-1-propen-2-yl)naphthalene 在 ruthenium trichloride 、 sodium periodate 作用下， 以 四氯化碳 、 水 、 乙腈 为溶剂， 反应 2.0h， 生成 1-萘乙酮
  参考文献：
  名称：

  Aromatic alkenylation using electrophilic organogallium reagent generated from allenylsilane and GaCl3

  摘要：

  Aromatic hydrocarbons are alkenylated with silylallene in the presence of GaCl3 at -90 degreesC. Organometallic electrophiles generated from the allene and GaCl3 are the active species in this reaction. A modest level of ortho-selectivity is observed. While the silylallene reacts exclusively at the 2-position, 1,2-alkradiene reacts at the 1-position predominantly. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(00)01043-7
• 作为产物：
  描述：

  萘 、 1-三乙基甲硅烷基-1,2-丙二烯 在 gallium(III) trichloride 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 生成 (E)-1-(1-triethylsilyl-1-propen-2-yl)naphthalene 、 (E)-2-(1-triethylsilyl-1-propen-2-yl)naphthalene
  参考文献：
  名称：

  Aromatic alkenylation using electrophilic organogallium reagent generated from allenylsilane and GaCl3

  摘要：

  Aromatic hydrocarbons are alkenylated with silylallene in the presence of GaCl3 at -90 degreesC. Organometallic electrophiles generated from the allene and GaCl3 are the active species in this reaction. A modest level of ortho-selectivity is observed. While the silylallene reacts exclusively at the 2-position, 1,2-alkradiene reacts at the 1-position predominantly. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(00)01043-7

文献信息

• Aromatic alkenylation using electrophilic organogallium reagent generated from allenylsilane and GaCl3
  作者：Yoshiyuki Kido、Fumi Yonehara、Masahiko Yamaguchi

  DOI：10.1016/s0040-4020(00)01043-7

  日期：2001.1

  Aromatic hydrocarbons are alkenylated with silylallene in the presence of GaCl3 at -90 degreesC. Organometallic electrophiles generated from the allene and GaCl3 are the active species in this reaction. A modest level of ortho-selectivity is observed. While the silylallene reacts exclusively at the 2-position, 1,2-alkradiene reacts at the 1-position predominantly. (C) 2001 Elsevier Science Ltd. All rights reserved.